Gai Li, Yanhui Yu, Chongtai Wang, Daoxiong Wu, Yingjie Hua, Peng Rao, Xinlong Tian, Jing Li
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引用次数: 0
摘要
海水电解制氢作为一种可再生能源转化方式,需要克服氯化反应和耐腐蚀等问题。考虑到这些问题,设计一种高效、耐腐蚀的催化剂是至关重要的。在这里,我们开发了一种包裹在氧化铁壳内的钒掺杂磷化钴(V-CoPx@FeOOH),作为海水电解质中析氧反应(OER)的高效核壳电催化剂。特别是,V-CoPx@FeOOH催化剂在100 mA cm−2时的OER过电位为270 mV。值得注意的是,V-CoPx||V-CoPx@FeOOH能够在500 mA cm−2的碱性海水中工作1000小时以上,表现出优异的稳定性。密度泛函理论(DFT)计算表明,HER活性的增强是由于V的引入增强了Co位点与H原子之间的键合,而OER活性的优化是由于V和Fe的存在共同优化了Co位点与OOH中间体之间的键合强度。核壳结构的高效催化剂在整体水/海水电解中具有广阔的应用前景。
Core-Shell Structured V-Doped CoPx@FeOOH for Efficient Seawater Electrolysis
As a renewable energy conversion method, the hydrogen from seawater electrolysis needs to overcome problems such as chlorination reaction and corrosion resistance. Considering these questions, it is vital to design a highly efficient and corrosion-resistant catalyst. Here, we developed a vanadium-doped cobalt phosphide encapsulated within an iron oxyhydroxide shell (V-CoPx@FeOOH) as an efficient core-shell electrocatalyst for the oxygen evolution reaction (OER) in seawater electrolytes. In particular, the OER overpotential of the V-CoPx@FeOOH catalyst at 100 mA cm−2 was 270 mV. Notably, V-CoPx||V-CoPx@FeOOH was able to operate in alkaline seawater at 500 mA cm−2 for more than 1000 h, showing excellent stability. Density functional theory (DFT) calculations indicate that the enhanced HER activity is attributed to the introduction of V, which strengthens the bonding between Co sites and H atoms, and the optimized OER activity results from the presence of both V and Fe, which together optimize the bonding strength between Co sites and OOH intermediates. The highly efficient catalyst of the core-shell structure has great prospects for overall water/seawater electrolysis.
期刊介绍:
With an impact factor of 4.495 (2018), ChemCatChem is one of the premier journals in the field of catalysis. The journal provides primary research papers and critical secondary information on heterogeneous, homogeneous and bio- and nanocatalysis. The journal is well placed to strengthen cross-communication within between these communities. Its authors and readers come from academia, the chemical industry, and government laboratories across the world. It is published on behalf of Chemistry Europe, an association of 16 European chemical societies, and is supported by the German Catalysis Society.