{"title":"一氢化铁(FeH)的项能分析","authors":"T.E. Blackmore, D.W. Tokaryk","doi":"10.1016/j.jqsrt.2025.109650","DOIUrl":null,"url":null,"abstract":"<div><div>MARVEL software was used to perform a global fit on all FeH transitions available in the literature to create an optimized and comprehensive term energy list. The diverse types of data, data sources, and electronic transitions that were used for this fit are organized and tabulated. To improve the fit, inconsistencies in the F <span><math><mrow><msup><mrow></mrow><mrow><mn>4</mn></mrow></msup><msub><mrow><mi>Δ</mi></mrow><mrow></mrow></msub></mrow></math></span> <span><math><msub><mrow></mrow><mrow></mrow></msub></math></span>-X <span><math><mrow><msup><mrow></mrow><mrow><mn>4</mn></mrow></msup><msub><mrow><mi>Δ</mi></mrow><mrow></mrow></msub></mrow></math></span> <span><math><msub><mrow></mrow><mrow></mrow></msub></math></span> analysis published in 1987 were fixed using modern computation and visualization techniques. F <span><math><mrow><msup><mrow></mrow><mrow><mn>4</mn></mrow></msup><msub><mrow><mi>Δ</mi></mrow><mrow></mrow></msub></mrow></math></span> <span><math><msub><mrow></mrow><mrow></mrow></msub></math></span>-A <span><math><mrow><msup><mrow></mrow><mrow><mn>4</mn></mrow></msup><msub><mrow><mi>Π</mi></mrow><mrow></mrow></msub></mrow></math></span> <span><math><msub><mrow></mrow><mrow></mrow></msub></math></span> transitions were identified in spectra published in the Kitt Peak archive and added to the fit. Also, several laser excitation and Fourier transform spectrometer measurements taken in our lab were added, including those from the newly discovered I <span><math><mrow><msup><mrow></mrow><mrow><mn>4</mn></mrow></msup><msub><mrow><mi>Φ</mi></mrow><mrow></mrow></msub></mrow></math></span> electronic state. The final term energy list and transition list are given in the supplementary material.</div></div>","PeriodicalId":16935,"journal":{"name":"Journal of Quantitative Spectroscopy & Radiative Transfer","volume":"347 ","pages":"Article 109650"},"PeriodicalIF":1.9000,"publicationDate":"2025-09-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Term energy analysis of iron monohydride (FeH)\",\"authors\":\"T.E. Blackmore, D.W. Tokaryk\",\"doi\":\"10.1016/j.jqsrt.2025.109650\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>MARVEL software was used to perform a global fit on all FeH transitions available in the literature to create an optimized and comprehensive term energy list. The diverse types of data, data sources, and electronic transitions that were used for this fit are organized and tabulated. To improve the fit, inconsistencies in the F <span><math><mrow><msup><mrow></mrow><mrow><mn>4</mn></mrow></msup><msub><mrow><mi>Δ</mi></mrow><mrow></mrow></msub></mrow></math></span> <span><math><msub><mrow></mrow><mrow></mrow></msub></math></span>-X <span><math><mrow><msup><mrow></mrow><mrow><mn>4</mn></mrow></msup><msub><mrow><mi>Δ</mi></mrow><mrow></mrow></msub></mrow></math></span> <span><math><msub><mrow></mrow><mrow></mrow></msub></math></span> analysis published in 1987 were fixed using modern computation and visualization techniques. F <span><math><mrow><msup><mrow></mrow><mrow><mn>4</mn></mrow></msup><msub><mrow><mi>Δ</mi></mrow><mrow></mrow></msub></mrow></math></span> <span><math><msub><mrow></mrow><mrow></mrow></msub></math></span>-A <span><math><mrow><msup><mrow></mrow><mrow><mn>4</mn></mrow></msup><msub><mrow><mi>Π</mi></mrow><mrow></mrow></msub></mrow></math></span> <span><math><msub><mrow></mrow><mrow></mrow></msub></math></span> transitions were identified in spectra published in the Kitt Peak archive and added to the fit. Also, several laser excitation and Fourier transform spectrometer measurements taken in our lab were added, including those from the newly discovered I <span><math><mrow><msup><mrow></mrow><mrow><mn>4</mn></mrow></msup><msub><mrow><mi>Φ</mi></mrow><mrow></mrow></msub></mrow></math></span> electronic state. The final term energy list and transition list are given in the supplementary material.</div></div>\",\"PeriodicalId\":16935,\"journal\":{\"name\":\"Journal of Quantitative Spectroscopy & Radiative Transfer\",\"volume\":\"347 \",\"pages\":\"Article 109650\"},\"PeriodicalIF\":1.9000,\"publicationDate\":\"2025-09-04\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Quantitative Spectroscopy & Radiative Transfer\",\"FirstCategoryId\":\"101\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0022407325003127\",\"RegionNum\":3,\"RegionCategory\":\"物理与天体物理\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"OPTICS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Quantitative Spectroscopy & Radiative Transfer","FirstCategoryId":"101","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0022407325003127","RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"OPTICS","Score":null,"Total":0}
MARVEL software was used to perform a global fit on all FeH transitions available in the literature to create an optimized and comprehensive term energy list. The diverse types of data, data sources, and electronic transitions that were used for this fit are organized and tabulated. To improve the fit, inconsistencies in the F -X analysis published in 1987 were fixed using modern computation and visualization techniques. F -A transitions were identified in spectra published in the Kitt Peak archive and added to the fit. Also, several laser excitation and Fourier transform spectrometer measurements taken in our lab were added, including those from the newly discovered I electronic state. The final term energy list and transition list are given in the supplementary material.
期刊介绍:
Papers with the following subject areas are suitable for publication in the Journal of Quantitative Spectroscopy and Radiative Transfer:
- Theoretical and experimental aspects of the spectra of atoms, molecules, ions, and plasmas.
- Spectral lineshape studies including models and computational algorithms.
- Atmospheric spectroscopy.
- Theoretical and experimental aspects of light scattering.
- Application of light scattering in particle characterization and remote sensing.
- Application of light scattering in biological sciences and medicine.
- Radiative transfer in absorbing, emitting, and scattering media.
- Radiative transfer in stochastic media.