{"title":"硼化学的最新进展","authors":"Cheng Chen, Zhengwei Ding, Yan Gao, Yi Jing, Yong-An Luo, Xingxing Ma, Xuenian Chen, Pengfei Li, Zaozao Qiu, Qiuling Song, Xiao-Ye Wang, Zuowei Xie","doi":"10.1007/s11426-025-2886-2","DOIUrl":null,"url":null,"abstract":"<div><p>Boron, positioned to the left of carbon in the periodic table with one fewer electron, exhibits unique chemical properties. Tricoordinate boron compounds are typically electron-deficient, acting as strong Lewis acids in general with electrophilic behavior. In contrast, tetracoordinate boron compounds, featuring a tetrahedral geometry, display nucleophilicity and enable transformations such as migration, transmetallation, and oxidation. Boron compounds serve as versatile synthons, reagents, and catalysts in organic reactions. Incorporating boron into conjugated systems enhances chemical diversity and modulates optoelectronic properties, while the vacant p orbital of boron imparts high electron affinity and unique stimulus-responsive characteristics. Additionally, boron forms deltahedral clusters in polyhedral (car)boranes, which are air-and moisture-stable and distinct from traditional hydrocarbon structures. This review provides an overview of the fundamental properties and diverse applications of boron compounds across various fields.\n</p><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":772,"journal":{"name":"Science China Chemistry","volume":"68 9","pages":"3927 - 3995"},"PeriodicalIF":9.7000,"publicationDate":"2025-07-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Recent advances in boron chemistry\",\"authors\":\"Cheng Chen, Zhengwei Ding, Yan Gao, Yi Jing, Yong-An Luo, Xingxing Ma, Xuenian Chen, Pengfei Li, Zaozao Qiu, Qiuling Song, Xiao-Ye Wang, Zuowei Xie\",\"doi\":\"10.1007/s11426-025-2886-2\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Boron, positioned to the left of carbon in the periodic table with one fewer electron, exhibits unique chemical properties. Tricoordinate boron compounds are typically electron-deficient, acting as strong Lewis acids in general with electrophilic behavior. In contrast, tetracoordinate boron compounds, featuring a tetrahedral geometry, display nucleophilicity and enable transformations such as migration, transmetallation, and oxidation. Boron compounds serve as versatile synthons, reagents, and catalysts in organic reactions. Incorporating boron into conjugated systems enhances chemical diversity and modulates optoelectronic properties, while the vacant p orbital of boron imparts high electron affinity and unique stimulus-responsive characteristics. Additionally, boron forms deltahedral clusters in polyhedral (car)boranes, which are air-and moisture-stable and distinct from traditional hydrocarbon structures. This review provides an overview of the fundamental properties and diverse applications of boron compounds across various fields.\\n</p><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>\",\"PeriodicalId\":772,\"journal\":{\"name\":\"Science China Chemistry\",\"volume\":\"68 9\",\"pages\":\"3927 - 3995\"},\"PeriodicalIF\":9.7000,\"publicationDate\":\"2025-07-28\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Science China Chemistry\",\"FirstCategoryId\":\"1\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s11426-025-2886-2\",\"RegionNum\":1,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Science China Chemistry","FirstCategoryId":"1","ListUrlMain":"https://link.springer.com/article/10.1007/s11426-025-2886-2","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Boron, positioned to the left of carbon in the periodic table with one fewer electron, exhibits unique chemical properties. Tricoordinate boron compounds are typically electron-deficient, acting as strong Lewis acids in general with electrophilic behavior. In contrast, tetracoordinate boron compounds, featuring a tetrahedral geometry, display nucleophilicity and enable transformations such as migration, transmetallation, and oxidation. Boron compounds serve as versatile synthons, reagents, and catalysts in organic reactions. Incorporating boron into conjugated systems enhances chemical diversity and modulates optoelectronic properties, while the vacant p orbital of boron imparts high electron affinity and unique stimulus-responsive characteristics. Additionally, boron forms deltahedral clusters in polyhedral (car)boranes, which are air-and moisture-stable and distinct from traditional hydrocarbon structures. This review provides an overview of the fundamental properties and diverse applications of boron compounds across various fields.
期刊介绍：
Science China Chemistry, co-sponsored by the Chinese Academy of Sciences and the National Natural Science Foundation of China and published by Science China Press, publishes high-quality original research in both basic and applied chemistry. Indexed by Science Citation Index, it is a premier academic journal in the field.
Categories of articles include:
Highlights. Brief summaries and scholarly comments on recent research achievements in any field of chemistry.
Perspectives. Concise reports on thelatest chemistry trends of interest to scientists worldwide, including discussions of research breakthroughs and interpretations of important science and funding policies.
Reviews. In-depth summaries of representative results and achievements of the past 5–10 years in selected topics based on or closely related to the research expertise of the authors, providing a thorough assessment of the significance, current status, and future research directions of the field.
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