离子液体微波辅助萃取绿原酸的研究

Ramalakshmi Kulathooran, Subhapriya Pushparaju, Dhanapal Venkatachalam, Divyashree Jangam Seshagiri, Katyaini Panday and Jagan Mohan Rao Lingamallu
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引用次数: 0

摘要

采用Box-Behnken响应面法(BRSM),利用亲水性离子液体1-丁基-3-甲基咪唑四氟硼酸盐[BMIM][BF4]微波辅助萃取(MAE),从绿咖啡豆中提取绿原酸。绿原酸的产率是离子液体浓度(M)、温度(℃)、功率(W)和时间(min)四个自变量的函数。通过对响应面三维曲面进行分析,利用Design Expert软件求解回归模型方程,确定了最优工艺条件。结果表明,提取温度为90℃,微波功率为800 W,离子液体浓度([BMIM][BF4])为1 M,提取时间为3 min,是提取绿原酸的最佳条件。在此条件下(IL-MAE)绿原酸提取率最高为7.31%,高于绿咖啡豆中绿原酸的常规提取方法(6.0%)。绿原酸的异构体被发现在传统和离子液体微波辅助萃取的绿咖啡豆中是相似的。研究进一步验证了该方法的可靠性,表明(BMIM)(BF4)基MAE对绿原酸的提取是有效的。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Ionic liquid-based microwave-assisted extraction of chlorogenic acid from green coffee beans

Ionic liquid-based microwave-assisted extraction of chlorogenic acid from green coffee beans

Microwave-assisted extraction (MAE) utilizing a hydrophilic ionic liquid, 1-butyl-3-methylimidazolium tetrafluoroborate [BMIM)][BF4], was employed to extract chlorogenic acid from green coffee beans using Box–Behnken response surface methodology (BRSM). The yield of chlorogenic acid was considered as a function of four independent variables, namely ionic liquid concentration (M), temperature (°C), wattage (W) and time (min). By analyzing a three-dimensional surface plot of the response surface and solving the regression model equation with Design Expert software, the optimal process conditions were determined. The result shows that an extraction temperature of 90 °C, microwave power of 800 W, ionic liquid concentration ([BMIM][BF4]) of 1 M and extraction time of 3 min were the best conditions for the extraction of chlorogenic acid. Under these conditions (IL-MAE), the maximum observed yield of chlorogenic acid was found to be 7.31%, which was higher than the conventional method of chlorogenic acid extraction (6.0%) from green coffee beans. The isomers of chlorogenic acids were found to be similar in both the conventional and ionic liquid-based microwave-assisted extracts isolated from green coffee beans. Further confirmation of the method's reliability was provided by the study, indicating that (BMIM)(BF4)-based MAE is effective for extracting chlorogenic acid from green coffee.

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