CO2与地层水、致密砂砾岩相互作用机理研究

IF 4.3 3区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY
ACS Omega Pub Date : 2025-09-12 DOI:10.1021/acsomega.5c05004
Haiming Gao*, , , Kaigui Liao, , , Ge Wu, , , Wanfen Pu, , and , Yong Heng, 
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引用次数: 0

摘要

致密砂砾岩储层物性差,非均质性强,渗透率低,开发难度大。了解二氧化碳与此类地层的相互作用对于提高采收率(EOR)至关重要。对CO2与地层水、致密砂砾岩相互作用机理进行了实验研究。结果表明,在89℃、37.0 MPa的储层条件下,CO2在地层水中的溶解度受温度、压力和矿化度的影响较大。二氧化碳在地层水中溶解后形成碳酸,在酸性条件下引发长石等矿物的溶解反应。这导致长石矿物含量降低,岩心质量下降0.31%。同时,岩石的微观表面变得粗糙,出现了大量的溶解孔和溶洞。平均孔喉半径增大,驱替压力减小。这些变化通过扩大孔喉尺寸改善了岩石的孔隙结构,为油气运移创造了额外的流动通道。渗透率提高7.4 ~ 11.0%,提高了致密砂砾岩储层的生产能力。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Study on the Interaction Mechanisms among CO2, the Formation Water, and Tight Sandy Conglomerate

Tight sandy conglomerate reservoirs exhibit poor physical properties, strong heterogeneity, and significant development challenges due to low permeability. Understanding the interaction of CO2 with such formations is critical for enhanced oil recovery (EOR). Experimental studies on the interaction mechanisms among CO2, formation water, and tight sandy conglomerate were conducted. The results indicate that under the reservoir conditions of 89 °C and 37.0 MPa, the solubility of CO2 in the formation water is significantly influenced by temperature, pressure, and salinity. After dissolving in formation water, CO2 forms carbonic acid, which triggers dissolution reactions of minerals such as feldspar under acidic conditions. This leads to a reduction in feldspar mineral content and a 0.31% decrease in core mass. Concurrently, the rock’s microscopic surface becomes rougher with numerous dissolution pores and cavities emerging. The average pore-throat radius increases, and the displacement pressure decreases. These alterations improve the rock’s pore structure by enlarging pore-throat dimensions, creating additional flow channels for oil and gas migration. Consequently, the permeability increases by 7.4–11.0%, thereby enhancing the production capacity of tight sandy conglomerate reservoirs.

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来源期刊
ACS Omega
ACS Omega Chemical Engineering-General Chemical Engineering
CiteScore
6.60
自引率
4.90%
发文量
3945
审稿时长
2.4 months
期刊介绍: ACS Omega is an open-access global publication for scientific articles that describe new findings in chemistry and interfacing areas of science, without any perceived evaluation of immediate impact.
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