Er3+和Yb3+离子共掺杂的手性无机纳米BiOBr荧光粉具有高度敏感的感温性能

IF 3.6 3区物理与天体物理 Q2 OPTICS

Journal of Luminescence Pub Date : 2025-09-10 DOI:10.1016/j.jlumin.2025.121524

Panying Jiang , Haoqiang Zhang , Yanni Lang , Rongze Ma , Dan Wu , Liang Xu , Aning Ma , Yongjin Li , Dacheng Zhou , Zhiguo Song , Yugeng Wen , Yong Yang , Jin Han , Jianbei Qiu

{"title":"Er3+和Yb3+离子共掺杂的手性无机纳米BiOBr荧光粉具有高度敏感的感温性能","authors":"Panying Jiang , Haoqiang Zhang , Yanni Lang , Rongze Ma , Dan Wu , Liang Xu , Aning Ma , Yongjin Li , Dacheng Zhou , Zhiguo Song , Yugeng Wen , Yong Yang , Jin Han , Jianbei Qiu","doi":"10.1016/j.jlumin.2025.121524","DOIUrl":null,"url":null,"abstract":"<div><div>A series of chiral nanostructured bismuth bromide doped with Er<sup>3+</sup>, Yb<sup>3+</sup> (D-BYE) phosphors were synthesized using a solvothermal method followed by an air annealing strategy. The upconversion luminescence (UCL) spectra were also recorded under 980 nm laser excitation in the temperature range from 295 to 565 K. The UCL intensity of D-BYE is about 34 times higher compared to the achiral nanostructured bismuth bromide doped with Er<sup>3+</sup>, Yb<sup>3+</sup> (A-BYE) phosphor. Optical temperature sensing of phosphors was achieved by evaluating the temperature sensing behavior using thermally coupled (TCLs) or non-thermally coupled (NTCLs) levels of Er<sup>3+</sup>. Impressively, the maximum relative sensitivity (S<sub>R</sub>) value of the D-BYE phosphor was 1.32 % K<sup>−1</sup> using the NTCLs method, which is about 1.6 times higher than the sensitivity of the TCLs-based method (0.86 % K<sup>−1</sup>). The results of this work demonstrate the great potential of D-BYE phosphors for optical temperature sensing.</div></div>","PeriodicalId":16159,"journal":{"name":"Journal of Luminescence","volume":"288 ","pages":"Article 121524"},"PeriodicalIF":3.6000,"publicationDate":"2025-09-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Chiral inorganic nanostructured BiOBr phosphor co-doped with Er3+ and Yb3+ ions exhibit highly sensitive temperature sensing properties\",\"authors\":\"Panying Jiang , Haoqiang Zhang , Yanni Lang , Rongze Ma , Dan Wu , Liang Xu , Aning Ma , Yongjin Li , Dacheng Zhou , Zhiguo Song , Yugeng Wen , Yong Yang , Jin Han , Jianbei Qiu\",\"doi\":\"10.1016/j.jlumin.2025.121524\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>A series of chiral nanostructured bismuth bromide doped with Er<sup>3+</sup>, Yb<sup>3+</sup> (D-BYE) phosphors were synthesized using a solvothermal method followed by an air annealing strategy. The upconversion luminescence (UCL) spectra were also recorded under 980 nm laser excitation in the temperature range from 295 to 565 K. The UCL intensity of D-BYE is about 34 times higher compared to the achiral nanostructured bismuth bromide doped with Er<sup>3+</sup>, Yb<sup>3+</sup> (A-BYE) phosphor. Optical temperature sensing of phosphors was achieved by evaluating the temperature sensing behavior using thermally coupled (TCLs) or non-thermally coupled (NTCLs) levels of Er<sup>3+</sup>. Impressively, the maximum relative sensitivity (S<sub>R</sub>) value of the D-BYE phosphor was 1.32 % K<sup>−1</sup> using the NTCLs method, which is about 1.6 times higher than the sensitivity of the TCLs-based method (0.86 % K<sup>−1</sup>). The results of this work demonstrate the great potential of D-BYE phosphors for optical temperature sensing.</div></div>\",\"PeriodicalId\":16159,\"journal\":{\"name\":\"Journal of Luminescence\",\"volume\":\"288 \",\"pages\":\"Article 121524\"},\"PeriodicalIF\":3.6000,\"publicationDate\":\"2025-09-10\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Luminescence\",\"FirstCategoryId\":\"101\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0022231325004648\",\"RegionNum\":3,\"RegionCategory\":\"物理与天体物理\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"OPTICS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Luminescence","FirstCategoryId":"101","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0022231325004648","RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"OPTICS","Score":null,"Total":0}

