Juan Tang, Ming-Xing Lan, Hai-Na Ding, Xue-Qing Mou, Yun Zhang, Yong-Zheng Chen, Bao-Dong Cui
{"title":"光催化还原硼化,磷化,硫化和硒化芳基碘化物以获得芳基硼酸盐,芳基磷酸盐,芳基硫化物和芳基硒化物","authors":"Juan Tang, Ming-Xing Lan, Hai-Na Ding, Xue-Qing Mou, Yun Zhang, Yong-Zheng Chen, Bao-Dong Cui","doi":"10.1002/ajoc.202500362","DOIUrl":null,"url":null,"abstract":"<p>A simple photoinduced radical borylation, phosphonation, sulfurization and selenization of various aryl iodides to construct the structurally diverse C-B/P/S/Se bonds has been developed. Using HCO<sub>2</sub>Na as the reductant, a wide range of aryl iodides including the substituted iodobenzenes, heteroaromatic iodides, aromatic iodides derived from the pharmaceutically active molecules could be utilized to react with the bis(pinacolato)diboron, triethyl phosphite, (RS)<sub>2</sub> or (RSe)<sub>2</sub> to obtain a variety of aryl borates, aryl phosphates, aryl sulfides and aryl selenides in general moderate to good yields.The advantage of this protocol is also highlighted by its no extra metal/photocatalyst, gram-scale synthesis and the further functional transformations of the products.</p>","PeriodicalId":130,"journal":{"name":"Asian Journal of Organic Chemistry","volume":"14 9","pages":""},"PeriodicalIF":2.7000,"publicationDate":"2025-07-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Photocatalytic Reductive Borylation, Phosphonation, Sulfurization, and Selenization of Aryl Iodides to Access Aryl Borates, Aryl Phosphates, Aryl Sulfides, and Aryl Selenides\",\"authors\":\"Juan Tang, Ming-Xing Lan, Hai-Na Ding, Xue-Qing Mou, Yun Zhang, Yong-Zheng Chen, Bao-Dong Cui\",\"doi\":\"10.1002/ajoc.202500362\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>A simple photoinduced radical borylation, phosphonation, sulfurization and selenization of various aryl iodides to construct the structurally diverse C-B/P/S/Se bonds has been developed. Using HCO<sub>2</sub>Na as the reductant, a wide range of aryl iodides including the substituted iodobenzenes, heteroaromatic iodides, aromatic iodides derived from the pharmaceutically active molecules could be utilized to react with the bis(pinacolato)diboron, triethyl phosphite, (RS)<sub>2</sub> or (RSe)<sub>2</sub> to obtain a variety of aryl borates, aryl phosphates, aryl sulfides and aryl selenides in general moderate to good yields.The advantage of this protocol is also highlighted by its no extra metal/photocatalyst, gram-scale synthesis and the further functional transformations of the products.</p>\",\"PeriodicalId\":130,\"journal\":{\"name\":\"Asian Journal of Organic Chemistry\",\"volume\":\"14 9\",\"pages\":\"\"},\"PeriodicalIF\":2.7000,\"publicationDate\":\"2025-07-09\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Asian Journal of Organic Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://aces.onlinelibrary.wiley.com/doi/10.1002/ajoc.202500362\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, ORGANIC\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Asian Journal of Organic Chemistry","FirstCategoryId":"92","ListUrlMain":"https://aces.onlinelibrary.wiley.com/doi/10.1002/ajoc.202500362","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, ORGANIC","Score":null,"Total":0}
Photocatalytic Reductive Borylation, Phosphonation, Sulfurization, and Selenization of Aryl Iodides to Access Aryl Borates, Aryl Phosphates, Aryl Sulfides, and Aryl Selenides
A simple photoinduced radical borylation, phosphonation, sulfurization and selenization of various aryl iodides to construct the structurally diverse C-B/P/S/Se bonds has been developed. Using HCO2Na as the reductant, a wide range of aryl iodides including the substituted iodobenzenes, heteroaromatic iodides, aromatic iodides derived from the pharmaceutically active molecules could be utilized to react with the bis(pinacolato)diboron, triethyl phosphite, (RS)2 or (RSe)2 to obtain a variety of aryl borates, aryl phosphates, aryl sulfides and aryl selenides in general moderate to good yields.The advantage of this protocol is also highlighted by its no extra metal/photocatalyst, gram-scale synthesis and the further functional transformations of the products.
期刊介绍:
Organic chemistry is the fundamental science that stands at the heart of chemistry, biology, and materials science. Research in these areas is vigorous and truly international, with three major regions making almost equal contributions: America, Europe and Asia. Asia now has its own top international organic chemistry journal—the Asian Journal of Organic Chemistry (AsianJOC)
The AsianJOC is designed to be a top-ranked international research journal and publishes primary research as well as critical secondary information from authors across the world. The journal covers organic chemistry in its entirety. Authors and readers come from academia, the chemical industry, and government laboratories.