碳纳米管修饰PA6/PA12 75/25导电聚合物复合材料的多功能性能

IF 4.6 3区 材料科学 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY
T. Arnal, P. Eisenberg, A. Ares-Pernas, C. Bernal, M. J. Abad
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引用次数: 0

摘要

导电聚合物复合材料(cpc)将聚合物的轻质和可加工特性与金属的导电性结合在一起,使其适用于包括电磁干扰屏蔽和传感器在内的一系列应用。本研究研究了聚酰胺6/聚酰胺12 (PA6/PA12)(75/25)聚酰胺6/PA12填充多壁碳纳米管(MWCNTs)的多功能特性。目前的研究重点是纳米复合材料的形态、流变、热学和电学性能。采用双螺杆挤出技术将MWCNTs掺入PA6/PA12共混物中,并采用压缩成型技术获得纳米复合材料。研究了不同的MWCNT负载,以优化导电填料网络的分散和连通性。扫描电镜形态学分析显示,随着MWCNT含量的增加,MWCNT的结构发生了显著变化,从海岛形态转变为更相互连接的网络。差示扫描量热法提供了对热行为的深入了解,显示了熔炼和结晶行为以及结晶度随填料加载的变化。流变学评估表明,复合粘度、储存模量和损失模量随MWCNT含量的不同而变化。利用Van der Pauw技术进行的电学测量强调了纳米复合材料导电性的提高。这些发现强调了PA6/PA12/MWCNT纳米复合材料在干扰屏蔽和传感器等高级应用方面的潜力。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Tailoring the Multifunctional Properties of PA6/PA12 75/25 Conductive Polymer Composites With Carbon Nanotubes

Tailoring the Multifunctional Properties of PA6/PA12 75/25 Conductive Polymer Composites With Carbon Nanotubes

Conductive polymer composites (CPCs) offer a unique combination of the lightweight and processable nature of polymers with the electrical conductivity of metals, making them suitable for a range of applications, including electromagnetic interference shielding and sensors. This study investigates the multifunctional properties of polyamide 6/polyamide 12 (PA6/PA12) (75/25) CPCs filled with multi-walled carbon nanotubes (MWCNTs). The present research focuses on the morphological, rheological, thermal, and electrical properties of nanocomposites. The incorporation of MWCNTs into the PA6/PA12 blend is achieved using twin-screw extrusion, and compression molding is used to obtain nanocomposites. Different MWCNT loadings are examined to optimize the dispersion and connectivity of the conductive filler network. Morphological analysis via scanning electron microscopy reveals significant structural changes with increasing MWCNT content, changing from a sea-island morphology to a more interconnected network. Differential scanning calorimetry provides insights into the thermal behavior, showing changes in melting and crystallization behavior as well as crystallinity degree with filler loading. Rheological assessments demonstrated variations in complex viscosity, storage modulus, and loss modulus with different MWCNT contents. Electrical measurements using the Van der Pauw technique highlightes the improved conductivity of the nanocomposites. The findings underscore the potential of PA6/PA12/MWCNT nanocomposites for advanced applications such as interference shielding and sensors.

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来源期刊
Macromolecular Materials and Engineering
Macromolecular Materials and Engineering 工程技术-材料科学:综合
CiteScore
7.30
自引率
5.10%
发文量
328
审稿时长
1.6 months
期刊介绍: Macromolecular Materials and Engineering is the high-quality polymer science journal dedicated to the design, modification, characterization, processing and application of advanced polymeric materials, including membranes, sensors, sustainability, composites, fibers, foams, 3D printing, actuators as well as energy and electronic applications. Macromolecular Materials and Engineering is among the top journals publishing original research in polymer science. The journal presents strictly peer-reviewed Research Articles, Reviews, Perspectives and Comments. ISSN: 1438-7492 (print). 1439-2054 (online). Readership:Polymer scientists, chemists, physicists, materials scientists, engineers Abstracting and Indexing Information: CAS: Chemical Abstracts Service (ACS) CCR Database (Clarivate Analytics) Chemical Abstracts Service/SciFinder (ACS) Chemistry Server Reaction Center (Clarivate Analytics) ChemWeb (ChemIndustry.com) Chimica Database (Elsevier) COMPENDEX (Elsevier) Current Contents: Physical, Chemical & Earth Sciences (Clarivate Analytics) Directory of Open Access Journals (DOAJ) INSPEC (IET) Journal Citation Reports/Science Edition (Clarivate Analytics) Materials Science & Engineering Database (ProQuest) PASCAL Database (INIST/CNRS) Polymer Library (iSmithers RAPRA) Reaction Citation Index (Clarivate Analytics) Science Citation Index (Clarivate Analytics) Science Citation Index Expanded (Clarivate Analytics) SciTech Premium Collection (ProQuest) SCOPUS (Elsevier) Technology Collection (ProQuest) Web of Science (Clarivate Analytics)
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