Andrei V. Polkovnichenko, Evgenia I. Kovaleva, Alexey V. Kisel’, Sergey Ya. Kvashnin, Maria V. Mironova, Egor V. Lupachev
{"title":"2,2,3,3,4,4,4 -七氟-1-丁醇和2,2,3,3,3,4,4,4 -七氟-乙酸丁酯:物理化学、热物理和光谱数据","authors":"Andrei V. Polkovnichenko, Evgenia I. Kovaleva, Alexey V. Kisel’, Sergey Ya. Kvashnin, Maria V. Mironova, Egor V. Lupachev","doi":"10.1007/s10765-025-03640-3","DOIUrl":null,"url":null,"abstract":"<div><p>New physicochemical data for 2, 2, 3, 3, 4, 4, 4-heptafluoro-1-butanol (≥ 0.998 mass fr.) and 2, 2, 3, 3, 4, 4, 4-heptafluorobutyl acetate (≥ 0.994 mass fr.) are presented. The dependences of the saturated vapor pressure of 2, 2, 3, 3, 4, 4, 4-heptafluoro-1-butanol and 2, 2, 3, 3, 4, 4, 4-heptafluorobutyl acetate on temperature were obtained. The coefficients of Antoine’s equation are calculated based on the experimental temperature–pressure dependence data. This article also presents data on the rheological properties (viscosity and apparent activation energy for the viscous flow) of the studied compounds. The dependencies of refractive index and excess volume (density) on temperature are studied. Fourier transform infrared spectroscopy spectra are also provided. The experimental data presented in this paper extend and complement the information presented in the scientific literature. These data are background information and a starting point for further research in engineering design of chemical processing equipment. In addition, the received data may support the development of property models of pure substances and systems containing them, such as phase behavior and the processes underlying it.</p></div>","PeriodicalId":598,"journal":{"name":"International Journal of Thermophysics","volume":"46 11","pages":""},"PeriodicalIF":2.9000,"publicationDate":"2025-09-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"2, 2, 3, 3, 4, 4, 4-Heptafluoro-1-Butanol and 2, 2, 3, 3, 4, 4, 4-Heptafluorobutyl Acetate: Physicochemical, Thermophysical, and Spectral Data\",\"authors\":\"Andrei V. Polkovnichenko, Evgenia I. Kovaleva, Alexey V. Kisel’, Sergey Ya. Kvashnin, Maria V. Mironova, Egor V. Lupachev\",\"doi\":\"10.1007/s10765-025-03640-3\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>New physicochemical data for 2, 2, 3, 3, 4, 4, 4-heptafluoro-1-butanol (≥ 0.998 mass fr.) and 2, 2, 3, 3, 4, 4, 4-heptafluorobutyl acetate (≥ 0.994 mass fr.) are presented. The dependences of the saturated vapor pressure of 2, 2, 3, 3, 4, 4, 4-heptafluoro-1-butanol and 2, 2, 3, 3, 4, 4, 4-heptafluorobutyl acetate on temperature were obtained. The coefficients of Antoine’s equation are calculated based on the experimental temperature–pressure dependence data. This article also presents data on the rheological properties (viscosity and apparent activation energy for the viscous flow) of the studied compounds. The dependencies of refractive index and excess volume (density) on temperature are studied. Fourier transform infrared spectroscopy spectra are also provided. The experimental data presented in this paper extend and complement the information presented in the scientific literature. These data are background information and a starting point for further research in engineering design of chemical processing equipment. In addition, the received data may support the development of property models of pure substances and systems containing them, such as phase behavior and the processes underlying it.</p></div>\",\"PeriodicalId\":598,\"journal\":{\"name\":\"International Journal of Thermophysics\",\"volume\":\"46 11\",\"pages\":\"\"},\"PeriodicalIF\":2.9000,\"publicationDate\":\"2025-09-08\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"International Journal of Thermophysics\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s10765-025-03640-3\",\"RegionNum\":4,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"International Journal of Thermophysics","FirstCategoryId":"5","ListUrlMain":"https://link.springer.com/article/10.1007/s10765-025-03640-3","RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
2, 2, 3, 3, 4, 4, 4-Heptafluoro-1-Butanol and 2, 2, 3, 3, 4, 4, 4-Heptafluorobutyl Acetate: Physicochemical, Thermophysical, and Spectral Data
New physicochemical data for 2, 2, 3, 3, 4, 4, 4-heptafluoro-1-butanol (≥ 0.998 mass fr.) and 2, 2, 3, 3, 4, 4, 4-heptafluorobutyl acetate (≥ 0.994 mass fr.) are presented. The dependences of the saturated vapor pressure of 2, 2, 3, 3, 4, 4, 4-heptafluoro-1-butanol and 2, 2, 3, 3, 4, 4, 4-heptafluorobutyl acetate on temperature were obtained. The coefficients of Antoine’s equation are calculated based on the experimental temperature–pressure dependence data. This article also presents data on the rheological properties (viscosity and apparent activation energy for the viscous flow) of the studied compounds. The dependencies of refractive index and excess volume (density) on temperature are studied. Fourier transform infrared spectroscopy spectra are also provided. The experimental data presented in this paper extend and complement the information presented in the scientific literature. These data are background information and a starting point for further research in engineering design of chemical processing equipment. In addition, the received data may support the development of property models of pure substances and systems containing them, such as phase behavior and the processes underlying it.
期刊介绍:
International Journal of Thermophysics serves as an international medium for the publication of papers in thermophysics, assisting both generators and users of thermophysical properties data. This distinguished journal publishes both experimental and theoretical papers on thermophysical properties of matter in the liquid, gaseous, and solid states (including soft matter, biofluids, and nano- and bio-materials), on instrumentation and techniques leading to their measurement, and on computer studies of model and related systems. Studies in all ranges of temperature, pressure, wavelength, and other relevant variables are included.