{"title":"快速充电锂离子电池的热材料协同作用","authors":"Wen-Ke Zhang, Xiao-Guang Yang, Chao-Yang Wang","doi":"10.1021/acsenergylett.5c02528","DOIUrl":null,"url":null,"abstract":"Fast charging of energy-dense lithium-ion batteries (LIBs) remains a formidable challenge, primarily constrained by lithium plating─a hazardous degradation mode exacerbated by low temperatures and thick electrode architectures. Preventing plating requires materials with high-rate capabilities of charge-transfer and ion-transport; however, such materials often suffer from poor thermal or electrochemical stability, resulting in an inherent activity–stability trade-off. This Perspective examines the origins of this dilemma and proposes that temperature─traditionally viewed as a degradation stressor─can be harnessed as a tool. We highlight how asymmetric temperature modulation enables brief high-temperature operation to enhance reaction kinetics while limiting long-term degradation, shifting the paradigm from passive thermal protection to active thermal control. Leveraging this, we propose a thermal–materials synergistic strategy centered on rapid temperature modulation and complemented by materials designed for high-temperature resilience. These advances offer a blueprint for enabling safe, reliable, and rapid charging of energy-dense cells across diverse climates.","PeriodicalId":16,"journal":{"name":"ACS Energy Letters ","volume":"214 1","pages":""},"PeriodicalIF":18.2000,"publicationDate":"2025-09-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Thermal–Materials Synergy for Fast-Charging Lithium-Ion Batteries\",\"authors\":\"Wen-Ke Zhang, Xiao-Guang Yang, Chao-Yang Wang\",\"doi\":\"10.1021/acsenergylett.5c02528\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Fast charging of energy-dense lithium-ion batteries (LIBs) remains a formidable challenge, primarily constrained by lithium plating─a hazardous degradation mode exacerbated by low temperatures and thick electrode architectures. Preventing plating requires materials with high-rate capabilities of charge-transfer and ion-transport; however, such materials often suffer from poor thermal or electrochemical stability, resulting in an inherent activity–stability trade-off. This Perspective examines the origins of this dilemma and proposes that temperature─traditionally viewed as a degradation stressor─can be harnessed as a tool. We highlight how asymmetric temperature modulation enables brief high-temperature operation to enhance reaction kinetics while limiting long-term degradation, shifting the paradigm from passive thermal protection to active thermal control. Leveraging this, we propose a thermal–materials synergistic strategy centered on rapid temperature modulation and complemented by materials designed for high-temperature resilience. These advances offer a blueprint for enabling safe, reliable, and rapid charging of energy-dense cells across diverse climates.\",\"PeriodicalId\":16,\"journal\":{\"name\":\"ACS Energy Letters \",\"volume\":\"214 1\",\"pages\":\"\"},\"PeriodicalIF\":18.2000,\"publicationDate\":\"2025-09-17\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"ACS Energy Letters \",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://doi.org/10.1021/acsenergylett.5c02528\",\"RegionNum\":1,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"ACS Energy Letters ","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.1021/acsenergylett.5c02528","RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
Thermal–Materials Synergy for Fast-Charging Lithium-Ion Batteries
Fast charging of energy-dense lithium-ion batteries (LIBs) remains a formidable challenge, primarily constrained by lithium plating─a hazardous degradation mode exacerbated by low temperatures and thick electrode architectures. Preventing plating requires materials with high-rate capabilities of charge-transfer and ion-transport; however, such materials often suffer from poor thermal or electrochemical stability, resulting in an inherent activity–stability trade-off. This Perspective examines the origins of this dilemma and proposes that temperature─traditionally viewed as a degradation stressor─can be harnessed as a tool. We highlight how asymmetric temperature modulation enables brief high-temperature operation to enhance reaction kinetics while limiting long-term degradation, shifting the paradigm from passive thermal protection to active thermal control. Leveraging this, we propose a thermal–materials synergistic strategy centered on rapid temperature modulation and complemented by materials designed for high-temperature resilience. These advances offer a blueprint for enabling safe, reliable, and rapid charging of energy-dense cells across diverse climates.
ACS Energy Letters Energy-Renewable Energy, Sustainability and the Environment
CiteScore
31.20
自引率
5.00%
发文量
469
审稿时长
1 months
期刊介绍:
ACS Energy Letters is a monthly journal that publishes papers reporting new scientific advances in energy research. The journal focuses on topics that are of interest to scientists working in the fundamental and applied sciences. Rapid publication is a central criterion for acceptance, and the journal is known for its quick publication times, with an average of 4-6 weeks from submission to web publication in As Soon As Publishable format.
ACS Energy Letters is ranked as the number one journal in the Web of Science Electrochemistry category. It also ranks within the top 10 journals for Physical Chemistry, Energy & Fuels, and Nanoscience & Nanotechnology.
The journal offers several types of articles, including Letters, Energy Express, Perspectives, Reviews, Editorials, Viewpoints and Energy Focus. Additionally, authors have the option to submit videos that summarize or support the information presented in a Perspective or Review article, which can be highlighted on the journal's website. ACS Energy Letters is abstracted and indexed in Chemical Abstracts Service/SciFinder, EBSCO-summon, PubMed, Web of Science, Scopus and Portico.