2,9-二氯-1,10-菲罗啉与仲胺的反应是一类新的有前途的配体的便捷途径

IF 1.7 4区化学 Q3 CHEMISTRY, MULTIDISCIPLINARY

Russian Chemical Bulletin Pub Date : 2025-09-12 DOI:10.1007/s11172-025-4722-3

V. M. Muzalevskiy, J. K. Isomiddinov, K. A. Lyssenko, V. G. Nenajdenko

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引用次数: 0

摘要

研究了2,9-二氯-1,10-菲罗啉中氯原子与仲胺的亲核取代。该反应产生单取代胺和双取代胺，包括含有两种不同仲胺的不对称化合物，产率为97-99%。产物的组成取决于反应温度、溶剂性质和胺的用量。以含有morpholine基团的对称双胺为原料，与AgNO3和HgCl2合成配合物。

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Reaction of 2,9-dichloro-1,10-phenanthroline with secondary amines as a convenient approach to a new class of promising ligands

Nucleophilic substitution of the chlorine atoms in 2,9-dichloro-1,10-phenanthroline with secondary amines was studied. This reaction provides mono- and bis-substituted amines, including unsymmetrical compounds with two different moieties of secondary amines, in 97–99% yields. The product composition depends on the reaction temperature, solvent nature, and the amount of amine used. Symmetrical bisamine bearing the morpholine moieties was used as a starting material to synthesize complexes with AgNO₃ and HgCl₂.

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来源期刊

Russian Chemical Bulletin 化学-化学综合

CiteScore

2.70

自引率

47.10%

发文量

257

审稿时长

3-8 weeks

期刊介绍： Publishing nearly 500 original articles a year, by leading Scientists from Russia and throughout the world, Russian Chemical Bulletin is a prominent international journal. The coverage of the journal spans practically all areas of fundamental chemical research and is presented in five sections: General and Inorganic Chemistry; Physical Chemistry; Organic Chemistry; Organometallic Chemistry; Chemistry of Natural Compounds and Bioorganic Chemistry.