{"title":"皮秒脉冲电子辐照损伤晶体硅太阳能电池的研究","authors":"Aram Sahakyan , Vachagan Harutyunyan , Norik Grigoryan , Arpine Martirosyan , Norair Martirosyan , Ashot Vardanyan , Christopher Rhodes , Eduard Aleksanyan","doi":"10.1016/j.solmat.2025.113956","DOIUrl":null,"url":null,"abstract":"<div><div>This study investigates the effects of picosecond electron irradiation on the performance parameters of commercial crystalline silicon solar cells fabricated using Passivated Emitter and Rear Contact (PERC) solar technology. The irradiation was performed using electrons with energies up to 3.6 MeV, a pulse current density of j<sub>pulse</sub> = 200 A/cm<sup>2</sup>, and a fluence of 5.4 × 10<sup>13</sup> e/cm<sup>2</sup>. Under these conditions the induced radiation defects are predominantly stable cluster-type defects, which is a result of the high electron beam peak intensity. The degradation of the silicon solar cells caused decrease of its parameters, such as the maximum power by more than 40 %. This phenomenon occurs at an electron irradiation fluence more than two orders of magnitude lower than previously reported in the literature for the same effect.</div><div>We propose a hypothesis to explain the open circuit voltage (V<sub>OC</sub>) behavior in irradiated silicon solar cells. Thus, in irradiated solar cells, charge layers are created within the insulator and at the semiconductor-insulator and/or semiconductor-metal interface, which creates electric field - directed oppositely to the field from the p-n junction. It has been shown that the electric field from these charged layers plays a significant role in reducing V<sub>OC</sub> in irradiated solar cells. We suggest that if a controlled charged layer could be created in a solar cell, the electric field direction from which is the same as that of the field from the p-n junction, then the V<sub>OC</sub> could be increased, thus enhancing the efficiency of the solar cells.</div></div>","PeriodicalId":429,"journal":{"name":"Solar Energy Materials and Solar Cells","volume":"295 ","pages":"Article 113956"},"PeriodicalIF":6.3000,"publicationDate":"2025-09-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Pico-second pulse electron irradiation damage studies in crystalline silicon solar cells\",\"authors\":\"Aram Sahakyan , Vachagan Harutyunyan , Norik Grigoryan , Arpine Martirosyan , Norair Martirosyan , Ashot Vardanyan , Christopher Rhodes , Eduard Aleksanyan\",\"doi\":\"10.1016/j.solmat.2025.113956\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>This study investigates the effects of picosecond electron irradiation on the performance parameters of commercial crystalline silicon solar cells fabricated using Passivated Emitter and Rear Contact (PERC) solar technology. The irradiation was performed using electrons with energies up to 3.6 MeV, a pulse current density of j<sub>pulse</sub> = 200 A/cm<sup>2</sup>, and a fluence of 5.4 × 10<sup>13</sup> e/cm<sup>2</sup>. Under these conditions the induced radiation defects are predominantly stable cluster-type defects, which is a result of the high electron beam peak intensity. The degradation of the silicon solar cells caused decrease of its parameters, such as the maximum power by more than 40 %. This phenomenon occurs at an electron irradiation fluence more than two orders of magnitude lower than previously reported in the literature for the same effect.</div><div>We propose a hypothesis to explain the open circuit voltage (V<sub>OC</sub>) behavior in irradiated silicon solar cells. Thus, in irradiated solar cells, charge layers are created within the insulator and at the semiconductor-insulator and/or semiconductor-metal interface, which creates electric field - directed oppositely to the field from the p-n junction. It has been shown that the electric field from these charged layers plays a significant role in reducing V<sub>OC</sub> in irradiated solar cells. We suggest that if a controlled charged layer could be created in a solar cell, the electric field direction from which is the same as that of the field from the p-n junction, then the V<sub>OC</sub> could be increased, thus enhancing the efficiency of the solar cells.</div></div>\",\"PeriodicalId\":429,\"journal\":{\"name\":\"Solar Energy Materials and Solar Cells\",\"volume\":\"295 \",\"pages\":\"Article 113956\"},\"PeriodicalIF\":6.3000,\"publicationDate\":\"2025-09-10\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Solar Energy Materials and Solar Cells\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0927024825005574\",\"RegionNum\":2,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"ENERGY & FUELS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Solar Energy Materials and Solar Cells","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0927024825005574","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"ENERGY & FUELS","Score":null,"Total":0}
引用次数: 0
摘要
研究了皮秒电子辐照对采用钝化发射极和后接触(PERC)太阳能技术制备的商用晶体硅太阳电池性能参数的影响。辐照的电子能量高达3.6 MeV,脉冲电流密度为jpulse = 200 a /cm2,影响为5.4 × 1013 e/cm2。在这种条件下,由于电子束峰值强度高,诱导辐射缺陷主要是稳定的团簇型缺陷。硅太阳能电池的退化导致其各项参数下降,如最大功率下降40%以上。这种现象发生在电子辐照强度比先前文献报道的相同效果低两个数量级以上的情况下。我们提出了一个假设来解释辐照硅太阳能电池的开路电压(VOC)行为。因此,在辐照太阳能电池中,电荷层在绝缘体内部和半导体-绝缘体和/或半导体-金属界面处产生,从而产生与pn结方向相反的电场。研究表明,来自这些带电层的电场在减少辐照太阳能电池中的VOC方面起着重要作用。我们建议在太阳能电池中建立一个受控带电层,使其电场方向与p-n结电场方向相同,则可以增加VOC,从而提高太阳能电池的效率。
Pico-second pulse electron irradiation damage studies in crystalline silicon solar cells
This study investigates the effects of picosecond electron irradiation on the performance parameters of commercial crystalline silicon solar cells fabricated using Passivated Emitter and Rear Contact (PERC) solar technology. The irradiation was performed using electrons with energies up to 3.6 MeV, a pulse current density of jpulse = 200 A/cm2, and a fluence of 5.4 × 1013 e/cm2. Under these conditions the induced radiation defects are predominantly stable cluster-type defects, which is a result of the high electron beam peak intensity. The degradation of the silicon solar cells caused decrease of its parameters, such as the maximum power by more than 40 %. This phenomenon occurs at an electron irradiation fluence more than two orders of magnitude lower than previously reported in the literature for the same effect.
We propose a hypothesis to explain the open circuit voltage (VOC) behavior in irradiated silicon solar cells. Thus, in irradiated solar cells, charge layers are created within the insulator and at the semiconductor-insulator and/or semiconductor-metal interface, which creates electric field - directed oppositely to the field from the p-n junction. It has been shown that the electric field from these charged layers plays a significant role in reducing VOC in irradiated solar cells. We suggest that if a controlled charged layer could be created in a solar cell, the electric field direction from which is the same as that of the field from the p-n junction, then the VOC could be increased, thus enhancing the efficiency of the solar cells.
期刊介绍:
Solar Energy Materials & Solar Cells is intended as a vehicle for the dissemination of research results on materials science and technology related to photovoltaic, photothermal and photoelectrochemical solar energy conversion. Materials science is taken in the broadest possible sense and encompasses physics, chemistry, optics, materials fabrication and analysis for all types of materials.