电纺阿拉伯胶- pvdf基灰水处理吸附剂和过滤器的生产

IF 5 3区 工程技术 Q2 ENGINEERING, ENVIRONMENTAL
Ayşenur Katırcı, Seniyecan Kahraman, Filiz Uğur Nigiz
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引用次数: 0

摘要

灰水是生活废水的主要组成部分,含有表面活性剂、染料、油脂、硝酸盐和磷酸盐等污染物。就日益严重的水资源短缺和可持续的水资源管理而言,有效处理灰水至关重要。本研究将阿拉伯胶(GA)作为一种低成本、具有生物相容性的功能性添加剂,用于提高聚偏氟乙烯(PVDF)膜的性能。采用静电纺丝法将GA以不同重量比(1-5 wt%)掺入PVDF中制备纳米纤维膜。利用扫描电镜(SEM)、红外光谱(FTIR)、热重分析仪(TGA)和差热分析(DSC)对膜进行了表征,以评估其形态、化学和热性能。SEM分析显示纤维分布均匀,无起球,GA的加入使纤维直径略有减小。热分析证实了GA改善了热稳定性和改变了降解行为。结果表明,随着GA的加入,接触角减小,亲水性增强。在3 wt% GA时,抗拉强度由6 MPa提高到12.5 MPa。利用响应面法(RSM)对亚甲基蓝(MB)、石油、微塑料(MP)和阴离子表面活性剂(LAS)的吸附实验进行了优化。过滤试验表明,MB的截留率为99%,油的截留率为87%,MP的截留率为100%。当总重量为2 wt%时,LAS的拒绝效率从26%提高到67.63%。然而,吸附性能仍然有限。结果表明,所研制的PVDF/GA膜在灰水过滤处理中具有很高的应用潜力,该技术可应用于类似类型的废水。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Electrospun Gum Arabic-Pvdf Based Adsorbent and Filter Production for Gray Water Treatment

Electrospun Gum Arabic-Pvdf Based Adsorbent and Filter Production for Gray Water Treatment

Electrospun Gum Arabic-Pvdf Based Adsorbent and Filter Production for Gray Water Treatment

Gray water is a major component of domestic wastewater, containing pollutants such as surfactants, dyes, oils, nitrates, and phosphates. Effective treatment of gray water is critical in terms of increasing water scarcity and sustainable water management. In this study, gum arabic (GA) was used as a low-cost, biocompatible, and functional additive to enhance the properties of polyvinylidene fluoride (PVDF) membranes. Electrospinning was employed to fabricate nanofiber membranes by incorporating GA into PVDF at different weight ratios (1–5 wt%). The membranes were characterized using SEM, FTIR, TGA, and DSC to assess morphological, chemical, and thermal properties. SEM analysis revealed uniform fiber distribution without pilling, and GA addition slightly reduced fiber diameters. Thermal analysis confirmed improved thermal stability and altered degradation behavior with GA. Results showed that the contact angle decreased with GA addition, indicating increased hydrophilicity. Tensile strength increased from 6 MPa to 12.5 MPa at 3 wt% GA. Adsorption experiments for methylene blue (MB), oil, microplastics (MP), and anionic surfactants (LAS) were optimized using response surface methodology (RSM). Filtration tests demonstrated rejection rates of 99% for MB, 87% for oil, and 100% for MP. LAS rejection efficiency increased from 26 to 67.63% at 2 wt% GA. However, adsorption performance remained limited. The results show that the developed PVDF/GA membranes have high potential in the filtration-based treatment of gray water and that this technology can be applied to similar types of wastewater.

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来源期刊
Journal of Polymers and the Environment
Journal of Polymers and the Environment 工程技术-高分子科学
CiteScore
9.50
自引率
7.50%
发文量
297
审稿时长
9 months
期刊介绍: The Journal of Polymers and the Environment fills the need for an international forum in this diverse and rapidly expanding field. The journal serves a crucial role for the publication of information from a wide range of disciplines and is a central outlet for the publication of high-quality peer-reviewed original papers, review articles and short communications. The journal is intentionally interdisciplinary in regard to contributions and covers the following subjects - polymers, environmentally degradable polymers, and degradation pathways: biological, photochemical, oxidative and hydrolytic; new environmental materials: derived by chemical and biosynthetic routes; environmental blends and composites; developments in processing and reactive processing of environmental polymers; characterization of environmental materials: mechanical, physical, thermal, rheological, morphological, and others; recyclable polymers and plastics recycling environmental testing: in-laboratory simulations, outdoor exposures, and standardization of methodologies; environmental fate: end products and intermediates of biodegradation; microbiology and enzymology of polymer biodegradation; solid-waste management and public legislation specific to environmental polymers; and other related topics.
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