吡啶二腈噻吩啉衍生物的合成及双态发射

IF 0.8 4区化学 Q4 CHEMISTRY, MULTIDISCIPLINARY

Russian Journal of General Chemistry Pub Date : 2025-09-10 DOI:10.1134/S1070363225603874

M. A. Shishlikova, A. I. Ershova, O. V. Ershov

{"title":"吡啶二腈噻吩啉衍生物的合成及双态发射","authors":"M. A. Shishlikova, A. I. Ershova, O. V. Ershov","doi":"10.1134/S1070363225603874","DOIUrl":null,"url":null,"abstract":"<p>A synthetic method for 2-thiomorpholinopyridine-3,4-dicarbonitrile derivatives was developed based on 2-chloropyridine-3,4-dicarbonitriles and thiomorpholine. The obtained compounds exhibit a rare type of dual-state emission (DSE), featuring fluorescence both in solution and in the solid state. The fluorescence maxima in benzene solution depend on the nature of the substituents and range from 470 to 508 nm, while in the solid state, they vary from 473 to 534 nm.</p>","PeriodicalId":761,"journal":{"name":"Russian Journal of General Chemistry","volume":"95 8","pages":"2266 - 2271"},"PeriodicalIF":0.8000,"publicationDate":"2025-09-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Synthesis and Dual-State Emission of Thiomorpholine Derivatives of Pyridinedicarbonitrile\",\"authors\":\"M. A. Shishlikova, A. I. Ershova, O. V. Ershov\",\"doi\":\"10.1134/S1070363225603874\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>A synthetic method for 2-thiomorpholinopyridine-3,4-dicarbonitrile derivatives was developed based on 2-chloropyridine-3,4-dicarbonitriles and thiomorpholine. The obtained compounds exhibit a rare type of dual-state emission (DSE), featuring fluorescence both in solution and in the solid state. The fluorescence maxima in benzene solution depend on the nature of the substituents and range from 470 to 508 nm, while in the solid state, they vary from 473 to 534 nm.</p>\",\"PeriodicalId\":761,\"journal\":{\"name\":\"Russian Journal of General Chemistry\",\"volume\":\"95 8\",\"pages\":\"2266 - 2271\"},\"PeriodicalIF\":0.8000,\"publicationDate\":\"2025-09-10\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Russian Journal of General Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1134/S1070363225603874\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Russian Journal of General Chemistry","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1134/S1070363225603874","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}

引用次数: 0

摘要

以2-氯吡啶-3,4-二碳腈和噻吩啉为原料，合成了2-硫代氨基吡啶-3,4-二碳腈衍生物。所获得的化合物表现出一种罕见的双态发射（DSE），在溶液和固体中都具有荧光。在苯溶液中，荧光最大值取决于取代基的性质，范围为470 ~ 508 nm，而在固态中，荧光最大值为473 ~ 534 nm。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Synthesis and Dual-State Emission of Thiomorpholine Derivatives of Pyridinedicarbonitrile

查看原文本刊更多论文

Synthesis and Dual-State Emission of Thiomorpholine Derivatives of Pyridinedicarbonitrile

A synthetic method for 2-thiomorpholinopyridine-3,4-dicarbonitrile derivatives was developed based on 2-chloropyridine-3,4-dicarbonitriles and thiomorpholine. The obtained compounds exhibit a rare type of dual-state emission (DSE), featuring fluorescence both in solution and in the solid state. The fluorescence maxima in benzene solution depend on the nature of the substituents and range from 470 to 508 nm, while in the solid state, they vary from 473 to 534 nm.

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

Russian Journal of General Chemistry 化学-化学综合

CiteScore

1.40

自引率

22.20%

发文量

252

审稿时长

2-4 weeks

期刊介绍： Russian Journal of General Chemistry is a journal that covers many problems that are of general interest to the whole community of chemists. The journal is the successor to Russia’s first chemical journal, Zhurnal Russkogo Khimicheskogo Obshchestva (Journal of the Russian Chemical Society ) founded in 1869 to cover all aspects of chemistry. Now the journal is focused on the interdisciplinary areas of chemistry (organometallics, organometalloids, organoinorganic complexes, mechanochemistry, nanochemistry, etc.), new achievements and long-term results in the field. The journal publishes reviews, current scientific papers, letters to the editor, and discussion papers.