{"title":"含蛋壳粉和粉煤灰的可持续自密实混凝土的性能和微观结构评价","authors":"Kalaiselvi Nivedha J , Mainak Mallik , Gokul Priya M , Saurabh Dubey","doi":"10.1016/j.scp.2025.102182","DOIUrl":null,"url":null,"abstract":"<div><div>In the pursuit of sustainable construction practices, this study evaluates the potential of eggshell powder (ESP) and fly ash as partial replacements for cement in self-compacting concrete (SCC). ESP, rich in calcium carbonate, and fly ash, known for its pozzolanic properties, were used at replacement levels of 5–20 % and 20 %, respectively. Comprehensive experiments assessed the fresh properties (slump flow, V-funnel, L-box, and J-ring), mechanical strength (compressive, split tensile, and flexural) at 7 and 28 days, and durability under acid exposure (HCl and H<sub>2</sub>SO <sub>3</sub>). Microstructural analyses via SEM and EDX confirmed the improved hydration and densification in the optimally dosed mixes. The findings revealed that replacing 10 % of the cement with ESP, along with 20 % fly ash, achieved the best performance, yielding a 14.7 % increase in compressive strength at 28 days compared to the control, enhanced tensile and flexural strengths, and superior acid resistance. However, higher ESP dosages (>10 %) led to strength and durability reduction due to increased porosity and excess unreacted CaCO<sub>3</sub>. The study demonstrates that optimized blends of ESP and fly ash can produce high-performance, eco-efficient SCC, providing a practical route toward circular economy practices and a reduced carbon footprint in concrete construction.</div></div>","PeriodicalId":22138,"journal":{"name":"Sustainable Chemistry and Pharmacy","volume":"48 ","pages":"Article 102182"},"PeriodicalIF":5.8000,"publicationDate":"2025-09-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Performance and microstructural evaluation of sustainable self-compacting concrete incorporating eggshell powder and fly ash as environmentally sustainable cement replacements\",\"authors\":\"Kalaiselvi Nivedha J , Mainak Mallik , Gokul Priya M , Saurabh Dubey\",\"doi\":\"10.1016/j.scp.2025.102182\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>In the pursuit of sustainable construction practices, this study evaluates the potential of eggshell powder (ESP) and fly ash as partial replacements for cement in self-compacting concrete (SCC). ESP, rich in calcium carbonate, and fly ash, known for its pozzolanic properties, were used at replacement levels of 5–20 % and 20 %, respectively. Comprehensive experiments assessed the fresh properties (slump flow, V-funnel, L-box, and J-ring), mechanical strength (compressive, split tensile, and flexural) at 7 and 28 days, and durability under acid exposure (HCl and H<sub>2</sub>SO <sub>3</sub>). Microstructural analyses via SEM and EDX confirmed the improved hydration and densification in the optimally dosed mixes. The findings revealed that replacing 10 % of the cement with ESP, along with 20 % fly ash, achieved the best performance, yielding a 14.7 % increase in compressive strength at 28 days compared to the control, enhanced tensile and flexural strengths, and superior acid resistance. However, higher ESP dosages (>10 %) led to strength and durability reduction due to increased porosity and excess unreacted CaCO<sub>3</sub>. The study demonstrates that optimized blends of ESP and fly ash can produce high-performance, eco-efficient SCC, providing a practical route toward circular economy practices and a reduced carbon footprint in concrete construction.</div></div>\",\"PeriodicalId\":22138,\"journal\":{\"name\":\"Sustainable Chemistry and Pharmacy\",\"volume\":\"48 \",\"pages\":\"Article 102182\"},\"PeriodicalIF\":5.8000,\"publicationDate\":\"2025-09-06\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Sustainable Chemistry and Pharmacy\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S2352554125002803\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Sustainable Chemistry and Pharmacy","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2352554125002803","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Performance and microstructural evaluation of sustainable self-compacting concrete incorporating eggshell powder and fly ash as environmentally sustainable cement replacements
In the pursuit of sustainable construction practices, this study evaluates the potential of eggshell powder (ESP) and fly ash as partial replacements for cement in self-compacting concrete (SCC). ESP, rich in calcium carbonate, and fly ash, known for its pozzolanic properties, were used at replacement levels of 5–20 % and 20 %, respectively. Comprehensive experiments assessed the fresh properties (slump flow, V-funnel, L-box, and J-ring), mechanical strength (compressive, split tensile, and flexural) at 7 and 28 days, and durability under acid exposure (HCl and H2SO 3). Microstructural analyses via SEM and EDX confirmed the improved hydration and densification in the optimally dosed mixes. The findings revealed that replacing 10 % of the cement with ESP, along with 20 % fly ash, achieved the best performance, yielding a 14.7 % increase in compressive strength at 28 days compared to the control, enhanced tensile and flexural strengths, and superior acid resistance. However, higher ESP dosages (>10 %) led to strength and durability reduction due to increased porosity and excess unreacted CaCO3. The study demonstrates that optimized blends of ESP and fly ash can produce high-performance, eco-efficient SCC, providing a practical route toward circular economy practices and a reduced carbon footprint in concrete construction.
期刊介绍:
Sustainable Chemistry and Pharmacy publishes research that is related to chemistry, pharmacy and sustainability science in a forward oriented manner. It provides a unique forum for the publication of innovative research on the intersection and overlap of chemistry and pharmacy on the one hand and sustainability on the other hand. This includes contributions related to increasing sustainability of chemistry and pharmaceutical science and industries itself as well as their products in relation to the contribution of these to sustainability itself. As an interdisciplinary and transdisciplinary journal it addresses all sustainability related issues along the life cycle of chemical and pharmaceutical products form resource related topics until the end of life of products. This includes not only natural science based approaches and issues but also from humanities, social science and economics as far as they are dealing with sustainability related to chemistry and pharmacy. Sustainable Chemistry and Pharmacy aims at bridging between disciplines as well as developing and developed countries.