将退役的风力涡轮机叶片升级为高性能工程木复合材料

IF 14.2 1区 材料科学 Q1 ENGINEERING, MULTIDISCIPLINARY
Hualei Zhang, Dekang Zuo, Mengfan Hu, Tiantian Zhang, Hongguang Liu, Li Li, Bin Luo
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引用次数: 0

摘要

风力涡轮机叶片中报废的玻璃纤维增强聚合物(GFRP)的处理构成了一个严峻的环境挑战,需要可持续的升级回收解决方案和实际利用。然而,化学惰性、低附着力的环氧树脂表面从根本上削弱了其增强潜力,这一障碍阻碍了其在高性能复合材料中的有效应用。在此,我们引入了一种可扩展且具有成本效益的策略,通过克服这一关键界面障碍,将这些有问题的废物升级为高性能,多功能工程木复合材料(EWC)。开发了一种定制设计的机械改性工艺,通过选择性去除惰性环氧树脂层来激活GFRP表面,形成粗糙,多孔且高度可湿性的界面。优化后的EWC-40复合材料,含有40%的改性GFRP,表现出显著的性能协同作用,包括抗弯强度(90.47 MPa)和内部粘合强度(1.56 MPa),大大超过传统木板。至关重要的是,该复合材料还表现出优异的防火安全性,峰值热释放率(pHRR)降低26.5%,总烟雾产量(TSP)降低45%。此外,它还表现出了出色的耐久性,不仅在剧烈加速老化循环后保持了良好的机械完整性,而且在抗腐蚀试验中达到了最高的耐久性等级(I级),质量损失比对照组减少了83.2%。本研究建立了一种具有成本效益和工业可行性的途径,将GFRP废物升级为优质结构材料,更广泛地说,证明了定向机械活化是一种强大的平台技术,可以使各种具有挑战性的热固性复合材料废物增值。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Upcycling decommissioned wind turbine blades into high-performance engineering wood composites
The disposal of end-of-life Glass Fiber Reinforced Polymer (GFRP) from wind turbine blades poses a critical environmental challenge, demanding sustainable upcycling solutions and practical utilization. However, unlocking its reinforcement potential is fundamentally crippled by the chemically inert, low-adhesion epoxy surface, a barrier that has precluded its effective use in high-performance composites. Herein, we introduce a scalable and cost-effective strategy to upcycle this problematic waste into high-performance, multifunctional engineering wood composites (EWC) by overcoming this critical interfacial barrier. A custom-designed mechanical modification process was developed to activate the GFRP surface, creating a rough, porous, and highly wettable interface by selectively removing the inert epoxy resin layer. The optimized EWC-40 composite, incorporating 40 % modified GFRP, demonstrated a remarkable synergy of properties, including a flexural strength (90.47 MPa) and internal bonding strength (1.56 MPa) that vastly surpass those of conventional wood panels. Crucially, the composite also exhibited superior fire safety, with a 26.5 % reduction in the peak heat release rate (pHRR) and a 45 % reduction in total smoke production (TSP). Furthermore, it demonstrated outstanding durability, not only retaining excellent mechanical integrity after aggressive accelerated aging cycles but also achieving the highest durability rating (Class I) in a decay resistance assay with 83.2 % less mass loss than the control. This study establishes a cost-effective and industrially viable pathway for upcycling GFRP waste into superior structural materials and, more broadly, demonstrates that targeted mechanical activation is a powerful platform technology for valorizing a wide range of challenging thermoset composite wastes.
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来源期刊
Composites Part B: Engineering
Composites Part B: Engineering 工程技术-材料科学:复合
CiteScore
24.40
自引率
11.50%
发文量
784
审稿时长
21 days
期刊介绍: Composites Part B: Engineering is a journal that publishes impactful research of high quality on composite materials. This research is supported by fundamental mechanics and materials science and engineering approaches. The targeted research can cover a wide range of length scales, ranging from nano to micro and meso, and even to the full product and structure level. The journal specifically focuses on engineering applications that involve high performance composites. These applications can range from low volume and high cost to high volume and low cost composite development. The main goal of the journal is to provide a platform for the prompt publication of original and high quality research. The emphasis is on design, development, modeling, validation, and manufacturing of engineering details and concepts. The journal welcomes both basic research papers and proposals for review articles. Authors are encouraged to address challenges across various application areas. These areas include, but are not limited to, aerospace, automotive, and other surface transportation. The journal also covers energy-related applications, with a focus on renewable energy. Other application areas include infrastructure, off-shore and maritime projects, health care technology, and recreational products.
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