纳秒脉冲放电的可靠点火超贫氢-空气混合物

IF 5.2 2区 工程技术 Q2 ENERGY & FUELS
Galia Faingold, Leander Krieg, Francis Pagaud, Quentin Malé, Nicolas Noiray
{"title":"纳秒脉冲放电的可靠点火超贫氢-空气混合物","authors":"Galia Faingold,&nbsp;Leander Krieg,&nbsp;Francis Pagaud,&nbsp;Quentin Malé,&nbsp;Nicolas Noiray","doi":"10.1016/j.proci.2025.105840","DOIUrl":null,"url":null,"abstract":"<div><div>The safe ignition and stabilization of ultra-lean hydrogen-air mixtures remain a critical challenge for enabling low-emission hydrogen combustion in gas turbines. This study investigates nanosecond repetitively pulsed discharges for reliable ignition under conditions relevant to lean-premixed hydrogen operation. Experiments were conducted in a modular combustion rig, where the influence of plasma parameters – including pulse energy, pulse repetition frequency, and pulse number – on ignition and flame kernel development was systematically explored. High-speed OH<span><math><msup><mrow></mrow><mrow><mo>∗</mo></mrow></msup></math></span> chemiluminescence imaging tracked ignition kernel formation and propagation, while optical emission spectroscopy provided characterization of the plasma properties. For equivalence ratios of <span><math><mrow><mi>ϕ</mi><mo>=</mo><mn>0</mn><mo>.</mo><mn>15</mn><mo>−</mo><mn>0</mn><mo>.</mo><mn>2</mn></mrow></math></span>, successful ignition is mostly a function of pulse energy, more than pulse number, with a clear transition from non-ignition to reliable ignition observed above a critical energy threshold. This transition coincides with the change from glow to spark regime. Rather than showing a probabilistic ignition behavior, ignition occurs reliably in the spark regime, and fails at the transition to glow. Optical emission spectroscopy measurements of gas and vibrational temperatures indicate that this shift coincides with an increased production of radicals rather than vibrational excitation, which are more effective in enhancing ignition. For equivalence ratios of <span><math><mrow><mi>ϕ</mi><mo>=</mo><mn>0</mn><mo>.</mo><mn>086</mn></mrow></math></span> and 0.1, kernels were created but did not expand in the flowing mixture, and the interaction between pulses — pulse number and repetition frequency became critical. At these ultra-lean conditions, these interactions enable the formation of larger ignition kernels that are less prone to extinction. These findings demonstrate that nanosecond repetitively pulsed based plasma-assisted ignition can significantly extend the ignition limits of lean hydrogen mixtures, offering a promising pathway for stabilizing ultra-lean hydrogen combustion with minimized NO<span><math><msub><mrow></mrow><mrow><mi>x</mi></mrow></msub></math></span> emissions. Moreover, the ability to reliably ignite ultra-lean mixtures is highly relevant for hydrogen internal combustion engines, where consistent ignition at low equivalence ratios is crucial to reducing cycle-to-cycle variability and improving efficiency.</div></div>","PeriodicalId":408,"journal":{"name":"Proceedings of the Combustion Institute","volume":"41 ","pages":"Article 105840"},"PeriodicalIF":5.2000,"publicationDate":"2025-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Nanosecond pulsed discharges for reliable ignition of ultra-lean hydrogen-air mixtures\",\"authors\":\"Galia Faingold,&nbsp;Leander Krieg,&nbsp;Francis Pagaud,&nbsp;Quentin Malé,&nbsp;Nicolas Noiray\",\"doi\":\"10.1016/j.proci.2025.105840\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>The safe ignition and stabilization of ultra-lean hydrogen-air mixtures remain a critical challenge for enabling low-emission hydrogen combustion in gas turbines. This study investigates nanosecond repetitively pulsed discharges for reliable ignition under conditions relevant to lean-premixed hydrogen operation. Experiments were conducted in a modular combustion rig, where the influence of plasma parameters – including pulse energy, pulse repetition frequency, and pulse number – on ignition and flame kernel development was systematically explored. High-speed OH<span><math><msup><mrow></mrow><mrow><mo>∗</mo></mrow></msup></math></span> chemiluminescence imaging tracked ignition kernel formation and propagation, while optical emission spectroscopy provided characterization of the plasma properties. For equivalence ratios of <span><math><mrow><mi>ϕ</mi><mo>=</mo><mn>0</mn><mo>.</mo><mn>15</mn><mo>−</mo><mn>0</mn><mo>.</mo><mn>2</mn></mrow></math></span>, successful ignition is mostly a function of pulse energy, more than pulse number, with a clear transition from non-ignition to reliable ignition observed above a critical energy threshold. This transition coincides with the change from glow to spark regime. Rather than showing a probabilistic ignition behavior, ignition occurs reliably in the spark regime, and fails at the transition to glow. Optical emission spectroscopy measurements of gas and vibrational temperatures indicate that this shift coincides with an increased production of radicals rather than vibrational excitation, which are more effective in enhancing ignition. For equivalence ratios of <span><math><mrow><mi>ϕ</mi><mo>=</mo><mn>0</mn><mo>.</mo><mn>086</mn></mrow></math></span> and 0.1, kernels were created but did not expand in the flowing mixture, and the interaction between pulses — pulse number and repetition frequency became critical. At these ultra-lean conditions, these interactions enable the formation of larger ignition kernels that are less prone to extinction. These findings demonstrate that nanosecond repetitively pulsed based plasma-assisted ignition can significantly extend the ignition limits of lean hydrogen mixtures, offering a promising pathway for stabilizing ultra-lean hydrogen combustion with minimized NO<span><math><msub><mrow></mrow><mrow><mi>x</mi></mrow></msub></math></span> emissions. Moreover, the ability to reliably ignite ultra-lean mixtures is highly relevant for hydrogen internal combustion engines, where consistent ignition at low equivalence ratios is crucial to reducing cycle-to-cycle variability and improving efficiency.</div></div>\",\"PeriodicalId\":408,\"journal\":{\"name\":\"Proceedings of the Combustion Institute\",\"volume\":\"41 \",\"pages\":\"Article 105840\"},\"PeriodicalIF\":5.2000,\"publicationDate\":\"2025-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Proceedings of the Combustion Institute\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S1540748925000549\",\"RegionNum\":2,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"ENERGY & FUELS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Proceedings of the Combustion Institute","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1540748925000549","RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"ENERGY & FUELS","Score":null,"Total":0}
引用次数: 0

