{"title":"结构可变波拉型冠醚-二茂铁表面活性剂囊泡的合成与表征","authors":"Wei Li, Yuji Jinbo, Tatsuro Kijima","doi":"10.1016/j.colcom.2025.100857","DOIUrl":null,"url":null,"abstract":"<div><div>Bola-type ferrocene surfactants with terminal 18-crown-6-ether groups were synthesized. Despite showing no improvement in activity over the monosubstituted analog, they exhibited a very low critical aggregation concentration (0.06 mM). Glucose encapsulation and SAXS confirmed vesicle formation with an internal aqueous phase, enabling controlled release via potassium ion complexation.</div></div>","PeriodicalId":10483,"journal":{"name":"Colloid and Interface Science Communications","volume":"69 ","pages":"Article 100857"},"PeriodicalIF":4.7000,"publicationDate":"2025-09-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Synthesis and characterization of structurally variable bola type crown ether-ferrocene surfactant vesicles\",\"authors\":\"Wei Li, Yuji Jinbo, Tatsuro Kijima\",\"doi\":\"10.1016/j.colcom.2025.100857\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Bola-type ferrocene surfactants with terminal 18-crown-6-ether groups were synthesized. Despite showing no improvement in activity over the monosubstituted analog, they exhibited a very low critical aggregation concentration (0.06 mM). Glucose encapsulation and SAXS confirmed vesicle formation with an internal aqueous phase, enabling controlled release via potassium ion complexation.</div></div>\",\"PeriodicalId\":10483,\"journal\":{\"name\":\"Colloid and Interface Science Communications\",\"volume\":\"69 \",\"pages\":\"Article 100857\"},\"PeriodicalIF\":4.7000,\"publicationDate\":\"2025-09-19\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Colloid and Interface Science Communications\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S221503822500041X\",\"RegionNum\":3,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Colloid and Interface Science Communications","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S221503822500041X","RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
Synthesis and characterization of structurally variable bola type crown ether-ferrocene surfactant vesicles
Bola-type ferrocene surfactants with terminal 18-crown-6-ether groups were synthesized. Despite showing no improvement in activity over the monosubstituted analog, they exhibited a very low critical aggregation concentration (0.06 mM). Glucose encapsulation and SAXS confirmed vesicle formation with an internal aqueous phase, enabling controlled release via potassium ion complexation.
期刊介绍:
Colloid and Interface Science Communications provides a forum for the highest visibility and rapid publication of short initial reports on new fundamental concepts, research findings, and topical applications at the forefront of the increasingly interdisciplinary area of colloid and interface science.