5-（羟甲基）糠醛电合成2,5-呋喃二甲酸的新一代纳米材料：方法、机制和挑战

IF 4.1 3区化学 Q1 CHEMISTRY, ANALYTICAL

Journal of Electroanalytical Chemistry Pub Date : 2025-09-02 DOI:10.1016/j.jelechem.2025.119449

Gaurav Yadav , Nidhi Yadav , Saptarshi Roy , Prateek Shukla , Ramesh Kumar Sharma , Ganga Ram Chaudhary , Suman Singh , Suddhasatwa Basu , Md. Ahmaruzzaman

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引用次数: 0

摘要

在过去的几十年里，电化学技术的进步极大地改善了能源生产、储存、材料表面改性和环境清理。一个有前景的应用是电化学氧化（ECO） 5-羟甲基糠醛（HMF）生成2,5-呋喃二羧酸（FDCA）， HMF是一种关键的生物质衍生平台化学品。FDCA是一种有价值的生产聚呋喃酸酯（PEF）的单体，为传统的化学催化方法提供了一种可持续的替代方案，有助于生物质增值和生物精炼厂的发展。本文综述了纳米材料在HMF电合成FDCA中的应用前景。它涵盖(1)电催化剂，如金属有机框架（MOFs），金属氧化物，层状双氢氧化物（LDHs），碳基材料和金属硫化物；(2) FDCA电合成的驱动机制；(3)动力学和热力学因素；(4)扩大中试生产的挑战；(5) SWOT分析，确定推进FDCA电催化工艺的优势、劣势、机会和威胁。此外，本文还强调了HMF电化学转化的关键障碍和机遇。它为推进HMF转化高效电催化剂的开发提供了宝贵的见解，为该领域未来的研究和创新提供了重要的指导。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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Next generation nanomaterials for electrosynthesis of 2,5-furandicarboxylic acid from 5-(hydroxymethyl)furfural: approaches, mechanisms, and challenges

Over the past few decades, advancements in electrochemical technologies have significantly improved energy production, storage, material surface modification, and environmental cleanup. One promising application is the electrochemical oxidation (ECO) of 5-hydroxymethylfurfural (HMF), a key biomass-derived platform chemical, into 2,5-furandicarboxylic acid (FDCA). FDCA, a valuable monomer for producing polyethylene furanoate (PEF), offers a sustainable alternative to traditional chemo-catalytic methods, contributing to biomass valorization and the development of biorefineries. This review explores the potential of nanomaterials for the electrosynthesis of FDCA from HMF. It covers (1) electrocatalysts such as metal-organic frameworks (MOFs), metal oxides, layered double hydroxides (LDHs), carbon-based materials, and metal sulfides; (2) the mechanisms driving FDCA electrosynthesis; (3) kinetics and thermodynamic factors; (4) challenges in scaling up to pilot production; and (5) a SWOT analysis, identifying strengths, weaknesses, opportunities, and threats for advancing FDCA electrocatalytic processes. Additionally, this review highlights key obstacles and opportunities in the electrochemical conversion of HMF. It provides valuable insights for advancing the development of efficient electrocatalysts for HMF conversion, offering critical guidance for future research and innovation in this field.

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来源期刊

Journal of Electroanalytical Chemistry 化学-电化学

CiteScore

7.80

自引率

6.70%

发文量

912

审稿时长

2.4 months

期刊介绍： The Journal of Electroanalytical Chemistry is the foremost international journal devoted to the interdisciplinary subject of electrochemistry in all its aspects, theoretical as well as applied. Electrochemistry is a wide ranging area that is in a state of continuous evolution. Rather than compiling a long list of topics covered by the Journal, the editors would like to draw particular attention to the key issues of novelty, topicality and quality. Papers should present new and interesting electrochemical science in a way that is accessible to the reader. The presentation and discussion should be at a level that is consistent with the international status of the Journal. Reports describing the application of well-established techniques to problems that are essentially technical will not be accepted. Similarly, papers that report observations but fail to provide adequate interpretation will be rejected by the Editors. Papers dealing with technical electrochemistry should be submitted to other specialist journals unless the authors can show that their work provides substantially new insights into electrochemical processes.