Filomena Marchetta , Lucia D'Arienzo , Luciano Di Maio , Luigi Botta , Maria Chiara Mistretta , Paola Rizzarelli , Melania Leanza , Paola Scarfato
{"title":"可持续生物复合材料从聚丁二酸增强glochids:结合废物增值与改进的材料性能和加速生物降解性","authors":"Filomena Marchetta , Lucia D'Arienzo , Luciano Di Maio , Luigi Botta , Maria Chiara Mistretta , Paola Rizzarelli , Melania Leanza , Paola Scarfato","doi":"10.1016/j.coco.2025.102597","DOIUrl":null,"url":null,"abstract":"<div><div>This study presents the development and characterization of novel biodegradable biocomposites composed of polybutylene succinate (PBS) reinforced with glochids, a fibrous agro-food waste from <em>Opuntia ficus-indica</em> fruits. With their naturally barbed surface, glochids offer the potential to enhance interfacial adhesion with the polymer matrix, contributing to improved composite performance. The research aligns with circular economy principles by transforming an abundant byproduct into a functional reinforcement, reducing waste while providing sustainable materials entirely derived from renewable resources with enhanced properties. Biocomposites with different glochids loadings (14, 20, and 30 wt%) were prepared using twin-screw extrusion and subjected to comprehensive physical-mechanical characterization (thermal and FT-IR spectroscopy measurements, morphological analyses, tensile tests) and biodegradability analyses in compost. The addition of glochids resulted in improved mechanical properties, including increased Young's modulus (up to a maximum of ca. 70 % for the most loaded system) and stiffness, with an enhancement in heat deflection temperature (HDT) of over 10 °C, suggesting suitability for high-temperature applications. Moreover, despite the fact that glochids induced an initial increase in hydrophobicity, compost burial tests revealed that the natural filler accelerated degradation within 90 days, demonstrating improved end-of-life performance. These findings highlight the potential of PBS/glochids biocomposites as eco-friendly alternatives to conventional plastics for applications such as packaging, consumer goods, and automotive interiors. By promoting waste valorization, these materials align with the principles of a circular economy, fostering more sustainable production and consumption practices.</div></div>","PeriodicalId":10533,"journal":{"name":"Composites Communications","volume":"59 ","pages":"Article 102597"},"PeriodicalIF":7.7000,"publicationDate":"2025-09-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Sustainable biocomposites from polybutylene succinate reinforced with glochids: Combining waste valorization with improved material properties and accelerated biodegradability\",\"authors\":\"Filomena Marchetta , Lucia D'Arienzo , Luciano Di Maio , Luigi Botta , Maria Chiara Mistretta , Paola Rizzarelli , Melania Leanza , Paola Scarfato\",\"doi\":\"10.1016/j.coco.2025.102597\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>This study presents the development and characterization of novel biodegradable biocomposites composed of polybutylene succinate (PBS) reinforced with glochids, a fibrous agro-food waste from <em>Opuntia ficus-indica</em> fruits. With their naturally barbed surface, glochids offer the potential to enhance interfacial adhesion with the polymer matrix, contributing to improved composite performance. The research aligns with circular economy principles by transforming an abundant byproduct into a functional reinforcement, reducing waste while providing sustainable materials entirely derived from renewable resources with enhanced properties. Biocomposites with different glochids loadings (14, 20, and 30 wt%) were prepared using twin-screw extrusion and subjected to comprehensive physical-mechanical characterization (thermal and FT-IR spectroscopy measurements, morphological analyses, tensile tests) and biodegradability analyses in compost. The addition of glochids resulted in improved mechanical properties, including increased Young's modulus (up to a maximum of ca. 70 % for the most loaded system) and stiffness, with an enhancement in heat deflection temperature (HDT) of over 10 °C, suggesting suitability for high-temperature applications. Moreover, despite the fact that glochids induced an initial increase in hydrophobicity, compost burial tests revealed that the natural filler accelerated degradation within 90 days, demonstrating improved end-of-life performance. These findings highlight the potential of PBS/glochids biocomposites as eco-friendly alternatives to conventional plastics for applications such as packaging, consumer goods, and automotive interiors. By promoting waste valorization, these materials align with the principles of a circular economy, fostering more sustainable production and consumption practices.</div></div>\",\"PeriodicalId\":10533,\"journal\":{\"name\":\"Composites Communications\",\"volume\":\"59 \",\"pages\":\"Article 102597\"},\"PeriodicalIF\":7.7000,\"publicationDate\":\"2025-09-17\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Composites Communications\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S245221392500350X\",\"RegionNum\":2,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"MATERIALS SCIENCE, COMPOSITES\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Composites Communications","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S245221392500350X","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"MATERIALS SCIENCE, COMPOSITES","Score":null,"Total":0}
Sustainable biocomposites from polybutylene succinate reinforced with glochids: Combining waste valorization with improved material properties and accelerated biodegradability
This study presents the development and characterization of novel biodegradable biocomposites composed of polybutylene succinate (PBS) reinforced with glochids, a fibrous agro-food waste from Opuntia ficus-indica fruits. With their naturally barbed surface, glochids offer the potential to enhance interfacial adhesion with the polymer matrix, contributing to improved composite performance. The research aligns with circular economy principles by transforming an abundant byproduct into a functional reinforcement, reducing waste while providing sustainable materials entirely derived from renewable resources with enhanced properties. Biocomposites with different glochids loadings (14, 20, and 30 wt%) were prepared using twin-screw extrusion and subjected to comprehensive physical-mechanical characterization (thermal and FT-IR spectroscopy measurements, morphological analyses, tensile tests) and biodegradability analyses in compost. The addition of glochids resulted in improved mechanical properties, including increased Young's modulus (up to a maximum of ca. 70 % for the most loaded system) and stiffness, with an enhancement in heat deflection temperature (HDT) of over 10 °C, suggesting suitability for high-temperature applications. Moreover, despite the fact that glochids induced an initial increase in hydrophobicity, compost burial tests revealed that the natural filler accelerated degradation within 90 days, demonstrating improved end-of-life performance. These findings highlight the potential of PBS/glochids biocomposites as eco-friendly alternatives to conventional plastics for applications such as packaging, consumer goods, and automotive interiors. By promoting waste valorization, these materials align with the principles of a circular economy, fostering more sustainable production and consumption practices.
期刊介绍:
Composites Communications (Compos. Commun.) is a peer-reviewed journal publishing short communications and letters on the latest advances in composites science and technology. With a rapid review and publication process, its goal is to disseminate new knowledge promptly within the composites community. The journal welcomes manuscripts presenting creative concepts and new findings in design, state-of-the-art approaches in processing, synthesis, characterization, and mechanics modeling. In addition to traditional fiber-/particulate-reinforced engineering composites, it encourages submissions on composites with exceptional physical, mechanical, and fracture properties, as well as those with unique functions and significant application potential. This includes biomimetic and bio-inspired composites for biomedical applications, functional nano-composites for thermal management and energy applications, and composites designed for extreme service environments.