{"title":"新型层状氧化硒化铜的复分解和构建块方法——有用的工具还是合成的死胡同?","authors":"Liam Kemp, Geoffrey Hyett","doi":"10.1039/d5mh01350j","DOIUrl":null,"url":null,"abstract":"<p><p>The use of metathesis, or ionic double displacement reactions, for the synthesis of layered copper oxyselenides is explored, and compared to the conventional solid state reaction approach across a range of temperatures. We have determined that metathesis does offer some advantages in product selectivity at low temperature but due to more complex synthetic requirements does not warrant more widespread adoption.</p>","PeriodicalId":87,"journal":{"name":"Materials Horizons","volume":" ","pages":""},"PeriodicalIF":10.7000,"publicationDate":"2025-09-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Metathesis and the building block approach to novel layered copper oxyselenides - useful tool or synthetic dead-end?\",\"authors\":\"Liam Kemp, Geoffrey Hyett\",\"doi\":\"10.1039/d5mh01350j\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p><p>The use of metathesis, or ionic double displacement reactions, for the synthesis of layered copper oxyselenides is explored, and compared to the conventional solid state reaction approach across a range of temperatures. We have determined that metathesis does offer some advantages in product selectivity at low temperature but due to more complex synthetic requirements does not warrant more widespread adoption.</p>\",\"PeriodicalId\":87,\"journal\":{\"name\":\"Materials Horizons\",\"volume\":\" \",\"pages\":\"\"},\"PeriodicalIF\":10.7000,\"publicationDate\":\"2025-09-05\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Materials Horizons\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://doi.org/10.1039/d5mh01350j\",\"RegionNum\":2,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Materials Horizons","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.1039/d5mh01350j","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Metathesis and the building block approach to novel layered copper oxyselenides - useful tool or synthetic dead-end?
The use of metathesis, or ionic double displacement reactions, for the synthesis of layered copper oxyselenides is explored, and compared to the conventional solid state reaction approach across a range of temperatures. We have determined that metathesis does offer some advantages in product selectivity at low temperature but due to more complex synthetic requirements does not warrant more widespread adoption.