{"title":"以三乙胺、2-羟乙基甲酸铵和Fe3O4@SiO2@[O-(CH2)2-NH2][HCO2H]为催化剂制备新型苯并铬衍生物","authors":"Fahimeh Abbaszadeh-Mahmoudi, Farhad Shirzaei, Hamid Reza Shaterian","doi":"10.1007/s11164-025-05698-y","DOIUrl":null,"url":null,"abstract":"<div><p>In this research, the preparation of new benzochromene derivatives was synthesized in a three-component reaction using 1-naphthol and 2-naphthol, methylsulfonylacetonitrile and malononitrile, and aldehyde derivatives in the presence of triethylamine as catalyst, 2-hydroxyethylammonium formate as ionic liquid catalyst, and Fe<sub>3</sub>O<sub>4</sub>@SiO<sub>2</sub>@[O-(CH<sub>2</sub>)<sub>2</sub>-NH<sub>2</sub>][HCO<sub>2</sub>H] as nanocatalyst. The advantages of this protocol include high yields, green chemistry, short reaction times, and catalyst recycling.</p></div>","PeriodicalId":753,"journal":{"name":"Research on Chemical Intermediates","volume":"51 10","pages":"5649 - 5665"},"PeriodicalIF":3.5000,"publicationDate":"2025-08-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Preparation of new benzochromene derivatives using triethylamine, 2-hydroxyethylammonium formate, and Fe3O4@SiO2@[O-(CH2)2-NH2][HCO2H] as catalysts\",\"authors\":\"Fahimeh Abbaszadeh-Mahmoudi, Farhad Shirzaei, Hamid Reza Shaterian\",\"doi\":\"10.1007/s11164-025-05698-y\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>In this research, the preparation of new benzochromene derivatives was synthesized in a three-component reaction using 1-naphthol and 2-naphthol, methylsulfonylacetonitrile and malononitrile, and aldehyde derivatives in the presence of triethylamine as catalyst, 2-hydroxyethylammonium formate as ionic liquid catalyst, and Fe<sub>3</sub>O<sub>4</sub>@SiO<sub>2</sub>@[O-(CH<sub>2</sub>)<sub>2</sub>-NH<sub>2</sub>][HCO<sub>2</sub>H] as nanocatalyst. The advantages of this protocol include high yields, green chemistry, short reaction times, and catalyst recycling.</p></div>\",\"PeriodicalId\":753,\"journal\":{\"name\":\"Research on Chemical Intermediates\",\"volume\":\"51 10\",\"pages\":\"5649 - 5665\"},\"PeriodicalIF\":3.5000,\"publicationDate\":\"2025-08-03\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Research on Chemical Intermediates\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s11164-025-05698-y\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Research on Chemical Intermediates","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s11164-025-05698-y","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Preparation of new benzochromene derivatives using triethylamine, 2-hydroxyethylammonium formate, and Fe3O4@SiO2@[O-(CH2)2-NH2][HCO2H] as catalysts
In this research, the preparation of new benzochromene derivatives was synthesized in a three-component reaction using 1-naphthol and 2-naphthol, methylsulfonylacetonitrile and malononitrile, and aldehyde derivatives in the presence of triethylamine as catalyst, 2-hydroxyethylammonium formate as ionic liquid catalyst, and Fe3O4@SiO2@[O-(CH2)2-NH2][HCO2H] as nanocatalyst. The advantages of this protocol include high yields, green chemistry, short reaction times, and catalyst recycling.
期刊介绍:
Research on Chemical Intermediates publishes current research articles and concise dynamic reviews on the properties, structures and reactivities of intermediate species in all the various domains of chemistry.
The journal also contains articles in related disciplines such as spectroscopy, molecular biology and biochemistry, atmospheric and environmental sciences, catalysis, photochemistry and photophysics. In addition, special issues dedicated to specific topics in the field are regularly published.