声化学剥离AlB2成具有固有还原能力的薄层化学功能化硼罗芬

IF 3.9 3区 化学 Q2 CHEMISTRY, PHYSICAL
ChemCatChem Pub Date : 2025-07-17 DOI:10.1002/cctc.202500661
Parth Shah, Kabeer Jasuja
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引用次数: 0

摘要

超声辅助层状金属二硼化物的液相剥离已成为获得缺金属准二维纳米结构的一种有前途的途径。在这项研究中,我们发现超声波可以结合螯合来实现高产量的AlB2剥离。我们发现,在含有乙二胺四乙酸酯的溶液中超声处理AlB2晶体可以得到几乎不含金属的、几层厚的富含硼的纳米片。这些奈米片呈现皱褶的形态,并有几个晶状区域。AFM表示厚度值在1到6纳米之间,横向尺寸延伸到几微米。化学分析表明,超低铝含量(Al:B摩尔比低至0.04:2)和氧、羟基和氢化物官能团的存在,使其成为化学官能团硼苯(CFB)纳米片。我们发现,通过选择合适的ph,纳米片的产率可提高30%。我们进一步表明,这些纳米片具有固有的还原能力,可以催化金盐还原成金纳米颗粒,同时作为模板来稳定它们,纳米颗粒的生长可达10 nm。本研究为自上而下高收率合成化学功能化硼罗芬的方法奠定了基础,并展示了其作为活性还原剂的潜力。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Sonochemical Exfoliation of AlB2 into Few-Layer-Thick Chemically Functionalized Borophene with Inherent Reducing Capability

Sonochemical Exfoliation of AlB2 into Few-Layer-Thick Chemically Functionalized Borophene with Inherent Reducing Capability

Sonochemical Exfoliation of AlB2 into Few-Layer-Thick Chemically Functionalized Borophene with Inherent Reducing Capability

Sonochemical Exfoliation of AlB2 into Few-Layer-Thick Chemically Functionalized Borophene with Inherent Reducing Capability

Ultrasonication-assisted liquid-phase exfoliation of layered metal diborides has emerged as a promising path for obtaining metal-deficient quasi-2D nanostructures. In this study, we show that ultrasonication can be combined with chelation to achieve exfoliation of AlB2 in high yields. We show that ultrasonicating AlB2 crystals in a solution containing ethylenediaminetetraacetate results in nearly metal-free, few-layer-thick nanosheets rich in boron. These nanosheets exhibit crumpled morphology with several instances of crystalline regions. AFM indicates thickness values between 1 and 6 nm with lateral dimensions extending up to a few microns. Chemical analyses show ultra-low aluminum content (Al:B molar ratio as low as 0.04:2) and presence of oxy, hydroxy, and hydride functional groups, rendering these as chemically functionalized borophene (CFB) nanosheets. We found that the yield of nanosheets can be increased up to 30% by choosing an appropriate pH. We further show that these nanosheets exhibit an inherent reducing capability and can catalyze the reduction of gold salt into gold nanoparticles while simultaneously serving as templates to stabilize them, with the growth of nanoparticles up to 10 nm. This study lays the ground for top-down approaches to synthesize chemically functionalized borophene in high yield and presents its potential as an active reducing agent.

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来源期刊
ChemCatChem
ChemCatChem 化学-物理化学
CiteScore
8.10
自引率
4.40%
发文量
511
审稿时长
1.3 months
期刊介绍: With an impact factor of 4.495 (2018), ChemCatChem is one of the premier journals in the field of catalysis. The journal provides primary research papers and critical secondary information on heterogeneous, homogeneous and bio- and nanocatalysis. The journal is well placed to strengthen cross-communication within between these communities. Its authors and readers come from academia, the chemical industry, and government laboratories across the world. It is published on behalf of Chemistry Europe, an association of 16 European chemical societies, and is supported by the German Catalysis Society.
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