Komal Ali Rao, Muhammad Rizwan Saleem, Muhammad Ehsan Mazhar, Javed Ahmad, Muhammad Imran Khan, Muhammad Bilal, Waseem Abbas, Nargis Bano, Aqsa Naz, Abdallah Shanableh, Mehak Bukhari, Rafael Luque
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To overcome this challenge, different metal-based oxides with MXene composites, namely, MCo<sub>2</sub>O<sub>4</sub>/composite (where M = Ni and Zn), were synthesized using a simple cost-effective hydrothermal method through a self-assembly process. These heterostructure composites reduced the specific capacitance loss brought on by volumetric variations by preventing MXene layers from restacking and at the same time improving the exposure of electrochemically active sites in MCo<sub>2</sub>O<sub>4</sub>/composite. Structural, morphological, and electrochemical analysis revealed that both composites have efficient and remarkable electrochemical properties with unique morphology. Detailed electrochemical analysis revealed that NiCo<sub>2</sub>O<sub>4</sub>/MXene have pseudocapacitive behavior with greater specific capacitance as compared with ZnCo<sub>2</sub>O<sub>4</sub>/MXene. NiCo<sub>2</sub>O<sub>4</sub>/MXene exhibited specific capacitance of 1575 F g<sup>−1</sup> at 1 A g<sup>−1</sup> with 89% cyclic stability over 10,000 cycles. Moreover, asymmetric supercapacitors constructed using NiCo<sub>2</sub>O<sub>4</sub>@Nb₂C as cathode and commercial activated carbon (AC) as anode demonstrated a high energy density of 31.2 Wh kg<sup>−1</sup> at a power density of 800 W kg<sup>−1</sup> Additionally, they exhibited excellent long-term cycling stability, retaining 81.2% of their initial capacitance after 5000 cycles.</p>\n </div>","PeriodicalId":8344,"journal":{"name":"Applied Organometallic Chemistry","volume":"39 10","pages":""},"PeriodicalIF":3.7000,"publicationDate":"2025-09-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Hydrothermal Synthesis of Bimetallic Spinel MCo2O4/MXene (M = Ni, Zn) Composites as Efficient Supercapacitor Electrodes\",\"authors\":\"Komal Ali Rao, Muhammad Rizwan Saleem, Muhammad Ehsan Mazhar, Javed Ahmad, Muhammad Imran Khan, Muhammad Bilal, Waseem Abbas, Nargis Bano, Aqsa Naz, Abdallah Shanableh, Mehak Bukhari, Rafael Luque\",\"doi\":\"10.1002/aoc.70390\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div>\\n \\n <p>MXene is an ideal choice for electrode material in supercapacitors due to its outstanding metallic conductivity, hydrophilic nature, and surface redox activity as well as superior chemical stability. 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引用次数: 0
摘要
由于其优异的金属导电性、亲水性、表面氧化还原活性以及优异的化学稳定性,MXene是超级电容器电极材料的理想选择。二维(2D)金属碳化物NbC2Tₓ-MXene显示出作为储能应用的赝电容电极材料的巨大潜力。然而,重新堆叠的MXene层使得离子难以进入,从而降低了体积性能,也减少了离子和电子的传递。为了克服这一挑战,采用一种简单经济的水热方法通过自组装工艺合成了不同的金属基氧化物MXene复合材料,即MCo2O4/复合材料(其中M = Ni和Zn)。这些异质结构复合材料通过防止MXene层重新堆积,减少了体积变化带来的比电容损失,同时改善了MCo2O4/复合材料中电化学活性位点的暴露。结构、形态和电化学分析表明,这两种复合材料具有独特的形貌和高效的电化学性能。详细的电化学分析表明,NiCo2O4/MXene与ZnCo2O4/MXene相比具有更大的比电容,具有假电容行为。NiCo2O4/MXene在1 A g−1时的比电容为1575 F g−1,在10,000次循环中具有89%的循环稳定性。此外,以NiCo2O4@Nb₂C为阴极,商用活性炭(AC)为阳极构建的非对称超级电容器在功率密度为800 W kg - 1时表现出31.2 Wh kg - 1的高能量密度,此外,它们表现出出色的长期循环稳定性,在5000次循环后保持了81.2%的初始电容。
Hydrothermal Synthesis of Bimetallic Spinel MCo2O4/MXene (M = Ni, Zn) Composites as Efficient Supercapacitor Electrodes
MXene is an ideal choice for electrode material in supercapacitors due to its outstanding metallic conductivity, hydrophilic nature, and surface redox activity as well as superior chemical stability. The two-dimensional (2D) metal carbide NbC2Tₓ-MXene exhibits significant potential as a pseudocapacitive electrode material for energy storage applications. Restacking of MXene's layers makes, however, difficult access of ions, which lowers volumetric performance and also reduces ion and electron transport. To overcome this challenge, different metal-based oxides with MXene composites, namely, MCo2O4/composite (where M = Ni and Zn), were synthesized using a simple cost-effective hydrothermal method through a self-assembly process. These heterostructure composites reduced the specific capacitance loss brought on by volumetric variations by preventing MXene layers from restacking and at the same time improving the exposure of electrochemically active sites in MCo2O4/composite. Structural, morphological, and electrochemical analysis revealed that both composites have efficient and remarkable electrochemical properties with unique morphology. Detailed electrochemical analysis revealed that NiCo2O4/MXene have pseudocapacitive behavior with greater specific capacitance as compared with ZnCo2O4/MXene. NiCo2O4/MXene exhibited specific capacitance of 1575 F g−1 at 1 A g−1 with 89% cyclic stability over 10,000 cycles. Moreover, asymmetric supercapacitors constructed using NiCo2O4@Nb₂C as cathode and commercial activated carbon (AC) as anode demonstrated a high energy density of 31.2 Wh kg−1 at a power density of 800 W kg−1 Additionally, they exhibited excellent long-term cycling stability, retaining 81.2% of their initial capacitance after 5000 cycles.
期刊介绍:
All new compounds should be satisfactorily identified and proof of their structure given according to generally accepted standards. Structural reports, such as papers exclusively dealing with synthesis and characterization, analytical techniques, or X-ray diffraction studies of metal-organic or organometallic compounds will not be considered. The editors reserve the right to refuse without peer review any manuscript that does not comply with the aims and scope of the journal. Applied Organometallic Chemistry publishes Full Papers, Reviews, Mini Reviews and Communications of scientific research in all areas of organometallic and metal-organic chemistry involving main group metals, transition metals, lanthanides and actinides. All contributions should contain an explicit application of novel compounds, for instance in materials science, nano science, catalysis, chemical vapour deposition, metal-mediated organic synthesis, polymers, bio-organometallics, metallo-therapy, metallo-diagnostics and medicine. Reviews of books covering aspects of the fields of focus are also published.