C-OCF3键转换的战略进展。

IF 4.2 2区化学 Q2 CHEMISTRY, MULTIDISCIPLINARY

Chemical Communications Pub Date : 2025-09-11 DOI:10.1039/d5cc03991f

Zhenbang Chang, Arushi Garg, Tatiana Besset

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引用次数: 0

摘要

虽然近年来合成三氟甲氧基芳烃的合成发展蓬勃发展，但C-OCF3键的裂解仍然是一个小众话题，也是一个需要克服的合成挑战。本文综述了激活强芳基C-OCF3键，使C-C、C-H和c -杂原子键形成的主要进展。这些进展强调了这一新兴领域进一步发展的变革潜力。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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Strategic advances in C-OCF₃ bond transformations.

While synthetic developments for the synthesis of trifluoromethoxylated arenes have flourished over the years, the cleavage of a C-OCF₃ bond remains a niche topic and a synthetic challenge to overcome. This review provides an overview of major advances made in activating a strong aryl C-OCF₃ bond, enabling C-C, C-H, and C-Heteroatom bond formations. These advances underscore the transformative potential of further developments in this emerging field.

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来源期刊

Chemical Communications 化学-化学综合

CiteScore

8.60

自引率

4.10%

发文量

2705

审稿时长

1.4 months

期刊介绍： ChemComm (Chemical Communications) is renowned as the fastest publisher of articles providing information on new avenues of research, drawn from all the world''s major areas of chemical research.