聚光太阳能热应用中高吸收率陶瓷涂层在热循环暴露过程中的微观结构稳定性

IF 6 2区 工程技术 Q2 ENERGY & FUELS
C. Oskay , M. Bik , C. Grimme , E. White , S. Auler , M. Kerbstadt , G. Alkan , P. Mechnich , G. San Vicente , A. Morales , F. Sutter , D. Benitez , A.C. González Alves , N. Benameur , S. Merlin , M. Galetz
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引用次数: 0

摘要

将尖晶石涂层沉积在富含fe2o3的陶瓷颗粒上,研究其显微结构稳定性和光学性能,在1000°C的热循环氧化长达3000小时。随着时间的推移,Cu-Cr和Cu-Mn-Co尖晶石涂层的太阳吸收率保持在一个非常高的水平(约97%)。而Cu-Mn-Fe尖晶石涂层在暴露初期的太阳吸收率显著增加,此后的吸收率稳定在95%左右。显微组织研究,结合EPMA分析和拉曼光谱相映射,揭示了尖晶石与基体之间的高温相互扩散导致涂层形成了由不同尖晶石相组成的复杂显微结构。这种交换反应在热循环暴露期间继续进行,但它们并不影响颗粒基CST应用的涂层的长期太阳吸收率。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Microstructural stability of coatings with high solar absorptance for ceramic particles during thermocyclic exposure for concentrated solar thermal applications
Spinel-based coatings were deposited on Fe2O3-rich ceramic particles to investigate their microstructural stability and optical properties during thermocyclic oxidation at 1000 °C for up to 3000 h. The solar absorptance over time remained stable at a very high level (around 97 %) for the Cu-Cr and Cu-Mn-Co spinel coatings, whereas the Cu-Mn-Fe spinel coating showed a significant increase in its solar absorptance during early stages of exposure and thereafter maintained a stable behavior around 95 %. The microstructural investigations, coupling EPMA analysis with phase mapping via Raman spectroscopy, revealed the formation of complex microstructures consisting of different spinel phases for the coatings due to high temperature interdiffusion between the spinels and the substrate, respectively. Such exchange reactions continued during thermocyclic exposure, but they did not affect the highly promising long-term solar absorptance of the coatings for particle-based CST applications.
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来源期刊
Solar Energy
Solar Energy 工程技术-能源与燃料
CiteScore
13.90
自引率
9.00%
发文量
0
审稿时长
47 days
期刊介绍: Solar Energy welcomes manuscripts presenting information not previously published in journals on any aspect of solar energy research, development, application, measurement or policy. The term "solar energy" in this context includes the indirect uses such as wind energy and biomass
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