使用MXene-CNT混合复合材料检测环境样品中对苯二酚的一次性纸基电化学传感器

IF 5.3 2区 化学 Q1 CHEMISTRY, ANALYTICAL
Pramod K. Kalambate, Sharad S. Upadhyay, Shambhavi Singh, Wanida Laiwattanapaisal,  Dhanjai
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引用次数: 0

摘要

研究了MXene/多壁碳纳米管(MWCNT)复合传感器的电化学性能,并与MWCNT进行了比较,用于未稀释水样中对苯二酚(HQ)的灵敏检测。该传感器采用定制的丝网印刷碳电极,用Ti3C2Tx/MWCNT修饰,允许快速制造和集成工作电极,参考电极和反电极到一个紧凑的便携式设备中。多层MXene提供了大的比表面积,而MWCNT提高了导电性,即使在复杂的样品基质中也能实现清晰的电化学信号。MWCNT/SPCE和Ti3C2Tx/MWCNT/SPCE传感器具有优异的灵敏度,检测限分别为0.055µM和0.261µM,线性范围分别为3-600µM和6-900µM。该传感器对HQ具有很强的选择性,对共存物种的干扰最小,并且几乎不需要制备样品,为实时环境监测提供了可行的方法。图形抽象
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Disposable paper-based electrochemical sensor for hydroquinone detection in environmental samples using a MXene-CNT hybrid composite

Disposable paper-based electrochemical sensor for hydroquinone detection in environmental samples using a MXene-CNT hybrid composite

Disposable paper-based electrochemical sensor for hydroquinone detection in environmental samples using a MXene-CNT hybrid composite

This study investigates the electrochemical performance of MXene/multi-walled carbon nanotubes (MWCNT) composite-based sensor and its comparison with MWCNT for the sensitive detection of hydroquinone (HQ) in undiluted water samples. The sensor employs custom-made screen-printed carbon electrodes modified with Ti3C2Tx/MWCNT, allowing for rapid fabrication and integration of the working, reference, and counter electrodes into a compact, portable device. The multilayer MXene provides a large specific surface area, while MWCNT enhances electrical conductivity, enabling clear electrochemical signals even in complex sample matrices. The MWCNT/SPCE and Ti3C2Tx/MWCNT/SPCE sensors demonstrated excellent sensitivity, achieving low detection limits of 0.055 µM and 0.261 µM, with wide Linear ranges of 3–600 µM and 6–900 µM, respectively. The sensor demonstrates strong selectivity for HQ with minimal interference from coexisting species and requires little to no sample preparation, offering a feasible approach for real-time environmental monitoring.

Graphical Abstract

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来源期刊
Microchimica Acta
Microchimica Acta 化学-分析化学
CiteScore
9.80
自引率
5.30%
发文量
410
审稿时长
2.7 months
期刊介绍: As a peer-reviewed journal for analytical sciences and technologies on the micro- and nanoscale, Microchimica Acta has established itself as a premier forum for truly novel approaches in chemical and biochemical analysis. Coverage includes methods and devices that provide expedient solutions to the most contemporary demands in this area. Examples are point-of-care technologies, wearable (bio)sensors, in-vivo-monitoring, micro/nanomotors and materials based on synthetic biology as well as biomedical imaging and targeting.
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