Haiming Gao*, , , Kaigui Liao, , , Ge Wu, , , Wanfen Pu, , and , Yong Heng,
{"title":"CO2与地层水、致密砂砾岩相互作用机理研究","authors":"Haiming Gao*, , , Kaigui Liao, , , Ge Wu, , , Wanfen Pu, , and , Yong Heng, ","doi":"10.1021/acsomega.5c05004","DOIUrl":null,"url":null,"abstract":"<p >Tight sandy conglomerate reservoirs exhibit poor physical properties, strong heterogeneity, and significant development challenges due to low permeability. Understanding the interaction of CO<sub>2</sub> with such formations is critical for enhanced oil recovery (EOR). Experimental studies on the interaction mechanisms among CO<sub>2</sub>, formation water, and tight sandy conglomerate were conducted. The results indicate that under the reservoir conditions of 89 °C and 37.0 MPa, the solubility of CO<sub>2</sub> in the formation water is significantly influenced by temperature, pressure, and salinity. After dissolving in formation water, CO<sub>2</sub> forms carbonic acid, which triggers dissolution reactions of minerals such as feldspar under acidic conditions. This leads to a reduction in feldspar mineral content and a 0.31% decrease in core mass. Concurrently, the rock’s microscopic surface becomes rougher with numerous dissolution pores and cavities emerging. The average pore-throat radius increases, and the displacement pressure decreases. These alterations improve the rock’s pore structure by enlarging pore-throat dimensions, creating additional flow channels for oil and gas migration. Consequently, the permeability increases by 7.4–11.0%, thereby enhancing the production capacity of tight sandy conglomerate reservoirs.</p>","PeriodicalId":22,"journal":{"name":"ACS Omega","volume":"10 37","pages":"42735–42745"},"PeriodicalIF":4.3000,"publicationDate":"2025-09-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.acs.org/doi/pdf/10.1021/acsomega.5c05004","citationCount":"0","resultStr":"{\"title\":\"Study on the Interaction Mechanisms among CO2, the Formation Water, and Tight Sandy Conglomerate\",\"authors\":\"Haiming Gao*, , , Kaigui Liao, , , Ge Wu, , , Wanfen Pu, , and , Yong Heng, \",\"doi\":\"10.1021/acsomega.5c05004\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p >Tight sandy conglomerate reservoirs exhibit poor physical properties, strong heterogeneity, and significant development challenges due to low permeability. Understanding the interaction of CO<sub>2</sub> with such formations is critical for enhanced oil recovery (EOR). Experimental studies on the interaction mechanisms among CO<sub>2</sub>, formation water, and tight sandy conglomerate were conducted. The results indicate that under the reservoir conditions of 89 °C and 37.0 MPa, the solubility of CO<sub>2</sub> in the formation water is significantly influenced by temperature, pressure, and salinity. After dissolving in formation water, CO<sub>2</sub> forms carbonic acid, which triggers dissolution reactions of minerals such as feldspar under acidic conditions. This leads to a reduction in feldspar mineral content and a 0.31% decrease in core mass. Concurrently, the rock’s microscopic surface becomes rougher with numerous dissolution pores and cavities emerging. The average pore-throat radius increases, and the displacement pressure decreases. These alterations improve the rock’s pore structure by enlarging pore-throat dimensions, creating additional flow channels for oil and gas migration. Consequently, the permeability increases by 7.4–11.0%, thereby enhancing the production capacity of tight sandy conglomerate reservoirs.</p>\",\"PeriodicalId\":22,\"journal\":{\"name\":\"ACS Omega\",\"volume\":\"10 37\",\"pages\":\"42735–42745\"},\"PeriodicalIF\":4.3000,\"publicationDate\":\"2025-09-12\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://pubs.acs.org/doi/pdf/10.1021/acsomega.5c05004\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"ACS Omega\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://pubs.acs.org/doi/10.1021/acsomega.5c05004\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"ACS Omega","FirstCategoryId":"92","ListUrlMain":"https://pubs.acs.org/doi/10.1021/acsomega.5c05004","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Study on the Interaction Mechanisms among CO2, the Formation Water, and Tight Sandy Conglomerate
Tight sandy conglomerate reservoirs exhibit poor physical properties, strong heterogeneity, and significant development challenges due to low permeability. Understanding the interaction of CO2 with such formations is critical for enhanced oil recovery (EOR). Experimental studies on the interaction mechanisms among CO2, formation water, and tight sandy conglomerate were conducted. The results indicate that under the reservoir conditions of 89 °C and 37.0 MPa, the solubility of CO2 in the formation water is significantly influenced by temperature, pressure, and salinity. After dissolving in formation water, CO2 forms carbonic acid, which triggers dissolution reactions of minerals such as feldspar under acidic conditions. This leads to a reduction in feldspar mineral content and a 0.31% decrease in core mass. Concurrently, the rock’s microscopic surface becomes rougher with numerous dissolution pores and cavities emerging. The average pore-throat radius increases, and the displacement pressure decreases. These alterations improve the rock’s pore structure by enlarging pore-throat dimensions, creating additional flow channels for oil and gas migration. Consequently, the permeability increases by 7.4–11.0%, thereby enhancing the production capacity of tight sandy conglomerate reservoirs.
ACS OmegaChemical Engineering-General Chemical Engineering
CiteScore
6.60
自引率
4.90%
发文量
3945
审稿时长
2.4 months
期刊介绍:
ACS Omega is an open-access global publication for scientific articles that describe new findings in chemistry and interfacing areas of science, without any perceived evaluation of immediate impact.