{"title":"合成α-V2O5纳米粒子,并探索其在氨气氛中作为气体传感器的性能","authors":"Surya Prakash Singh , Satyam Tripathi , Atul Kumar , Vijay Prajapati , Jyoti Yadav , Ravindra Kumar Rawat , Pratima Chauhan","doi":"10.1016/j.physb.2025.417782","DOIUrl":null,"url":null,"abstract":"<div><div>Metal oxide semiconductor (MOS) chemiresistive sensors are effective for detecting ammonia (NH<sub>3</sub>), but need high temperatures and have low sensitivity. This work investigates hydrothermally produced α-V<sub>2</sub>O<sub>5</sub> irregular nanodiscs as a possible NH<sub>3</sub> sensor for ambient conditions. XRD, UV–vis spectroscopy, FE-SEM, HR-TEM, EDX mapping, and FT-IR were used to identify the material's structure, morphology, composition, and functional groups. The crystallite size (∼27 nm) and band gap (3.4 eV) were determined using the Debye-Scherrer and Tauc equations, respectively, suggesting excellent electronic characteristics. The sensor was tested at 50–500 ppm NH<sub>3</sub> concentrations and shown great sensitivity with quick response (22 s) and recovery (17 s). Importantly, performance remained consistent across various relative humidity levels, suggesting resilience to environmental conditions. These findings suggest that α-V<sub>2</sub>O<sub>5</sub> nanodiscs are potentially effective for current time ammonia detection at ambient temperature.</div></div>","PeriodicalId":20116,"journal":{"name":"Physica B-condensed Matter","volume":"717 ","pages":"Article 417782"},"PeriodicalIF":2.8000,"publicationDate":"2025-09-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Synthesized α-V2O5 nanoparticles and explored their performance as gas sensors in an ammonia atmosphere\",\"authors\":\"Surya Prakash Singh , Satyam Tripathi , Atul Kumar , Vijay Prajapati , Jyoti Yadav , Ravindra Kumar Rawat , Pratima Chauhan\",\"doi\":\"10.1016/j.physb.2025.417782\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Metal oxide semiconductor (MOS) chemiresistive sensors are effective for detecting ammonia (NH<sub>3</sub>), but need high temperatures and have low sensitivity. This work investigates hydrothermally produced α-V<sub>2</sub>O<sub>5</sub> irregular nanodiscs as a possible NH<sub>3</sub> sensor for ambient conditions. XRD, UV–vis spectroscopy, FE-SEM, HR-TEM, EDX mapping, and FT-IR were used to identify the material's structure, morphology, composition, and functional groups. The crystallite size (∼27 nm) and band gap (3.4 eV) were determined using the Debye-Scherrer and Tauc equations, respectively, suggesting excellent electronic characteristics. The sensor was tested at 50–500 ppm NH<sub>3</sub> concentrations and shown great sensitivity with quick response (22 s) and recovery (17 s). Importantly, performance remained consistent across various relative humidity levels, suggesting resilience to environmental conditions. These findings suggest that α-V<sub>2</sub>O<sub>5</sub> nanodiscs are potentially effective for current time ammonia detection at ambient temperature.</div></div>\",\"PeriodicalId\":20116,\"journal\":{\"name\":\"Physica B-condensed Matter\",\"volume\":\"717 \",\"pages\":\"Article 417782\"},\"PeriodicalIF\":2.8000,\"publicationDate\":\"2025-09-11\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Physica B-condensed Matter\",\"FirstCategoryId\":\"101\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0921452625008993\",\"RegionNum\":3,\"RegionCategory\":\"物理与天体物理\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"PHYSICS, CONDENSED MATTER\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Physica B-condensed Matter","FirstCategoryId":"101","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0921452625008993","RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"PHYSICS, CONDENSED MATTER","Score":null,"Total":0}
Synthesized α-V2O5 nanoparticles and explored their performance as gas sensors in an ammonia atmosphere
Metal oxide semiconductor (MOS) chemiresistive sensors are effective for detecting ammonia (NH3), but need high temperatures and have low sensitivity. This work investigates hydrothermally produced α-V2O5 irregular nanodiscs as a possible NH3 sensor for ambient conditions. XRD, UV–vis spectroscopy, FE-SEM, HR-TEM, EDX mapping, and FT-IR were used to identify the material's structure, morphology, composition, and functional groups. The crystallite size (∼27 nm) and band gap (3.4 eV) were determined using the Debye-Scherrer and Tauc equations, respectively, suggesting excellent electronic characteristics. The sensor was tested at 50–500 ppm NH3 concentrations and shown great sensitivity with quick response (22 s) and recovery (17 s). Importantly, performance remained consistent across various relative humidity levels, suggesting resilience to environmental conditions. These findings suggest that α-V2O5 nanodiscs are potentially effective for current time ammonia detection at ambient temperature.
期刊介绍:
Physica B: Condensed Matter comprises all condensed matter and material physics that involve theoretical, computational and experimental work.
Papers should contain further developments and a proper discussion on the physics of experimental or theoretical results in one of the following areas:
-Magnetism
-Materials physics
-Nanostructures and nanomaterials
-Optics and optical materials
-Quantum materials
-Semiconductors
-Strongly correlated systems
-Superconductivity
-Surfaces and interfaces