聚合物衍生陶瓷的无溶剂和无粘结剂添加剂制造:流变调谐和结构性能

IF 11.1 1区 工程技术 Q1 ENGINEERING, MANUFACTURING
Laxmi Sai Viswanadha , Jeremy Watts , Mohammad Naraghi
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引用次数: 0

摘要

碳化硅(SiC)陶瓷基复合材料因其高强度、耐热性和耐腐蚀性而广泛应用于航空航天领域。然而,传统的加工方法使得复杂形状的加工具有挑战性。本研究提出了一种无溶剂和无粘结剂的直接墨水书写(DIW)方法,用于使用聚碳硅烷SMP-10生产SiC/SiOC复合材料,SMP-10是一种预陶瓷聚合物,既可以作为陶瓷前驱体又可以作为液相,从而消除了对挥发性溶剂和牺牲粘结剂的需求。通过调整碳化硅含量,研制出可印刷的油墨配方,并对其流动性能进行了分析。研究了墙体间距、基层宽度等几何因素对结构稳定性的影响。更宽的基层提供了更大的支撑,增加了破坏前的最大可打印高度,而墙壁间距较大的结构由于侧向支撑减少,更容易倒塌。这些发现强调了结构设计在实现稳定和精确打印中的重要性。印刷晶格结构的抗压强度为5.62 ± 1.75 MPa - 9.62 ± 1.10 MPa,密度为2.05 - 2.34 g/cm³,具有优异的绝热性和稳定性。这种方法为制造具有优异机械和热性能的复杂陶瓷结构提供了一种简单有效的方法,使其与先进的航空航天和高温应用高度相关。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Solvent- and binder-free additive manufacturing of polymer-derived ceramics: Rheological tuning and structural performance
Silicon carbide (SiC) ceramic matrix composites are widely used in aerospace applications due to their high strength, heat resistance, and corrosion resistance. However, traditional machining methods make it challenging to fabricate complex shapes. This study presents a solvent-free and binder-free direct ink writing (DIW) method for producing SiC/SiOC composites using polycarbosilane SMP-10, a preceramic polymer that acts as both the ceramic precursor and the liquid phase, thereby eliminating the need for volatile solvents and sacrificial binders. By adjusting the SiC content, printable ink formulations were developed, and their flow properties were analyzed. The influence of geometric factors, such as inter-wall spacing and base layer width, on structural stability was also examined. Wider base layers provided greater support, increasing the maximum printable height before failure, while structures with larger inter-wall spacing were more prone to collapse due to reduced lateral support. These findings highlight the importance of structural design in achieving stable and precise prints. The printed lattice structures exhibited compressive strength of 5.62 ± 1.75 MPa – 9.62 ± 1.10 MPa and density of 2.05 – 2.34 g/cm³, alongside exceptional thermal insulation and stability. This approach offers an easy and efficient method for fabricating complex ceramic structures with excellent mechanical and thermal performance, making it highly relevant for advanced aerospace and high-temperature applications.
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来源期刊
Additive manufacturing
Additive manufacturing Materials Science-General Materials Science
CiteScore
19.80
自引率
12.70%
发文量
648
审稿时长
35 days
期刊介绍: Additive Manufacturing stands as a peer-reviewed journal dedicated to delivering high-quality research papers and reviews in the field of additive manufacturing, serving both academia and industry leaders. The journal's objective is to recognize the innovative essence of additive manufacturing and its diverse applications, providing a comprehensive overview of current developments and future prospects. The transformative potential of additive manufacturing technologies in product design and manufacturing is poised to disrupt traditional approaches. In response to this paradigm shift, a distinctive and comprehensive publication outlet was essential. Additive Manufacturing fulfills this need, offering a platform for engineers, materials scientists, and practitioners across academia and various industries to document and share innovations in these evolving technologies.
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