正烷基苯和正戊烷二元混合物:密度、声速和0.1 MPa下288.15和333.15 K范围内的粘度

IF 2.1 3区 工程技术 Q3 CHEMISTRY, MULTIDISCIPLINARY
Dianne J. Luning Prak*,  and , Jim S. Cowart, 
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引用次数: 0

摘要

烷烃和芳烃混合物的物理性质有助于理解和模拟它们在发动机中的燃烧。本文报道了正烷基苯和十五烷二元混合物的密度、粘度和声速及其相应的超摩尔体积(VmE)、超声速(cE)、超等熵可压缩性(ΚsE)和粘度偏差(Δη)。一般来说,除了甲苯、乙苯、丙苯和丁基苯混合物的声速外,混合物的密度、粘度和声速随摩尔分数的变化而单调增加。这些属性可用于燃料建模目的。VmE值、Δη值、cE值和KsE值分别为0.04 ~ 0.56 cm·mol-1、- 0.14 ~ 0.09 mPa·s、- 14.8 ~ 2.5 m·s - 1和- 2.2 ~ 18.1 TPa-1。在293.15 K时,增加正烷基苯的掺量(至十二烷基苯)使等摩尔混合物的VmE′s、Δη′s和KsE′s降低,cE′s升高。较小的正烷基苯分子的性质受芳香族的影响较大。与正烷基环己烷/十五烷混合物相比,正烷基苯/十五烷混合物Δη的趋势相似,但VmE、cE和KsE的趋势不同,表明苄基和环己基的分子相互作用对体积和可压缩性的影响大于对粘度的影响。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Binary Mixtures of n-Alkylbenzenes and Pentadecane: Densities, Speeds of Sound, and Viscosities within the Range of 288.15 and 333.15 K and at 0.1 MPa

The physical properties of mixtures of alkanes and aromatic compounds can aid in the understanding and modeling of their combustion in engines. Herein, densities, viscosities, and speeds of sound of binary mixtures of n-alkylbenzenes with pentadecane and their corresponding excess molar volumes (VmE), excess speeds of sound (cE), excess isentropic compressibilities (ΚsE), and viscosity deviations (Δη) are reported. In general, mixture densities, viscosities, and speeds of sound increased monotonically with changing mole fractions, except for the speeds of sound of toluene, ethylbenzene, propylbenzene, and butylbenzene mixtures. These properties can be used for fuel modeling purposes. VmE’s, Δη’s, cE’s, and KsE’s ranged from 0.04 to 0.56 cm·mol–1, −0.14 to 0.09 mPa·s, −14.8 to 2.5 m·s–1, and −2.2 to 18.1 TPa–1, respectively. Increasing the n-alkylbenzene size (up to decylbenzene) caused the equimolar mixture’s VmE’s, Δη’s, and KsE’s to decrease and cE’s to increase at 293.15 K. The properties of smaller n-alkylbenzene molecules were more affected by the aromatic group. In comparison with n-alkylcyclohexane/pentadecane mixtures, n-alkylbenzene/pentadecane mixture Δη trends were similar, but VmE’s, cE’s, and KsE’s trends were different, suggesting that molecular interactions of the benzyl and cyclohexyl groups affect volume and compressibility more than they affect viscosity.

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来源期刊
Journal of Chemical & Engineering Data
Journal of Chemical & Engineering Data 工程技术-工程:化工
CiteScore
5.20
自引率
19.20%
发文量
324
审稿时长
2.2 months
期刊介绍: The Journal of Chemical & Engineering Data is a monthly journal devoted to the publication of data obtained from both experiment and computation, which are viewed as complementary. It is the only American Chemical Society journal primarily concerned with articles containing data on the phase behavior and the physical, thermodynamic, and transport properties of well-defined materials, including complex mixtures of known compositions. While environmental and biological samples are of interest, their compositions must be known and reproducible. As a result, adsorption on natural product materials does not generally fit within the scope of Journal of Chemical & Engineering Data.
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