C. Oskay , M. Bik , C. Grimme , E. White , S. Auler , M. Kerbstadt , G. Alkan , P. Mechnich , G. San Vicente , A. Morales , F. Sutter , D. Benitez , A.C. González Alves , N. Benameur , S. Merlin , M. Galetz
{"title":"聚光太阳能热应用中高吸收率陶瓷涂层在热循环暴露过程中的微观结构稳定性","authors":"C. Oskay , M. Bik , C. Grimme , E. White , S. Auler , M. Kerbstadt , G. Alkan , P. Mechnich , G. San Vicente , A. Morales , F. Sutter , D. Benitez , A.C. González Alves , N. Benameur , S. Merlin , M. Galetz","doi":"10.1016/j.solener.2025.113961","DOIUrl":null,"url":null,"abstract":"<div><div>Spinel-based coatings were deposited on Fe<sub>2</sub>O<sub>3</sub>-rich ceramic particles to investigate their microstructural stability and optical properties during thermocyclic oxidation at 1000 °C for up to 3000 h. The solar absorptance over time remained stable at a very high level (around 97 %) for the Cu-Cr and Cu-Mn-Co spinel coatings, whereas the Cu-Mn-Fe spinel coating showed a significant increase in its solar absorptance during early stages of exposure and thereafter maintained a stable behavior around 95 %. The microstructural investigations, coupling EPMA analysis with phase mapping via Raman spectroscopy, revealed the formation of complex microstructures consisting of different spinel phases for the coatings due to high temperature interdiffusion between the spinels and the substrate, respectively. Such exchange reactions continued during thermocyclic exposure, but they did not affect the highly promising long-term solar absorptance of the coatings for particle-based CST applications.</div></div>","PeriodicalId":428,"journal":{"name":"Solar Energy","volume":"301 ","pages":"Article 113961"},"PeriodicalIF":6.0000,"publicationDate":"2025-09-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Microstructural stability of coatings with high solar absorptance for ceramic particles during thermocyclic exposure for concentrated solar thermal applications\",\"authors\":\"C. Oskay , M. Bik , C. Grimme , E. White , S. Auler , M. Kerbstadt , G. Alkan , P. Mechnich , G. San Vicente , A. Morales , F. Sutter , D. Benitez , A.C. González Alves , N. Benameur , S. Merlin , M. Galetz\",\"doi\":\"10.1016/j.solener.2025.113961\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Spinel-based coatings were deposited on Fe<sub>2</sub>O<sub>3</sub>-rich ceramic particles to investigate their microstructural stability and optical properties during thermocyclic oxidation at 1000 °C for up to 3000 h. The solar absorptance over time remained stable at a very high level (around 97 %) for the Cu-Cr and Cu-Mn-Co spinel coatings, whereas the Cu-Mn-Fe spinel coating showed a significant increase in its solar absorptance during early stages of exposure and thereafter maintained a stable behavior around 95 %. The microstructural investigations, coupling EPMA analysis with phase mapping via Raman spectroscopy, revealed the formation of complex microstructures consisting of different spinel phases for the coatings due to high temperature interdiffusion between the spinels and the substrate, respectively. Such exchange reactions continued during thermocyclic exposure, but they did not affect the highly promising long-term solar absorptance of the coatings for particle-based CST applications.</div></div>\",\"PeriodicalId\":428,\"journal\":{\"name\":\"Solar Energy\",\"volume\":\"301 \",\"pages\":\"Article 113961\"},\"PeriodicalIF\":6.0000,\"publicationDate\":\"2025-09-15\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Solar Energy\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0038092X25007248\",\"RegionNum\":2,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"ENERGY & FUELS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Solar Energy","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0038092X25007248","RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"ENERGY & FUELS","Score":null,"Total":0}
Microstructural stability of coatings with high solar absorptance for ceramic particles during thermocyclic exposure for concentrated solar thermal applications
Spinel-based coatings were deposited on Fe2O3-rich ceramic particles to investigate their microstructural stability and optical properties during thermocyclic oxidation at 1000 °C for up to 3000 h. The solar absorptance over time remained stable at a very high level (around 97 %) for the Cu-Cr and Cu-Mn-Co spinel coatings, whereas the Cu-Mn-Fe spinel coating showed a significant increase in its solar absorptance during early stages of exposure and thereafter maintained a stable behavior around 95 %. The microstructural investigations, coupling EPMA analysis with phase mapping via Raman spectroscopy, revealed the formation of complex microstructures consisting of different spinel phases for the coatings due to high temperature interdiffusion between the spinels and the substrate, respectively. Such exchange reactions continued during thermocyclic exposure, but they did not affect the highly promising long-term solar absorptance of the coatings for particle-based CST applications.
期刊介绍:
Solar Energy welcomes manuscripts presenting information not previously published in journals on any aspect of solar energy research, development, application, measurement or policy. The term "solar energy" in this context includes the indirect uses such as wind energy and biomass