2,2,3,3,4,4,4 -七氟-1-丁醇和2,2,3,3,3,4,4,4 -七氟-乙酸丁酯:物理化学、热物理和光谱数据

IF 2.9 4区 工程技术 Q3 CHEMISTRY, PHYSICAL
Andrei V. Polkovnichenko, Evgenia I. Kovaleva, Alexey V. Kisel’, Sergey Ya. Kvashnin, Maria V. Mironova, Egor V. Lupachev
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引用次数: 0

摘要

提出了2,2,3,3,4,4,4 -七氟-1-丁醇(质量质量比≥0.998)和2,2,3,3,4,4,4 -七氟-乙酸丁酯(质量质量比≥0.994)的新理化数据。得到了2,2,3,3,4,4,4,4 -七氟-1-丁醇和2,2,3,3,3,4,4,4 -七氟乙酸丁酯的饱和蒸汽压随温度的变化规律。根据实验温度-压力相关数据,计算了安托万方程的系数。本文还介绍了所研究化合物的流变特性(粘度和黏性流动的表观活化能)的数据。研究了折射率和多余体积(密度)随温度的变化规律。并给出了傅里叶变换红外光谱。本文提供的实验数据扩展和补充了科学文献中提供的信息。这些数据是化工加工设备工程设计进一步研究的背景资料和出发点。此外,接收到的数据可以支持纯物质和包含它们的系统的属性模型的发展,例如相行为及其背后的过程。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

2, 2, 3, 3, 4, 4, 4-Heptafluoro-1-Butanol and 2, 2, 3, 3, 4, 4, 4-Heptafluorobutyl Acetate: Physicochemical, Thermophysical, and Spectral Data

2, 2, 3, 3, 4, 4, 4-Heptafluoro-1-Butanol and 2, 2, 3, 3, 4, 4, 4-Heptafluorobutyl Acetate: Physicochemical, Thermophysical, and Spectral Data

2, 2, 3, 3, 4, 4, 4-Heptafluoro-1-Butanol and 2, 2, 3, 3, 4, 4, 4-Heptafluorobutyl Acetate: Physicochemical, Thermophysical, and Spectral Data

New physicochemical data for 2, 2, 3, 3, 4, 4, 4-heptafluoro-1-butanol (≥ 0.998 mass fr.) and 2, 2, 3, 3, 4, 4, 4-heptafluorobutyl acetate (≥ 0.994 mass fr.) are presented. The dependences of the saturated vapor pressure of 2, 2, 3, 3, 4, 4, 4-heptafluoro-1-butanol and 2, 2, 3, 3, 4, 4, 4-heptafluorobutyl acetate on temperature were obtained. The coefficients of Antoine’s equation are calculated based on the experimental temperature–pressure dependence data. This article also presents data on the rheological properties (viscosity and apparent activation energy for the viscous flow) of the studied compounds. The dependencies of refractive index and excess volume (density) on temperature are studied. Fourier transform infrared spectroscopy spectra are also provided. The experimental data presented in this paper extend and complement the information presented in the scientific literature. These data are background information and a starting point for further research in engineering design of chemical processing equipment. In addition, the received data may support the development of property models of pure substances and systems containing them, such as phase behavior and the processes underlying it.

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来源期刊
CiteScore
4.10
自引率
9.10%
发文量
179
审稿时长
5 months
期刊介绍: International Journal of Thermophysics serves as an international medium for the publication of papers in thermophysics, assisting both generators and users of thermophysical properties data. This distinguished journal publishes both experimental and theoretical papers on thermophysical properties of matter in the liquid, gaseous, and solid states (including soft matter, biofluids, and nano- and bio-materials), on instrumentation and techniques leading to their measurement, and on computer studies of model and related systems. Studies in all ranges of temperature, pressure, wavelength, and other relevant variables are included.
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