Tips and Procedures for Safe Handling of Anhydrous Hydrogen Fluoride and Pure Elemental Fluorine in Chemical University Laboratories

In this article, we summarize our experience in working safely with pure fluorine and hydrogen fluoride and highlight potential hazards so that they can be realistically assessed. Technical, organizational, and personal protective measures for safe working are discussed, and suitable materials and selected equipment for handling pure fluorine and reactive fluorides are presented. Options for disposing of reactive waste, measures to be taken in the event of accidents, and first aid measures are also described. With careful experimental planning by trained personnel and compliance with safety measures, it is possible to handle anhydrous hydrogen fluoride, elemental fluorine, and other highly reactive substances on a laboratory scale while minimizing risks.