{"title":"二维过渡金属二氯化物气体传感器的研究进展。","authors":"Chandan Patra*, , , Vijay Kumar Guna, , , Sohini Chakraborty, , , Subrata Mondal, , and , Yerumbu Nandakishora, ","doi":"10.1021/acssensors.5c02126","DOIUrl":null,"url":null,"abstract":"<p >Two-dimensional (2D) transition metal dichalcogenides (TMDs), such as MoS<sub>2</sub>, MoSe<sub>2</sub>, MoTe<sub>2</sub>, WS<sub>2</sub>, TaS<sub>2</sub>, and VS<sub>2</sub> have emerged as highly promising candidates for next-generation gas sensors due to their unique electrical, chemical, and mechanical properties. Their high surface-to-volume ratio, tunable bandgaps, and ability to operate at room temperature make them particularly attractive for low-power, highly sensitive, and selective detection of toxic gases such as NO<sub>2</sub>, NH<sub>3</sub>, CO, and H<sub>2</sub>S. These characteristics are especially relevant for modern applications in flexible and wearable electronics, where sensors must be compact, efficient, and compatible with Internet of things (IoT) technologies. This review critically examines recent advancements in TMD-based gas sensors, with a focus on synthesis strategies (e.g., chemical vapor deposition, exfoliation, and hydrothermal methods), sensing mechanisms, and performance metrics including sensitivity, selectivity, and response/recovery times. Furthermore, we discuss enhancement techniques such as defect engineering, doping, heterostructuring, and surface functionalization to improve sensor performance. The review concludes with an outlook on the key challenges and future directions for integrating TMD-based sensors into scalable, energy-efficient, and commercially viable environmental monitoring systems.</p>","PeriodicalId":24,"journal":{"name":"ACS Sensors","volume":"10 9","pages":"6347–6379"},"PeriodicalIF":9.1000,"publicationDate":"2025-09-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Advances in 2D Transition Metal Dichalcogenide-Based Gas Sensors\",\"authors\":\"Chandan Patra*, , , Vijay Kumar Guna, , , Sohini Chakraborty, , , Subrata Mondal, , and , Yerumbu Nandakishora, \",\"doi\":\"10.1021/acssensors.5c02126\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p >Two-dimensional (2D) transition metal dichalcogenides (TMDs), such as MoS<sub>2</sub>, MoSe<sub>2</sub>, MoTe<sub>2</sub>, WS<sub>2</sub>, TaS<sub>2</sub>, and VS<sub>2</sub> have emerged as highly promising candidates for next-generation gas sensors due to their unique electrical, chemical, and mechanical properties. Their high surface-to-volume ratio, tunable bandgaps, and ability to operate at room temperature make them particularly attractive for low-power, highly sensitive, and selective detection of toxic gases such as NO<sub>2</sub>, NH<sub>3</sub>, CO, and H<sub>2</sub>S. These characteristics are especially relevant for modern applications in flexible and wearable electronics, where sensors must be compact, efficient, and compatible with Internet of things (IoT) technologies. This review critically examines recent advancements in TMD-based gas sensors, with a focus on synthesis strategies (e.g., chemical vapor deposition, exfoliation, and hydrothermal methods), sensing mechanisms, and performance metrics including sensitivity, selectivity, and response/recovery times. Furthermore, we discuss enhancement techniques such as defect engineering, doping, heterostructuring, and surface functionalization to improve sensor performance. The review concludes with an outlook on the key challenges and future directions for integrating TMD-based sensors into scalable, energy-efficient, and commercially viable environmental monitoring systems.</p>\",\"PeriodicalId\":24,\"journal\":{\"name\":\"ACS Sensors\",\"volume\":\"10 9\",\"pages\":\"6347–6379\"},\"PeriodicalIF\":9.1000,\"publicationDate\":\"2025-09-12\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"ACS Sensors\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://pubs.acs.org/doi/10.1021/acssensors.5c02126\",\"RegionNum\":1,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, ANALYTICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"ACS Sensors","FirstCategoryId":"92","ListUrlMain":"https://pubs.acs.org/doi/10.1021/acssensors.5c02126","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, ANALYTICAL","Score":null,"Total":0}
Advances in 2D Transition Metal Dichalcogenide-Based Gas Sensors
Two-dimensional (2D) transition metal dichalcogenides (TMDs), such as MoS2, MoSe2, MoTe2, WS2, TaS2, and VS2 have emerged as highly promising candidates for next-generation gas sensors due to their unique electrical, chemical, and mechanical properties. Their high surface-to-volume ratio, tunable bandgaps, and ability to operate at room temperature make them particularly attractive for low-power, highly sensitive, and selective detection of toxic gases such as NO2, NH3, CO, and H2S. These characteristics are especially relevant for modern applications in flexible and wearable electronics, where sensors must be compact, efficient, and compatible with Internet of things (IoT) technologies. This review critically examines recent advancements in TMD-based gas sensors, with a focus on synthesis strategies (e.g., chemical vapor deposition, exfoliation, and hydrothermal methods), sensing mechanisms, and performance metrics including sensitivity, selectivity, and response/recovery times. Furthermore, we discuss enhancement techniques such as defect engineering, doping, heterostructuring, and surface functionalization to improve sensor performance. The review concludes with an outlook on the key challenges and future directions for integrating TMD-based sensors into scalable, energy-efficient, and commercially viable environmental monitoring systems.
期刊介绍:
ACS Sensors is a peer-reviewed research journal that focuses on the dissemination of new and original knowledge in the field of sensor science, particularly those that selectively sense chemical or biological species or processes. The journal covers a broad range of topics, including but not limited to biosensors, chemical sensors, gas sensors, intracellular sensors, single molecule sensors, cell chips, and microfluidic devices. It aims to publish articles that address conceptual advances in sensing technology applicable to various types of analytes or application papers that report on the use of existing sensing concepts in new ways or for new analytes.