{"title":"一步合成具有高性能抗菌性能的绿色、柔性和可拉伸高吸水性聚合物片材：一种可扩展和可持续的溶液聚合方法","authors":"Alireza Sabzevari, Mobina Dashti, Kourosh Kabiri","doi":"10.1007/s10924-025-03670-w","DOIUrl":null,"url":null,"abstract":"<div><p>This study presents a novel one-step synthesis method for producing green, flexible, and stretchable superabsorbent polymer sheets with high-performance antibacterial properties, utilizing an energy-efficient and sustainable solution polymerization approach. Acrylic acid was partially neutralized and crosslinked with polyethylene glycol diacrylate, while ethylene glycol was a reactive solvent. Quaternary ammonium compounds (CTAB and TBAB) were incorporated as antibacterial agents, with UV initiation enabling rapid polymerization at room temperature. The resulting SAPs exhibited exceptional swelling capacities (up to 79.8 g/g in water) and mechanical properties, including elongation at break up to 294.2%, attributed to the plasticizing effects of CTAB and TBAB. Antibacterial assays demonstrated > 99.9% bacterial reduction within 1–3 h for CTAB-containing SAPs. The elimination of energy-intensive drying and surface crosslinking steps highlights the scalability and sustainability of this method. Biocompatibility tests confirmed cell viability > 84%, meeting ISO 10993–5 standards. This technology offers a promising pathway for advanced applications in hygiene products and regenerative medicine.</p><h3>Graphical abstract</h3><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":659,"journal":{"name":"Journal of Polymers and the Environment","volume":"33 10","pages":"4601 - 4615"},"PeriodicalIF":5.0000,"publicationDate":"2025-09-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"One-Step Synthesis of Green, Flexible, and Stretchable Superabsorbent Polymer Sheets with High-Performance Antibacterial Properties: A Scalable and Sustainable Solution Polymerization Approach\",\"authors\":\"Alireza Sabzevari, Mobina Dashti, Kourosh Kabiri\",\"doi\":\"10.1007/s10924-025-03670-w\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>This study presents a novel one-step synthesis method for producing green, flexible, and stretchable superabsorbent polymer sheets with high-performance antibacterial properties, utilizing an energy-efficient and sustainable solution polymerization approach. Acrylic acid was partially neutralized and crosslinked with polyethylene glycol diacrylate, while ethylene glycol was a reactive solvent. Quaternary ammonium compounds (CTAB and TBAB) were incorporated as antibacterial agents, with UV initiation enabling rapid polymerization at room temperature. The resulting SAPs exhibited exceptional swelling capacities (up to 79.8 g/g in water) and mechanical properties, including elongation at break up to 294.2%, attributed to the plasticizing effects of CTAB and TBAB. Antibacterial assays demonstrated > 99.9% bacterial reduction within 1–3 h for CTAB-containing SAPs. The elimination of energy-intensive drying and surface crosslinking steps highlights the scalability and sustainability of this method. Biocompatibility tests confirmed cell viability > 84%, meeting ISO 10993–5 standards. This technology offers a promising pathway for advanced applications in hygiene products and regenerative medicine.</p><h3>Graphical abstract</h3><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>\",\"PeriodicalId\":659,\"journal\":{\"name\":\"Journal of Polymers and the Environment\",\"volume\":\"33 10\",\"pages\":\"4601 - 4615\"},\"PeriodicalIF\":5.0000,\"publicationDate\":\"2025-09-05\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Polymers and the Environment\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s10924-025-03670-w\",\"RegionNum\":3,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"ENGINEERING, ENVIRONMENTAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Polymers and the Environment","FirstCategoryId":"5","ListUrlMain":"https://link.springer.com/article/10.1007/s10924-025-03670-w","RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"ENGINEERING, ENVIRONMENTAL","Score":null,"Total":0}
One-Step Synthesis of Green, Flexible, and Stretchable Superabsorbent Polymer Sheets with High-Performance Antibacterial Properties: A Scalable and Sustainable Solution Polymerization Approach
This study presents a novel one-step synthesis method for producing green, flexible, and stretchable superabsorbent polymer sheets with high-performance antibacterial properties, utilizing an energy-efficient and sustainable solution polymerization approach. Acrylic acid was partially neutralized and crosslinked with polyethylene glycol diacrylate, while ethylene glycol was a reactive solvent. Quaternary ammonium compounds (CTAB and TBAB) were incorporated as antibacterial agents, with UV initiation enabling rapid polymerization at room temperature. The resulting SAPs exhibited exceptional swelling capacities (up to 79.8 g/g in water) and mechanical properties, including elongation at break up to 294.2%, attributed to the plasticizing effects of CTAB and TBAB. Antibacterial assays demonstrated > 99.9% bacterial reduction within 1–3 h for CTAB-containing SAPs. The elimination of energy-intensive drying and surface crosslinking steps highlights the scalability and sustainability of this method. Biocompatibility tests confirmed cell viability > 84%, meeting ISO 10993–5 standards. This technology offers a promising pathway for advanced applications in hygiene products and regenerative medicine.
期刊介绍：
The Journal of Polymers and the Environment fills the need for an international forum in this diverse and rapidly expanding field. The journal serves a crucial role for the publication of information from a wide range of disciplines and is a central outlet for the publication of high-quality peer-reviewed original papers, review articles and short communications. The journal is intentionally interdisciplinary in regard to contributions and covers the following subjects - polymers, environmentally degradable polymers, and degradation pathways: biological, photochemical, oxidative and hydrolytic; new environmental materials: derived by chemical and biosynthetic routes; environmental blends and composites; developments in processing and reactive processing of environmental polymers; characterization of environmental materials: mechanical, physical, thermal, rheological, morphological, and others; recyclable polymers and plastics recycling environmental testing: in-laboratory simulations, outdoor exposures, and standardization of methodologies; environmental fate: end products and intermediates of biodegradation; microbiology and enzymology of polymer biodegradation; solid-waste management and public legislation specific to environmental polymers; and other related topics.
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