{"title":"基于h-ZnTiO3:Ta/p-GaN外延异质结的高温鲁棒自供电紫外探测器","authors":"Biao Zhang, , , Xiaochen Ma*, , , Yuankang Wang, , , Hongyan Zhu, , , Caina Luan, , , Jin Ma, , and , Hongdi Xiao*, ","doi":"10.1021/acsaelm.5c00774","DOIUrl":null,"url":null,"abstract":"<p >A self-powered photodetector based on a Ta-doped ZnTiO<sub>3</sub>/p-GaN single-crystal p–n heterojunction with a cross-finger (CF) structure is fabricated. Compared with the flat-plate structure, the CF-type photodetector presented higher photoresponsivity in a wavelength range of 250–350 nm. At zero bias, the UV photodetector with a CF structure exhibits excellent detection performance, including a high responsivity of 0.73 A/W, a good detectivity of 3.98 × 10<sup>12</sup> Jones, and a fast response time of 42.2/10.2 ms. The band composition and working mechanism of the heterojunction detector are elucidated accordingly. Besides, benefiting from the single-crystal structure, the <i>h</i>-ZnTiO<sub>3</sub>:Ta/p-GaN heterojunction self-powered detector maintains robust detection for UV signals at high temperatures. Compared to room temperature, even at 200 °C, the performance of the device only slightly deteriorates, with a responsivity of 0.66 A/W, a detectivity of 2.19 × 10<sup>12</sup> Jones, and a response time of 46.2/11.9 ms. This work provides a good candidate for a stabilized self-powered UV detector applied in high-temperature environments.</p>","PeriodicalId":3,"journal":{"name":"ACS Applied Electronic Materials","volume":"7 18","pages":"8348–8356"},"PeriodicalIF":4.7000,"publicationDate":"2025-09-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Robust Self-Powered UV Detector Based on a h-ZnTiO3:Ta/p-GaN Epitaxial Heterojunction for High-Temperature Application\",\"authors\":\"Biao Zhang, , , Xiaochen Ma*, , , Yuankang Wang, , , Hongyan Zhu, , , Caina Luan, , , Jin Ma, , and , Hongdi Xiao*, \",\"doi\":\"10.1021/acsaelm.5c00774\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p >A self-powered photodetector based on a Ta-doped ZnTiO<sub>3</sub>/p-GaN single-crystal p–n heterojunction with a cross-finger (CF) structure is fabricated. Compared with the flat-plate structure, the CF-type photodetector presented higher photoresponsivity in a wavelength range of 250–350 nm. At zero bias, the UV photodetector with a CF structure exhibits excellent detection performance, including a high responsivity of 0.73 A/W, a good detectivity of 3.98 × 10<sup>12</sup> Jones, and a fast response time of 42.2/10.2 ms. The band composition and working mechanism of the heterojunction detector are elucidated accordingly. Besides, benefiting from the single-crystal structure, the <i>h</i>-ZnTiO<sub>3</sub>:Ta/p-GaN heterojunction self-powered detector maintains robust detection for UV signals at high temperatures. Compared to room temperature, even at 200 °C, the performance of the device only slightly deteriorates, with a responsivity of 0.66 A/W, a detectivity of 2.19 × 10<sup>12</sup> Jones, and a response time of 46.2/11.9 ms. This work provides a good candidate for a stabilized self-powered UV detector applied in high-temperature environments.</p>\",\"PeriodicalId\":3,\"journal\":{\"name\":\"ACS Applied Electronic Materials\",\"volume\":\"7 18\",\"pages\":\"8348–8356\"},\"PeriodicalIF\":4.7000,\"publicationDate\":\"2025-09-11\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"ACS Applied Electronic Materials\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://pubs.acs.org/doi/10.1021/acsaelm.5c00774\",\"RegionNum\":3,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"ENGINEERING, ELECTRICAL & ELECTRONIC\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"ACS Applied Electronic Materials","FirstCategoryId":"88","ListUrlMain":"https://pubs.acs.org/doi/10.1021/acsaelm.5c00774","RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"ENGINEERING, ELECTRICAL & ELECTRONIC","Score":null,"Total":0}
引用次数: 0
摘要
制备了一种基于ta掺杂ZnTiO3/p-GaN单晶p-n异质结交叉指(CF)结构的自供电光电探测器。与平板结构相比,cf型光电探测器在250 ~ 350 nm波长范围内具有更高的光响应性。在零偏置下,具有CF结构的紫外光电探测器具有良好的检测性能,包括0.73 a /W的高响应率,3.98 × 1012 Jones的良好探测率和42.2/10.2 ms的快速响应时间。并据此阐明了异质结探测器的能带组成和工作机理。此外,得益于单晶结构,h-ZnTiO3:Ta/p-GaN异质结自供电探测器在高温下保持对紫外信号的稳定检测。与室温相比,即使在200°C时,器件的性能也仅略有下降,响应率为0.66 a /W,探测率为2.19 × 1012 Jones,响应时间为46.2/11.9 ms。这项工作为高温环境下稳定的自供电紫外探测器提供了良好的候选材料。
Robust Self-Powered UV Detector Based on a h-ZnTiO3:Ta/p-GaN Epitaxial Heterojunction for High-Temperature Application
A self-powered photodetector based on a Ta-doped ZnTiO3/p-GaN single-crystal p–n heterojunction with a cross-finger (CF) structure is fabricated. Compared with the flat-plate structure, the CF-type photodetector presented higher photoresponsivity in a wavelength range of 250–350 nm. At zero bias, the UV photodetector with a CF structure exhibits excellent detection performance, including a high responsivity of 0.73 A/W, a good detectivity of 3.98 × 1012 Jones, and a fast response time of 42.2/10.2 ms. The band composition and working mechanism of the heterojunction detector are elucidated accordingly. Besides, benefiting from the single-crystal structure, the h-ZnTiO3:Ta/p-GaN heterojunction self-powered detector maintains robust detection for UV signals at high temperatures. Compared to room temperature, even at 200 °C, the performance of the device only slightly deteriorates, with a responsivity of 0.66 A/W, a detectivity of 2.19 × 1012 Jones, and a response time of 46.2/11.9 ms. This work provides a good candidate for a stabilized self-powered UV detector applied in high-temperature environments.
期刊介绍:
ACS Applied Electronic Materials is an interdisciplinary journal publishing original research covering all aspects of electronic materials. The journal is devoted to reports of new and original experimental and theoretical research of an applied nature that integrate knowledge in the areas of materials science, engineering, optics, physics, and chemistry into important applications of electronic materials. Sample research topics that span the journal's scope are inorganic, organic, ionic and polymeric materials with properties that include conducting, semiconducting, superconducting, insulating, dielectric, magnetic, optoelectronic, piezoelectric, ferroelectric and thermoelectric.
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