机制定制的二维金属纳米片用于先进的电催化二氧化碳还原:从结构设计到实际应用

IF 4.5 3区 工程技术 Q2 ENGINEERING, CHEMICAL
Zhijian Li, Deqing Kong, Yu Sun, Yifan Shao, Xi Wang
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引用次数: 0

摘要

电化学二氧化碳还原反应(CO2RR)是可持续碳循环和化学合成的关键策略。本文综合分析了二维(2D)金属纳米片(如Bi, Ag, Co, Pd, Cu)作为CO2RR的高性能电催化剂的新兴领域。我们深入研究了它们在气相(如CO, CH4, C2H4)和液相(如HCOOH, CH3OH, C2H5OH)产物形成途径中活性的基本催化机制,特别侧重于破译关键的构效关系。关键的内在性质:组成,暴露的晶体面,和缺陷工程,被系统地检查,以阐明他们对催化活性,选择性和产品分布的深刻影响。除了机理方面的见解,本文还对这些2D金属催化剂的实际用途进行了批判性评估,重点介绍了新兴应用、持续挑战(例如,可扩展性、长期稳定性、竞争性反应、C2+选择性控制)以及未来有希望的研究轨迹。通过将基本催化原理与应用材料设计相结合,这项工作为推进对实现碳中和目标至关重要的高效和选择性CO2RR技术提供了新的视角。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Mechanism-tailored two-dimensional metal nanosheets for advanced electrocatalytic CO2 reduction: from structural design to practical application

Electrochemical carbon dioxide reduction reaction (CO2RR) represents a pivotal strategy for sustainable carbon cycling and chemical synthesis. This review comprehensively analyzes the burgeoning field of two-dimensional (2D) metal nanosheets (e.g., Bi, Ag, Co, Pd, Cu) as high-performance electrocatalysts for CO2RR. We delve into the fundamental catalytic mechanisms underpinning their activity across both gas-phase (e.g., CO, CH4, C2H4) and liquid-phase (e.g., HCOOH, CH3OH, C2H5OH) product formation pathways, with a particular focus on deciphering critical structure-activity relationships. Key intrinsic properties: composition, exposed crystal facets, and defect engineering, are systematically examined to elucidate their profound influence on catalytic activity, selectivity, and product distribution. Beyond mechanistic insights, the review critically assesses the practical utility of these 2D metal catalysts, highlighting emerging applications, persistent challenges (e.g., scalability, long-term stability, competitive reactions, C2+ selectivity control), and promising future research trajectories. By bridging fundamental catalytic principles with applied materials design, this work provides novel perspectives for advancing efficient and selective CO2RR technologies crucial for achieving carbon neutrality goals.

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来源期刊
CiteScore
7.60
自引率
6.70%
发文量
868
审稿时长
1 months
期刊介绍: Frontiers of Chemical Science and Engineering presents the latest developments in chemical science and engineering, emphasizing emerging and multidisciplinary fields and international trends in research and development. The journal promotes communication and exchange between scientists all over the world. The contents include original reviews, research papers and short communications. Coverage includes catalysis and reaction engineering, clean energy, functional material, nanotechnology and nanoscience, biomaterials and biotechnology, particle technology and multiphase processing, separation science and technology, sustainable technologies and green processing.
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