{"title":"过渡金属化合物双电子氧还原晶体结构调控策略的研究进展","authors":"Hang Feng, Shiyu Yu, Chengxu Zhang, Jue Hu","doi":"10.1007/s11705-025-2605-7","DOIUrl":null,"url":null,"abstract":"<div><p>Currently, the electrocatalytic two-electron oxygen reduction reaction for the production of H<sub>2</sub>O<sub>2</sub> presents a promising alternative to the energy-intensive anthraquinone process. Enhancing the selectivity and activity of the catalyst is crucial for achieving efficient electrosynthesis of H<sub>2</sub>O<sub>2</sub>. Transition metal compound catalysts are considered ideal electrocatalysts due to their advantages, including simple preparation, low cost, diverse crystal structures, abundant availability, environmental friendliness, and the synergistic effects between coupled metals. This paper systematically reviews the latest research advancements regarding transition metal compounds used in oxygen reduction reactions to generate H<sub>2</sub>O<sub>2</sub>. It begins by elaborating on the fundamental concepts related to oxygen reduction reactions and subsequently discusses various methods for regulating transition metal compound catalysts, including element doping, defect generation, heterogeneous structure construction, crystal design, and polycrystalline transformation. The activities, selectivity, and stability of different transition metal compounds in the electrocatalytic synthesis of H<sub>2</sub>O<sub>2</sub> are summarized, and the future development directions for transition metal compound catalysts are explored, providing valuable insights for the large-scale and efficient electrosynthesis of H<sub>2</sub>O<sub>2</sub> in the future.</p><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":571,"journal":{"name":"Frontiers of Chemical Science and Engineering","volume":"19 11","pages":""},"PeriodicalIF":4.5000,"publicationDate":"2025-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Research progress on crystal structure regulation strategies for two-electron oxygen reduction of transition metal compounds\",\"authors\":\"Hang Feng, Shiyu Yu, Chengxu Zhang, Jue Hu\",\"doi\":\"10.1007/s11705-025-2605-7\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Currently, the electrocatalytic two-electron oxygen reduction reaction for the production of H<sub>2</sub>O<sub>2</sub> presents a promising alternative to the energy-intensive anthraquinone process. Enhancing the selectivity and activity of the catalyst is crucial for achieving efficient electrosynthesis of H<sub>2</sub>O<sub>2</sub>. Transition metal compound catalysts are considered ideal electrocatalysts due to their advantages, including simple preparation, low cost, diverse crystal structures, abundant availability, environmental friendliness, and the synergistic effects between coupled metals. This paper systematically reviews the latest research advancements regarding transition metal compounds used in oxygen reduction reactions to generate H<sub>2</sub>O<sub>2</sub>. It begins by elaborating on the fundamental concepts related to oxygen reduction reactions and subsequently discusses various methods for regulating transition metal compound catalysts, including element doping, defect generation, heterogeneous structure construction, crystal design, and polycrystalline transformation. The activities, selectivity, and stability of different transition metal compounds in the electrocatalytic synthesis of H<sub>2</sub>O<sub>2</sub> are summarized, and the future development directions for transition metal compound catalysts are explored, providing valuable insights for the large-scale and efficient electrosynthesis of H<sub>2</sub>O<sub>2</sub> in the future.</p><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>\",\"PeriodicalId\":571,\"journal\":{\"name\":\"Frontiers of Chemical Science and Engineering\",\"volume\":\"19 11\",\"pages\":\"\"},\"PeriodicalIF\":4.5000,\"publicationDate\":\"2025-09-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Frontiers of Chemical Science and Engineering\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s11705-025-2605-7\",\"RegionNum\":3,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"ENGINEERING, CHEMICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Frontiers of Chemical Science and Engineering","FirstCategoryId":"5","ListUrlMain":"https://link.springer.com/article/10.1007/s11705-025-2605-7","RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"ENGINEERING, CHEMICAL","Score":null,"Total":0}
Research progress on crystal structure regulation strategies for two-electron oxygen reduction of transition metal compounds
Currently, the electrocatalytic two-electron oxygen reduction reaction for the production of H2O2 presents a promising alternative to the energy-intensive anthraquinone process. Enhancing the selectivity and activity of the catalyst is crucial for achieving efficient electrosynthesis of H2O2. Transition metal compound catalysts are considered ideal electrocatalysts due to their advantages, including simple preparation, low cost, diverse crystal structures, abundant availability, environmental friendliness, and the synergistic effects between coupled metals. This paper systematically reviews the latest research advancements regarding transition metal compounds used in oxygen reduction reactions to generate H2O2. It begins by elaborating on the fundamental concepts related to oxygen reduction reactions and subsequently discusses various methods for regulating transition metal compound catalysts, including element doping, defect generation, heterogeneous structure construction, crystal design, and polycrystalline transformation. The activities, selectivity, and stability of different transition metal compounds in the electrocatalytic synthesis of H2O2 are summarized, and the future development directions for transition metal compound catalysts are explored, providing valuable insights for the large-scale and efficient electrosynthesis of H2O2 in the future.
期刊介绍:
Frontiers of Chemical Science and Engineering presents the latest developments in chemical science and engineering, emphasizing emerging and multidisciplinary fields and international trends in research and development. The journal promotes communication and exchange between scientists all over the world. The contents include original reviews, research papers and short communications. Coverage includes catalysis and reaction engineering, clean energy, functional material, nanotechnology and nanoscience, biomaterials and biotechnology, particle technology and multiphase processing, separation science and technology, sustainable technologies and green processing.