{"title":"用连续波腔内泵-斯托克斯光束实现高灵敏度、高分辨率受激拉曼光声光谱","authors":"Qinxue Nie, Guanda Lyu, Chao Wei, Wei Ren","doi":"10.1002/lpor.202501645","DOIUrl":null,"url":null,"abstract":"Raman spectroscopy is essential for chemical analysis by offering non‐invasive and selective detection of molecular vibrations. However, weak Raman signals from gas‐phase species pose significant challenges to detection sensitivity, even with high‐power laser sources. Here, cavity‐enhanced stimulated Raman photoacoustic spectroscopy is reported using continuous‐wave mW‐level near‐infrared lasers, achieving remarkable sensitivity and resolution. This approach involves coupling the pump and Stokes beams into a high‐finesse (>220 000) Fabry‐Perot cavity, enhancing the intracavity power of both lasers by four orders of magnitude. By modulating the light intensity of the pump laser, the stimulated Raman scattering‐induced acoustic waves are sensitively detected by a microphone. Additionally, a difference frequency scanning method is introduced that resolves narrow‐linewidth Raman transitions by tuning the length of the dual‐laser‐locked optical cavity. The effectiveness of the method is validated by measuring the Raman rotational transition <jats:italic>S</jats:italic><jats:sub>0</jats:sub>(0) of hydrogen, achieving a minimum detection limit of 0.5 ppm with a 200‐s averaging time. This study establishes a new Raman spectroscopic platform for high‐sensitivity, high‐resolution molecular spectroscopy, with promising applications in chemical analysis and trace gas sensing.","PeriodicalId":204,"journal":{"name":"Laser & Photonics Reviews","volume":"28 1","pages":""},"PeriodicalIF":10.0000,"publicationDate":"2025-09-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"High‐Sensitivity, High‐Resolution Stimulated Raman Photoacoustic Spectroscopy Enabled by Continuous‐Wave Intracavity Pump‐Stokes Beams\",\"authors\":\"Qinxue Nie, Guanda Lyu, Chao Wei, Wei Ren\",\"doi\":\"10.1002/lpor.202501645\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Raman spectroscopy is essential for chemical analysis by offering non‐invasive and selective detection of molecular vibrations. However, weak Raman signals from gas‐phase species pose significant challenges to detection sensitivity, even with high‐power laser sources. Here, cavity‐enhanced stimulated Raman photoacoustic spectroscopy is reported using continuous‐wave mW‐level near‐infrared lasers, achieving remarkable sensitivity and resolution. This approach involves coupling the pump and Stokes beams into a high‐finesse (>220 000) Fabry‐Perot cavity, enhancing the intracavity power of both lasers by four orders of magnitude. By modulating the light intensity of the pump laser, the stimulated Raman scattering‐induced acoustic waves are sensitively detected by a microphone. Additionally, a difference frequency scanning method is introduced that resolves narrow‐linewidth Raman transitions by tuning the length of the dual‐laser‐locked optical cavity. The effectiveness of the method is validated by measuring the Raman rotational transition <jats:italic>S</jats:italic><jats:sub>0</jats:sub>(0) of hydrogen, achieving a minimum detection limit of 0.5 ppm with a 200‐s averaging time. This study establishes a new Raman spectroscopic platform for high‐sensitivity, high‐resolution molecular spectroscopy, with promising applications in chemical analysis and trace gas sensing.\",\"PeriodicalId\":204,\"journal\":{\"name\":\"Laser & Photonics Reviews\",\"volume\":\"28 1\",\"pages\":\"\"},\"PeriodicalIF\":10.0000,\"publicationDate\":\"2025-09-19\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Laser & Photonics Reviews\",\"FirstCategoryId\":\"101\",\"ListUrlMain\":\"https://doi.org/10.1002/lpor.202501645\",\"RegionNum\":1,\"RegionCategory\":\"物理与天体物理\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"OPTICS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Laser & Photonics Reviews","FirstCategoryId":"101","ListUrlMain":"https://doi.org/10.1002/lpor.202501645","RegionNum":1,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"OPTICS","Score":null,"Total":0}
Raman spectroscopy is essential for chemical analysis by offering non‐invasive and selective detection of molecular vibrations. However, weak Raman signals from gas‐phase species pose significant challenges to detection sensitivity, even with high‐power laser sources. Here, cavity‐enhanced stimulated Raman photoacoustic spectroscopy is reported using continuous‐wave mW‐level near‐infrared lasers, achieving remarkable sensitivity and resolution. This approach involves coupling the pump and Stokes beams into a high‐finesse (>220 000) Fabry‐Perot cavity, enhancing the intracavity power of both lasers by four orders of magnitude. By modulating the light intensity of the pump laser, the stimulated Raman scattering‐induced acoustic waves are sensitively detected by a microphone. Additionally, a difference frequency scanning method is introduced that resolves narrow‐linewidth Raman transitions by tuning the length of the dual‐laser‐locked optical cavity. The effectiveness of the method is validated by measuring the Raman rotational transition S0(0) of hydrogen, achieving a minimum detection limit of 0.5 ppm with a 200‐s averaging time. This study establishes a new Raman spectroscopic platform for high‐sensitivity, high‐resolution molecular spectroscopy, with promising applications in chemical analysis and trace gas sensing.
期刊介绍:
Laser & Photonics Reviews is a reputable journal that publishes high-quality Reviews, original Research Articles, and Perspectives in the field of photonics and optics. It covers both theoretical and experimental aspects, including recent groundbreaking research, specific advancements, and innovative applications.
As evidence of its impact and recognition, Laser & Photonics Reviews boasts a remarkable 2022 Impact Factor of 11.0, according to the Journal Citation Reports from Clarivate Analytics (2023). Moreover, it holds impressive rankings in the InCites Journal Citation Reports: in 2021, it was ranked 6th out of 101 in the field of Optics, 15th out of 161 in Applied Physics, and 12th out of 69 in Condensed Matter Physics.
The journal uses the ISSN numbers 1863-8880 for print and 1863-8899 for online publications.