回收风力发电机叶片粉末制成HDPE木塑复合材料:通过界面改性增强机械性能和阻燃性能

IF 7.4 2区 化学 Q1 POLYMER SCIENCE
YiChen Chen , Wufei Tang , Zhaozhen Zhang , Peixin Li , Shibing Sun , Wanfu Wang , Xiaodong Jin
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引用次数: 0

摘要

为了充分回收废弃风力发电机叶片(rWTB)粉末,将其主要成分(玻璃钢(GFRP)和轻木(BW))掺入高密度聚乙烯(HDPE)中,制备以马来酸酐接枝聚乙烯(MAPE)为相容剂的木塑复合材料(WPC)。通过改变GFRP与BW的质量比,系统地研究了rWTB/HDPE复合材料的力学性能、界面形态和吸水性。当gpr用量为30%,BW用量为10%时,得到的H/30G10B复合材料的抗拉强度最高(27.73 MPa), MAPE用量为3%时,其冲击强度提高(21.85 KJ/m2)。扫描电镜(SEM)图像显示,MAPE改善了填料与HDPE基体之间的界面结合。为了提高HDPE复合材料的耐火性,在H/30G10B样品中进一步掺入了聚磷酸铵(APP)。当APP添加量为22%时,最佳样品的极限氧指数(LOI)为36.8%,UL-94的V-0等级,锥量热法的放热减少。综上所述,本文提供了一种资源利用的新方法,既可以提高复合材料的性能,又可以避免对环境的污染。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Recycling of wind turbine blade powder into HDPE wood-plastic composites: Enhanced mechanical and flame-retardant properties via interfacial modification
To fully recycle the wasted wind turbine blades (rWTB) powder, its major components (glass fiber reinforced plastic (GFRP) and balsa wood (BW)) was incorporated into high-density polyethylene (HDPE) to prepare wood-plastic composites (WPC) with maleic anhydride grafted polyethylene (MAPE) as the compatibilizer. By varying the mass ratio of GFRP to BW, the mechanical properties, interfacial morphology and water absorption of rWTB/HDPE composites were systematically investigated. With the combination of 30 % GFPR and 10 %BW, the obtained H/30G10B composites exhibited the highest the tensile strength (27.73 MPa) and increased impact strength (21.85 KJ/m2) with the presence of 3 % MAPE. Scanning electron microscopy (SEM) images showed that MAPE improved the interfacial bonding between the filler and the HDPE matrix. To improve the fire resistance of HDPE composites, ammonium polyphosphate (APP) was further incorporated into H/30G10B sample. With the addition of 22 % APP, the best sample could reach a limiting oxygen index (LOI) of 36.8 %, V-0 rating in UL-94 and a decreased heat release in cone calorimetry. In summary, this paper provides a new method for resource utilization of rWTB, which can improve the performance of composites and avoid environmental pollution.
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来源期刊
Polymer Degradation and Stability
Polymer Degradation and Stability 化学-高分子科学
CiteScore
10.10
自引率
10.20%
发文量
325
审稿时长
23 days
期刊介绍: Polymer Degradation and Stability deals with the degradation reactions and their control which are a major preoccupation of practitioners of the many and diverse aspects of modern polymer technology. Deteriorative reactions occur during processing, when polymers are subjected to heat, oxygen and mechanical stress, and during the useful life of the materials when oxygen and sunlight are the most important degradative agencies. In more specialised applications, degradation may be induced by high energy radiation, ozone, atmospheric pollutants, mechanical stress, biological action, hydrolysis and many other influences. The mechanisms of these reactions and stabilisation processes must be understood if the technology and application of polymers are to continue to advance. The reporting of investigations of this kind is therefore a major function of this journal. However there are also new developments in polymer technology in which degradation processes find positive applications. For example, photodegradable plastics are now available, the recycling of polymeric products will become increasingly important, degradation and combustion studies are involved in the definition of the fire hazards which are associated with polymeric materials and the microelectronics industry is vitally dependent upon polymer degradation in the manufacture of its circuitry. Polymer properties may also be improved by processes like curing and grafting, the chemistry of which can be closely related to that which causes physical deterioration in other circumstances.
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