通过钝化阴极活性和促进稀土氧化膜来设计超高耐蚀性镁合金

IF 7.4 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY
Ye Tian , Zhihao Yang , Junsheng Wang , Chi Zhang , Chengpeng Xue , Hui Su , Yisheng Miao , Zhongyao Li , Wenbo Wu , Xinghai Yang
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引用次数: 0

摘要

许多提高镁合金耐蚀性的研究都集中在寻找能够降低镁合金腐蚀速率的元素上。然而,由于没有对合金元素的单独贡献及其综合作用进行定量分析,耐腐蚀合金的设计总是在试错的过程中进行。在本研究中,我们量化了二元、三元和四元添加Y、Ce和Mn对镁合金的影响,并通过浸泡前后的微观结构量化发现,镁合金的电化学性能不仅是简单溶解的函数,而且是其存在状态的函数。利用第一性原理计算,我们发现稀土(RE)元素,如Ce和Y,只有当它们形成二次相并作为阳极在Mg基体前形成氧化膜时才能有效;而Mn的溶解实际上可以钝化阴极活性,提高基体的功函数(从3.66 eV提高到3.80 eV)。铸态Mg-2Y-0.5Ce-0.5Mn合金表现出最佳的耐蚀性(0.395 mm/y),这是由于电偶腐蚀部位的减少和含re氧化物的保护。因此,通过钝化阴极活性和促进稀土氧化膜,成功开发出了超高耐腐蚀镁合金,进一步为不锈钢镁合金的发展指明了一条新的途径。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Designing ultra-high corrosion resistance Mg alloys by passivating cathodic activity and promoting RE oxide films
Many studies on improving the corrosion resistance of Mg alloys have been focusing on identifying certain elements which can reduce the corrosion rate of Mg alloys. However, without quantitative analysis of individual contributions of alloying elements and their combined effects, the corrosion resistance alloy design is always performed by trial-and-error process. In this study, we have quantified the effects of binary, ternary and quaternary additions of Y, Ce, and Mn to Mg alloys and found that their electrochemical performances are not only a function of simple dissolution but also their existing states by microstructure quantification before and after immersion tests. Using first-principles calculations, we have found that the beneficial effects of Rare Earth (RE) elements, such as Ce, and Y, can only be effective when they form secondary phases and act as the anode to form oxide films in front of Mg matrix; while dissolution of Mn can actually passivate the cathodic activity and improve the work function of the matrix (from 3.66 eV to 3.80 eV). Measurements of as-cast Mg-2Y-0.5Ce-0.5Mn alloy exhibit the best corrosion resistance (0.395 mm/y), due to both reduction of galvanic corrosion sites and protection of RE-containing oxides. Therefore, ultra-high corrosion-resistant Mg alloys have been successfully developed by passivating cathodic activity and promoting RE oxide films, further illuminating a new route for stainless Mg alloy development.
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来源期刊
Corrosion Science
Corrosion Science 工程技术-材料科学:综合
CiteScore
13.60
自引率
18.10%
发文量
763
审稿时长
46 days
期刊介绍: Corrosion occurrence and its practical control encompass a vast array of scientific knowledge. Corrosion Science endeavors to serve as the conduit for the exchange of ideas, developments, and research across all facets of this field, encompassing both metallic and non-metallic corrosion. The scope of this international journal is broad and inclusive. Published papers span from highly theoretical inquiries to essentially practical applications, covering diverse areas such as high-temperature oxidation, passivity, anodic oxidation, biochemical corrosion, stress corrosion cracking, and corrosion control mechanisms and methodologies. This journal publishes original papers and critical reviews across the spectrum of pure and applied corrosion, material degradation, and surface science and engineering. It serves as a crucial link connecting metallurgists, materials scientists, and researchers investigating corrosion and degradation phenomena. Join us in advancing knowledge and understanding in the vital field of corrosion science.
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