钠电池碳工程:连接材料设计和混合系统创新的多用途架构

IF 39 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY
Qianxiong Wen, Chuangchuang Li, Qinghang Chen, Pandeng Zhao, Chun Wu, Xingqiao Wu, Shu-Lei Chou
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引用次数: 0

摘要

钠(Na)电池正在成为可持续的能源存储解决方案,但其性能受到诸如离子动力学缓慢、枝晶形成和界面不相容等内在挑战的阻碍。碳基材料具有高度可调的物理化学性质,提供了多种功能,可以解决各种钠电池系统的这些限制。在这篇综述中,我们首先探讨了碳材料在四种钠电池中的多作用工程。然后,在功能-性能矩阵中建立了碳的结构和化学性质(包括晶格间距、缺陷密度、石墨有序度和孔隙层次)与电化学性能的相关性,以指导特定电池设计的材料选择。在这些见解的基础上,我们提出了一种混合钠电池范例,利用碳的双重能力:插层驱动的Na+存储用于面向能源的应用,缺陷引导的Na沉积用于面向电力的需求。该系统集成了三种自适应运行模式:标准、增强和生存模式,为从消费电子产品到电网存储和极端环境的应用提供了特定场景的优化。最后,我们确定了碳工程中的关键挑战,例如模式切换过程中的动态界面演变和混合系统中电位驱动的相变。通过将多尺度碳设计与混合电池电化学相结合,本文为碳工程开发具有广泛应用兼容性的钠电池提供了路线图,解决了可持续能源存储的基础和技术挑战。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Carbon engineering for sodium batteries: multi-role architectures bridging material design and hybrid system innovation

Carbon engineering for sodium batteries: multi-role architectures bridging material design and hybrid system innovation
Sodium (Na) batteries are emerging as sustainable energy storage solutions, but their performance is hindered by intrinsic challenges such as sluggish ion kinetics, dendrite formation, and interfacial incompatibility. Carbon-based materials, with their highly tunable physicochemical properties, offer versatile functionalities to address these limitations across various Na battery systems. In this review, we first explore the multi-role engineering of carbon materials in four Na battery types. Then, the correlation of carbon's structural and chemical properties (including lattice spacing, defect density, graphitic order, and pore hierarchy) with electrochemical performance was established in a functionality–performance matrix to guide material selection for specific battery designs. Building on these insights, we propose a hybrid Na battery paradigm that leverages carbon's dual capabilities: intercalation-driven Na+ storage for energy-oriented applications and defect-guided Na deposition for power-oriented needs. This system integrates three adaptive operation modes: standard, boost, and survival, enabling scenario-specific optimization for applications ranging from consumer electronics to grid storage and extreme environments. Finally, we identify critical challenges in carbon engineering, such as dynamic interface evolution during mode-switching and potential-driven phase transitions in hybrid systems. By bridging multi-scale carbon design with hybrid battery electrochemistry, this review provides a roadmap for developing Na batteries with broad application compatibility by carbon engineering, addressing both fundamental and technological challenges in sustainable energy storage.
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来源期刊
Chemical Society Reviews
Chemical Society Reviews 化学-化学综合
CiteScore
80.80
自引率
1.10%
发文量
345
审稿时长
6.0 months
期刊介绍: Chemical Society Reviews is published by: Royal Society of Chemistry. Focus: Review articles on topics of current interest in chemistry; Predecessors: Quarterly Reviews, Chemical Society (1947–1971); Current title: Since 1971; Impact factor: 60.615 (2021); Themed issues: Occasional themed issues on new and emerging areas of research in the chemical sciences
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