引用次数: 0

摘要

采用溶剂热法和空气退火法制备了一系列掺杂Er3+， Yb3+ (D-BYE)荧光粉的手性纳米溴化铋。在980 nm激光激发下，在295 ~ 565 K的温度范围内记录了上转换发光光谱。与掺杂Er3+， Yb3+ (A-BYE)荧光粉的非手性纳米结构溴化铋相比，D-BYE的UCL强度提高了约34倍。利用Er3+的热耦合（TCLs）或非热耦合（NTCLs）水平来评估荧光体的温度传感行为，从而实现了荧光体的光学温度传感。令人印象深刻的是，使用NTCLs方法的D-BYE荧光粉的最大相对灵敏度（SR）值为1.32% K−1，比基于tcls方法的灵敏度（0.86% K−1）高约1.6倍。这项工作的结果证明了D-BYE荧光粉在光学温度传感方面的巨大潜力。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

查看原文本刊更多论文

Chiral inorganic nanostructured BiOBr phosphor co-doped with Er3+ and Yb3+ ions exhibit highly sensitive temperature sensing properties

A series of chiral nanostructured bismuth bromide doped with Er³⁺, Yb³⁺ (D-BYE) phosphors were synthesized using a solvothermal method followed by an air annealing strategy. The upconversion luminescence (UCL) spectra were also recorded under 980 nm laser excitation in the temperature range from 295 to 565 K. The UCL intensity of D-BYE is about 34 times higher compared to the achiral nanostructured bismuth bromide doped with Er³⁺, Yb³⁺ (A-BYE) phosphor. Optical temperature sensing of phosphors was achieved by evaluating the temperature sensing behavior using thermally coupled (TCLs) or non-thermally coupled (NTCLs) levels of Er³⁺. Impressively, the maximum relative sensitivity (S_R) value of the D-BYE phosphor was 1.32 % K⁻¹ using the NTCLs method, which is about 1.6 times higher than the sensitivity of the TCLs-based method (0.86 % K⁻¹). The results of this work demonstrate the great potential of D-BYE phosphors for optical temperature sensing.

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

Journal of Luminescence 物理-光学

CiteScore

6.70

自引率

13.90%

发文量

850

审稿时长

3.8 months

期刊介绍： The purpose of the Journal of Luminescence is to provide a means of communication between scientists in different disciplines who share a common interest in the electronic excited states of molecular, ionic and covalent systems, whether crystalline, amorphous, or liquid. We invite original papers and reviews on such subjects as: exciton and polariton dynamics, dynamics of localized excited states, energy and charge transport in ordered and disordered systems, radiative and non-radiative recombination, relaxation processes, vibronic interactions in electronic excited states, photochemistry in condensed systems, excited state resonance, double resonance, spin dynamics, selective excitation spectroscopy, hole burning, coherent processes in excited states, (e.g. coherent optical transients, photon echoes, transient gratings), multiphoton processes, optical bistability, photochromism, and new techniques for the study of excited states. This list is not intended to be exhaustive. Papers in the traditional areas of optical spectroscopy (absorption, MCD, luminescence, Raman scattering) are welcome. Papers on applications (phosphors, scintillators, electro- and cathodo-luminescence, radiography, bioimaging, solar energy, energy conversion, etc.) are also welcome if they present results of scientific, rather than only technological interest. However, papers containing purely theoretical results, not related to phenomena in the excited states, as well as papers using luminescence spectroscopy to perform routine analytical chemistry or biochemistry procedures, are outside the scope of the journal. Some exceptions will be possible at the discretion of the editors.