过渡金属化合物双电子氧还原晶体结构调控策略的研究进展

IF 4.5 3区 工程技术 Q2 ENGINEERING, CHEMICAL
Hang Feng, Shiyu Yu, Chengxu Zhang, Jue Hu
{"title":"过渡金属化合物双电子氧还原晶体结构调控策略的研究进展","authors":"Hang Feng,&nbsp;Shiyu Yu,&nbsp;Chengxu Zhang,&nbsp;Jue Hu","doi":"10.1007/s11705-025-2605-7","DOIUrl":null,"url":null,"abstract":"<div><p>Currently, the electrocatalytic two-electron oxygen reduction reaction for the production of H<sub>2</sub>O<sub>2</sub> presents a promising alternative to the energy-intensive anthraquinone process. Enhancing the selectivity and activity of the catalyst is crucial for achieving efficient electrosynthesis of H<sub>2</sub>O<sub>2</sub>. Transition metal compound catalysts are considered ideal electrocatalysts due to their advantages, including simple preparation, low cost, diverse crystal structures, abundant availability, environmental friendliness, and the synergistic effects between coupled metals. This paper systematically reviews the latest research advancements regarding transition metal compounds used in oxygen reduction reactions to generate H<sub>2</sub>O<sub>2</sub>. It begins by elaborating on the fundamental concepts related to oxygen reduction reactions and subsequently discusses various methods for regulating transition metal compound catalysts, including element doping, defect generation, heterogeneous structure construction, crystal design, and polycrystalline transformation. The activities, selectivity, and stability of different transition metal compounds in the electrocatalytic synthesis of H<sub>2</sub>O<sub>2</sub> are summarized, and the future development directions for transition metal compound catalysts are explored, providing valuable insights for the large-scale and efficient electrosynthesis of H<sub>2</sub>O<sub>2</sub> in the future.</p><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":571,"journal":{"name":"Frontiers of Chemical Science and Engineering","volume":"19 11","pages":""},"PeriodicalIF":4.5000,"publicationDate":"2025-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Research progress on crystal structure regulation strategies for two-electron oxygen reduction of transition metal compounds\",\"authors\":\"Hang Feng,&nbsp;Shiyu Yu,&nbsp;Chengxu Zhang,&nbsp;Jue Hu\",\"doi\":\"10.1007/s11705-025-2605-7\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Currently, the electrocatalytic two-electron oxygen reduction reaction for the production of H<sub>2</sub>O<sub>2</sub> presents a promising alternative to the energy-intensive anthraquinone process. Enhancing the selectivity and activity of the catalyst is crucial for achieving efficient electrosynthesis of H<sub>2</sub>O<sub>2</sub>. Transition metal compound catalysts are considered ideal electrocatalysts due to their advantages, including simple preparation, low cost, diverse crystal structures, abundant availability, environmental friendliness, and the synergistic effects between coupled metals. This paper systematically reviews the latest research advancements regarding transition metal compounds used in oxygen reduction reactions to generate H<sub>2</sub>O<sub>2</sub>. It begins by elaborating on the fundamental concepts related to oxygen reduction reactions and subsequently discusses various methods for regulating transition metal compound catalysts, including element doping, defect generation, heterogeneous structure construction, crystal design, and polycrystalline transformation. The activities, selectivity, and stability of different transition metal compounds in the electrocatalytic synthesis of H<sub>2</sub>O<sub>2</sub> are summarized, and the future development directions for transition metal compound catalysts are explored, providing valuable insights for the large-scale and efficient electrosynthesis of H<sub>2</sub>O<sub>2</sub> in the future.</p><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>\",\"PeriodicalId\":571,\"journal\":{\"name\":\"Frontiers of Chemical Science and Engineering\",\"volume\":\"19 11\",\"pages\":\"\"},\"PeriodicalIF\":4.5000,\"publicationDate\":\"2025-09-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Frontiers of Chemical Science and Engineering\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s11705-025-2605-7\",\"RegionNum\":3,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"ENGINEERING, CHEMICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Frontiers of Chemical Science and Engineering","FirstCategoryId":"5","ListUrlMain":"https://link.springer.com/article/10.1007/s11705-025-2605-7","RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"ENGINEERING, CHEMICAL","Score":null,"Total":0}
引用次数: 0

摘要

目前,电催化双电子氧还原反应生产H2O2是替代能源密集型蒽醌工艺的一种很有前途的方法。提高催化剂的选择性和活性是实现高效电合成H2O2的关键。过渡金属化合物催化剂具有制备简单、成本低、晶体结构多样、可利用性丰富、环境友好、偶联金属间具有协同效应等优点,被认为是理想的电催化剂。本文系统地综述了过渡金属化合物用于氧还原反应生成H2O2的最新研究进展。首先阐述了与氧还原反应相关的基本概念,随后讨论了调节过渡金属化合物催化剂的各种方法,包括元素掺杂、缺陷生成、非均相结构构建、晶体设计和多晶转变。综述了不同过渡金属化合物在电催化合成H2O2中的活性、选择性和稳定性,并对过渡金属化合物催化剂的未来发展方向进行了探讨,为今后大规模高效电合成H2O2提供有价值的见解。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Research progress on crystal structure regulation strategies for two-electron oxygen reduction of transition metal compounds

Currently, the electrocatalytic two-electron oxygen reduction reaction for the production of H2O2 presents a promising alternative to the energy-intensive anthraquinone process. Enhancing the selectivity and activity of the catalyst is crucial for achieving efficient electrosynthesis of H2O2. Transition metal compound catalysts are considered ideal electrocatalysts due to their advantages, including simple preparation, low cost, diverse crystal structures, abundant availability, environmental friendliness, and the synergistic effects between coupled metals. This paper systematically reviews the latest research advancements regarding transition metal compounds used in oxygen reduction reactions to generate H2O2. It begins by elaborating on the fundamental concepts related to oxygen reduction reactions and subsequently discusses various methods for regulating transition metal compound catalysts, including element doping, defect generation, heterogeneous structure construction, crystal design, and polycrystalline transformation. The activities, selectivity, and stability of different transition metal compounds in the electrocatalytic synthesis of H2O2 are summarized, and the future development directions for transition metal compound catalysts are explored, providing valuable insights for the large-scale and efficient electrosynthesis of H2O2 in the future.

求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
CiteScore
7.60
自引率
6.70%
发文量
868
审稿时长
1 months
期刊介绍: Frontiers of Chemical Science and Engineering presents the latest developments in chemical science and engineering, emphasizing emerging and multidisciplinary fields and international trends in research and development. The journal promotes communication and exchange between scientists all over the world. The contents include original reviews, research papers and short communications. Coverage includes catalysis and reaction engineering, clean energy, functional material, nanotechnology and nanoscience, biomaterials and biotechnology, particle technology and multiphase processing, separation science and technology, sustainable technologies and green processing.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:604180095
Book学术官方微信