ZnO掺杂氧化石墨烯修饰在聚苯乙烯-共马来酸酐上的高性能超级电容器

IF 4.9 3区 化学 Q2 POLYMER SCIENCE
Remya Simon, Sohini Chakraborty, D. Elias Jesu Packiam, Dona Mary Sam, K. S. Darshini, Nisha George, N. L. Mary
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引用次数: 0

摘要

由于最近新型储能技术的发展激增,独特的组合物已经出现,旨在拓宽这一研究领域。我们早期的研究已经描述了噻二唑和二胺改性聚苯乙烯-共马来酸酐及其纳米复合材料作为高效储能器件的电化学性能。在这里,我们的目标是通过将氧化石墨烯(GO)和氧化锌(ZnO)纳米颗粒掺入聚苯乙烯-共马来酸酐的聚合物基体中,进一步改进这种支架。氧化石墨烯和氧化锌纳米粒子在赝电容和双电层电容的协同作用下形成纳米复合材料。对这些样品进行了广泛的表征,以证实它们的光谱、形态和热性能。此外,还对其进行了电化学测试,以评估其超电容性能。所制备的超级电容器电极在5 mV s−1下具有850 Fg−1的高比电容,在1 a g−1下循环1000次后电容保持率为93%。基于这些特性,所制备的纳米复合材料显示出巨大的潜力,被认为是传统超级电容器的潜在替代品。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
ZnO Doped GO Decorated on Poly (Styrene-Co-Maleic Anhydride) for High Performance Supercapacitors

Due to the recent surge in the development of novel energy storage technologies, unique compositions have emerged which aim to broaden this field of study. Our earlier investigations have depicted the electrochemical performances of thiadiazole and diamine modified poly (styrene-co-maleic anhydride) and their nanocomposites for efficient energy storage devices. Here, we aim to improve this scaffold further through the incorporation of Graphene oxide (GO) and Zinc oxide (ZnO) nanoparticles to the polymer matrix of poly (styrene-co-maleic anhydride). GO and ZnO NPs impart synergistic effects of both pseudocapacitance and electrical double layer capacitance to the resultant nanocomposite. These samples have been characterized extensively to substantiate their spectral, morphological and thermal properties. Additionally, they have been subjected to electrochemical testing to evaluate their supercapacitive performance. The developed supercapacitor electrodes exhibit a high specific capacitance of 850 Fg− 1 at 5 mV s−1 coupled with a capacitance retention of 93% after 1000 cycles at 1 A g− 1. Based on these attributes, the prepared nanocomposites exhibited great potential to be considered as potential alternatives to conventional supercapacitors.

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来源期刊
CiteScore
8.30
自引率
7.50%
发文量
335
审稿时长
1.8 months
期刊介绍: Journal of Inorganic and Organometallic Polymers and Materials [JIOP or JIOPM] is a comprehensive resource for reports on the latest theoretical and experimental research. This bimonthly journal encompasses a broad range of synthetic and natural substances which contain main group, transition, and inner transition elements. The publication includes fully peer-reviewed original papers and shorter communications, as well as topical review papers that address the synthesis, characterization, evaluation, and phenomena of inorganic and organometallic polymers, materials, and supramolecular systems.
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