由三叉戟硫给体支持的生物激发的杂双核铁钼配合物及其对肼歧化的催化活性

IF 3.3 3区化学 Q2 CHEMISTRY, INORGANIC & NUCLEAR

Dalton Transactions Pub Date : 2025-09-15 DOI:10.1039/d5dt01575h

Xiang Xu, Ronghuan Du, Luyang Sun, Dawei Yang, Baomin Wang, Jingping Qu

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引用次数: 0

摘要

设计并合成了一种生物启发的硫酸盐桥接铁钼配合物，其结构基序与FeMoco的{FeS3Mo}部分相似。光谱和计算研究表明，它包含一个低自旋FeII和一个弱金属-金属键的MoIV中心。此外，还证明了它是一种很好的肼歧化催化剂。

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A bioinspired hetero-binuclear iron-molybdenum complex supported by tridentate sulfur donors and its catalytic activity toward hydrazine disproportionation

A bioinspired thiolate-bridged iron-molybdenum complex was designed and synthesized, featuring similar structural motifs as found in the {FeS3Mo} moiety of FeMoco. Spectroscopic and computational studies reveal it contains a low-spin FeII and a MoIV centre with weak metal-metal bonding. Furthermore, it is proven as a good catalyst for hydrazine disproportionation.

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来源期刊

Dalton Transactions 化学-无机化学与核化学

CiteScore

6.60

自引率

7.50%

发文量

1832

审稿时长

1.5 months

期刊介绍： Dalton Transactions is a journal for all areas of inorganic chemistry, which encompasses the organometallic, bioinorganic and materials chemistry of the elements, with applications including synthesis, catalysis, energy conversion/storage, electrical devices and medicine. Dalton Transactions welcomes high-quality, original submissions in all of these areas and more, where the advancement of knowledge in inorganic chemistry is significant.