硫脲与一氯乙酸在水中的反应：修正及其可能机理

IF 0.8 4区化学 Q4 CHEMISTRY, MULTIDISCIPLINARY

Russian Journal of General Chemistry Pub Date : 2025-09-10 DOI:10.1134/S1070363225602583

V. V. Andreeva, D. A. Smirnova, S. M. Ramsh

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引用次数: 0

摘要

研究了硫脲和一氯乙酸在水中的相互作用，包括在普通实验室温度下长时间保持反应混合物。在此基础上，结合文献资料，提出了中间产物假硫代氢酸盐酸盐和假硫代氢酸分别环化为假硫代氢酰盐酸盐和假硫代氢酰盐酸盐的反应转化方案和可能的环化机理。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Reaction of Thiourea with Monochloroacetic Acid in Water: Revision and Probable Mechanisms

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Reaction of Thiourea with Monochloroacetic Acid in Water: Revision and Probable Mechanisms

The interaction of thiourea and monochloroacetic acid in water was studied, including prolonged holding of the reaction mixture at ordinary laboratory temperature. Based on the results obtained, taking into account literature data, a scheme of the reaction transformations and probable mechanisms of cyclization of the intermediate pseudothiohygantoic acid hydrochloride and pseudothiohydantoic acid into pseudothiohydantoin hydrochloride and pseudothiohydantoin, respectively, was proposed.

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来源期刊

Russian Journal of General Chemistry 化学-化学综合

CiteScore

1.40

自引率

22.20%

发文量

252

审稿时长

2-4 weeks

期刊介绍： Russian Journal of General Chemistry is a journal that covers many problems that are of general interest to the whole community of chemists. The journal is the successor to Russia’s first chemical journal, Zhurnal Russkogo Khimicheskogo Obshchestva (Journal of the Russian Chemical Society ) founded in 1869 to cover all aspects of chemistry. Now the journal is focused on the interdisciplinary areas of chemistry (organometallics, organometalloids, organoinorganic complexes, mechanochemistry, nanochemistry, etc.), new achievements and long-term results in the field. The journal publishes reviews, current scientific papers, letters to the editor, and discussion papers.