{"title":"碘空位调制双S-scheme BiOI/BiSI/BiOBr异质结增强盐酸四环素降解的制备","authors":"Jiexi Wang, Sheng Wang, Chengxiong Xu, Wenju Yu","doi":"10.1016/j.jiec.2025.04.034","DOIUrl":null,"url":null,"abstract":"<div><div>In this work, an iodine vacancy-modulated dual S-scheme BiOI/BiSI/BiOBr heterojunction was prepared via a hydrothermal method, and its photocatalytic efficiency was assessed through the degradation of tetracycline hydrochloride (TCH). The results reveal that the combined effects of improved visible light absorption, iodine vacancies, S-scheme charge transfer, and electron sacrificial agent significantly enhance photocatalytic activity. Under visible light irradiation for 240 min, the BiOI/BiSI/BiOBr heterojunction achieves an impressive TCH degradation rate of 89.51 %, which is approximately 2.06 times higher than that of BiOBr. Additionally, the heterojunction remains stable throughout the photocatalytic process as long as surface-adsorbed TCH is removed with deionized water and anhydrous ethanol after each cycle. The anion vacancy-modulated dual S-scheme charge transfer offers valuable insights into the photocatalytic oxidation of contaminants.</div></div>","PeriodicalId":363,"journal":{"name":"Journal of Industrial and Engineering Chemistry","volume":"151 ","pages":"Pages 639-652"},"PeriodicalIF":5.9000,"publicationDate":"2025-04-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Fabrication of iodine vacancy-modulated dual S-scheme BiOI/BiSI/BiOBr heterojunction for enhanced tetracycline hydrochloride degradation\",\"authors\":\"Jiexi Wang, Sheng Wang, Chengxiong Xu, Wenju Yu\",\"doi\":\"10.1016/j.jiec.2025.04.034\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>In this work, an iodine vacancy-modulated dual S-scheme BiOI/BiSI/BiOBr heterojunction was prepared via a hydrothermal method, and its photocatalytic efficiency was assessed through the degradation of tetracycline hydrochloride (TCH). The results reveal that the combined effects of improved visible light absorption, iodine vacancies, S-scheme charge transfer, and electron sacrificial agent significantly enhance photocatalytic activity. Under visible light irradiation for 240 min, the BiOI/BiSI/BiOBr heterojunction achieves an impressive TCH degradation rate of 89.51 %, which is approximately 2.06 times higher than that of BiOBr. Additionally, the heterojunction remains stable throughout the photocatalytic process as long as surface-adsorbed TCH is removed with deionized water and anhydrous ethanol after each cycle. The anion vacancy-modulated dual S-scheme charge transfer offers valuable insights into the photocatalytic oxidation of contaminants.</div></div>\",\"PeriodicalId\":363,\"journal\":{\"name\":\"Journal of Industrial and Engineering Chemistry\",\"volume\":\"151 \",\"pages\":\"Pages 639-652\"},\"PeriodicalIF\":5.9000,\"publicationDate\":\"2025-04-20\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Industrial and Engineering Chemistry\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S1226086X25002692\",\"RegionNum\":3,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Industrial and Engineering Chemistry","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1226086X25002692","RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Fabrication of iodine vacancy-modulated dual S-scheme BiOI/BiSI/BiOBr heterojunction for enhanced tetracycline hydrochloride degradation
In this work, an iodine vacancy-modulated dual S-scheme BiOI/BiSI/BiOBr heterojunction was prepared via a hydrothermal method, and its photocatalytic efficiency was assessed through the degradation of tetracycline hydrochloride (TCH). The results reveal that the combined effects of improved visible light absorption, iodine vacancies, S-scheme charge transfer, and electron sacrificial agent significantly enhance photocatalytic activity. Under visible light irradiation for 240 min, the BiOI/BiSI/BiOBr heterojunction achieves an impressive TCH degradation rate of 89.51 %, which is approximately 2.06 times higher than that of BiOBr. Additionally, the heterojunction remains stable throughout the photocatalytic process as long as surface-adsorbed TCH is removed with deionized water and anhydrous ethanol after each cycle. The anion vacancy-modulated dual S-scheme charge transfer offers valuable insights into the photocatalytic oxidation of contaminants.
期刊介绍:
Journal of Industrial and Engineering Chemistry is published monthly in English by the Korean Society of Industrial and Engineering Chemistry. JIEC brings together multidisciplinary interests in one journal and is to disseminate information on all aspects of research and development in industrial and engineering chemistry. Contributions in the form of research articles, short communications, notes and reviews are considered for publication. The editors welcome original contributions that have not been and are not to be published elsewhere. Instruction to authors and a manuscript submissions form are printed at the end of each issue. Bulk reprints of individual articles can be ordered. This publication is partially supported by Korea Research Foundation and the Korean Federation of Science and Technology Societies.