封面：放大的三喹啉（Enl-TQ）：三聚喹啉环体系的几何缩放在化学行为上的差异（化学）。亚洲J. 17/2025)

IF 3.3 3区化学 Q2 CHEMISTRY, MULTIDISCIPLINARY

Chemistry - An Asian Journal Pub Date : 2025-09-19 DOI:10.1002/asia.70306

Mai Yamashita, Dr. Ryosuke Tsutsumi, Dr. Toi Kobayashi, Prof. Dr. Naoya Kumagai

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引用次数: 0

摘要

三喹啉（TQ）是一种头尾排列的准平面环喹啉三聚体，它强烈地捕获质子并表现出不同寻常的物理化学性质。见第10.1002/asia条。202500429， Naoya Kumagai及其同事设计并合成了其扩展类似物，expanded - triquinoline (Enl-TQ)，其中三个炔单元嵌入三个喹啉单元之间以获得扩展环体系。尽管其结构与TQ相似，但几何缩放的Enl-TQ表现出不同的寄主能力和光物理特性。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Front Cover: Enlarged-TriQuinoline (Enl-TQ): Disparity in Chemical Behaviors by Geometric Scaling of the Trimeric Quinoline Ring System (Chem. Asian J. 17/2025)

查看原文本刊更多论文

Front Cover: Enlarged-TriQuinoline (Enl-TQ): Disparity in Chemical Behaviors by Geometric Scaling of the Trimeric Quinoline Ring System (Chem. Asian J. 17/2025)

TriQuinoline (TQ), a quasi-planar cyclic quinoline trimer in a head-to-tail arrangement, strongly captures a proton and exhibits unusual physicochemical properties. In article 10.1002/asia.202500429, Naoya Kumagai and co-workers designed and synthesized its expanded analog, Enlarged-TriQuinoline (Enl-TQ), in which three alkyne units are embedded between three quinoline units to acquire an expanded ring system. Despite its structural similarity to TQ, geometrically scaled Enl-TQ displayed distinct host capability and photophysical characteristics.

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来源期刊

Chemistry - An Asian Journal 化学-化学综合

CiteScore

7.00

自引率

2.40%

发文量

535

审稿时长

1.3 months

期刊介绍： Chemistry—An Asian Journal is an international high-impact journal for chemistry in its broadest sense. The journal covers all aspects of chemistry from biochemistry through organic and inorganic chemistry to physical chemistry, including interdisciplinary topics. Chemistry—An Asian Journal publishes Full Papers, Communications, and Focus Reviews. A professional editorial team headed by Dr. Theresa Kueckmann and an Editorial Board (headed by Professor Susumu Kitagawa) ensure the highest quality of the peer-review process, the contents and the production of the journal. Chemistry—An Asian Journal is published on behalf of the Asian Chemical Editorial Society (ACES), an association of numerous Asian chemical societies, and supported by the Gesellschaft Deutscher Chemiker (GDCh, German Chemical Society), ChemPubSoc Europe, and the Federation of Asian Chemical Societies (FACS).