摘要

超稀薄氢-空气混合物的安全点火和稳定仍然是实现燃气轮机低排放氢燃烧的关键挑战。本文研究了在稀薄预混氢操作条件下,纳秒重复脉冲放电的可靠点火。在模块化燃烧装置上进行了实验,系统地探索了等离子体参数(脉冲能量、脉冲重复频率和脉冲数)对点火和火焰核发展的影响。高速OH *化学发光成像跟踪了点火核的形成和传播,而光学发射光谱提供了等离子体特性的表征。对于等效比φ =0.15−0.2,成功点火主要是脉冲能量的函数,而不是脉冲数,在临界能量阈值以上观察到从不点火到可靠点火的明显转变。这种转变与从发光到火花的变化一致。而不是显示一个概率点火行为,点火发生可靠的火花制度,并在过渡到发光失败。气体和振动温度的光学发射光谱测量表明,这种变化与自由基产生的增加而不是振动激发相一致,振动激发在增强点火方面更有效。对于等效比的φ =0.086和0.1,内核被创建,但没有扩大在流动的混合物,和脉冲之间的相互作用-脉冲数和重复频率变得至关重要。在这些超稀薄的条件下,这些相互作用使形成更大的点火核,不易熄灭。这些发现表明,基于纳秒重复脉冲的等离子体辅助点火可以显著延长贫氢混合物的点火极限,为稳定超低NOx排放的超贫氢燃烧提供了一条有希望的途径。此外,可靠地点燃超稀混合物的能力与氢内燃机高度相关,在低当量比下持续点火对于减少循环间的可变性和提高效率至关重要。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Nanosecond pulsed discharges for reliable ignition of ultra-lean hydrogen-air mixtures
The safe ignition and stabilization of ultra-lean hydrogen-air mixtures remain a critical challenge for enabling low-emission hydrogen combustion in gas turbines. This study investigates nanosecond repetitively pulsed discharges for reliable ignition under conditions relevant to lean-premixed hydrogen operation. Experiments were conducted in a modular combustion rig, where the influence of plasma parameters – including pulse energy, pulse repetition frequency, and pulse number – on ignition and flame kernel development was systematically explored. High-speed OH chemiluminescence imaging tracked ignition kernel formation and propagation, while optical emission spectroscopy provided characterization of the plasma properties. For equivalence ratios of ϕ=0.150.2, successful ignition is mostly a function of pulse energy, more than pulse number, with a clear transition from non-ignition to reliable ignition observed above a critical energy threshold. This transition coincides with the change from glow to spark regime. Rather than showing a probabilistic ignition behavior, ignition occurs reliably in the spark regime, and fails at the transition to glow. Optical emission spectroscopy measurements of gas and vibrational temperatures indicate that this shift coincides with an increased production of radicals rather than vibrational excitation, which are more effective in enhancing ignition. For equivalence ratios of ϕ=0.086 and 0.1, kernels were created but did not expand in the flowing mixture, and the interaction between pulses — pulse number and repetition frequency became critical. At these ultra-lean conditions, these interactions enable the formation of larger ignition kernels that are less prone to extinction. These findings demonstrate that nanosecond repetitively pulsed based plasma-assisted ignition can significantly extend the ignition limits of lean hydrogen mixtures, offering a promising pathway for stabilizing ultra-lean hydrogen combustion with minimized NOx emissions. Moreover, the ability to reliably ignite ultra-lean mixtures is highly relevant for hydrogen internal combustion engines, where consistent ignition at low equivalence ratios is crucial to reducing cycle-to-cycle variability and improving efficiency.
求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
Proceedings of the Combustion Institute
Proceedings of the Combustion Institute 工程技术-工程:化工
CiteScore
7.00
自引率
0.00%
发文量
420
审稿时长
3.0 months
期刊介绍: The Proceedings of the Combustion Institute contains forefront contributions in fundamentals and applications of combustion science. For more than 50 years, the Combustion Institute has served as the peak international society for dissemination of scientific and technical research in the combustion field. In addition to author submissions, the Proceedings of the Combustion Institute includes the Institute''s prestigious invited strategic and topical reviews that represent indispensable resources for emergent research in the field. All papers are subjected to rigorous peer review. Research papers and invited topical reviews; Reaction Kinetics; Soot, PAH, and other large molecules; Diagnostics; Laminar Flames; Turbulent Flames; Heterogeneous Combustion; Spray and Droplet Combustion; Detonations, Explosions & Supersonic Combustion; Fire Research; Stationary Combustion Systems; IC Engine and Gas Turbine Combustion; New Technology Concepts The electronic version of Proceedings of the Combustion Institute contains supplemental material such as reaction mechanisms, illustrating movies, and other data.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:604180095
Book学术官方微信