Ross Chandler , Ignacio González-Álverez , John Mavrogenes , Luke Blais
{"title":"澳大利亚碳酸盐岩及其伴生REE-Nb矿化研究综述","authors":"Ross Chandler , Ignacio González-Álverez , John Mavrogenes , Luke Blais","doi":"10.1016/j.gexplo.2025.107870","DOIUrl":null,"url":null,"abstract":"<div><div>Australia has 16 known carbonatites, and two other occurrences of REE mineralisation interpreted as carbonatite-related. These are all located within Precambrian crust, and host known resources of c. 7.2 Mt. of rare earth oxides (containing c. 1.73 Mt. of Nd<sub>2</sub>O<sub>3</sub> and Pr<sub>6</sub>O<sub>11</sub>), and c. 2.7 Mt. of Nb<sub>2</sub>O<sub>5</sub>.</div><div>Australia's carbonatites range from Neoarchean to Jurassic, and display extreme diversity in geological characteristics, ranging from large, multiphase intrusive complexes dominated by either carbonatite (e.g. Gifford Creek and Mt. Weld, Western Australia) or silicate rocks (e.g. Cummins Range and Cundeelee, Western Australia), to single phase and small volume carbonatite dykes (e.g. Yungal dykes, Western Australia). Studied occurrences show similarly diverse radiogenic isotopic signatures (Rb/Sr and Sm/Nd), indicating derivation from a variety of mantle sources ranging from HIMU through to EM1.</div><div>Significant rare earth element (REE) and niobium (Nb) mineralisation occurs in both fresh and weathered carbonatites throughout Australia, with markedly different mineralogical and grade characteristics. While weathering history and preservation are crucial to the formation of supergene enrichments in REE and Nb, analysis of whole-rock geochemical data for different carbonatite types from the Mt. Weld and Gifford Creek complexes suggest primary magmatic composition plays the strongest determinant in the magnitude of grade increase, with siderite-dominated carbonatites having less potential for supergene upgrade than dolomite, ankerite and calcite-dominated examples.</div><div>The distinct geophysical signatures of Australia's known carbonatites have aided exploration efforts leading to early discoveries of deposits within highly magnetic complexes such as Mt. Weld and Cummins Range. Recent discoveries of geophysically subtle complexes (e.g. Gifford Creek complex, West Arunta) suggests both alternative geophysical techniques and a comprehensive structural understanding are crucial to discovery.</div><div>Explorers should focus on areas of known carbonatite magmatism, with a particular focus on developing an understanding of the regional structures that can facilitate carbonatite intrusion. On a local scale, the selection of relevant carbonatite geophysical and exploration signatures leveraging previous local discoveries should be prioritised. The small number of known carbonatites in Australia compared to the other continents abundances indicates further carbonatites and associated mineralisation may be discovered with increased exploration.</div></div>","PeriodicalId":16336,"journal":{"name":"Journal of Geochemical Exploration","volume":"279 ","pages":"Article 107870"},"PeriodicalIF":3.3000,"publicationDate":"2025-09-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"A review of Australian carbonatites and associated REE-Nb mineralisation\",\"authors\":\"Ross Chandler , Ignacio González-Álverez , John Mavrogenes , Luke Blais\",\"doi\":\"10.1016/j.gexplo.2025.107870\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Australia has 16 known carbonatites, and two other occurrences of REE mineralisation interpreted as carbonatite-related. These are all located within Precambrian crust, and host known resources of c. 7.2 Mt. of rare earth oxides (containing c. 1.73 Mt. of Nd<sub>2</sub>O<sub>3</sub> and Pr<sub>6</sub>O<sub>11</sub>), and c. 2.7 Mt. of Nb<sub>2</sub>O<sub>5</sub>.</div><div>Australia's carbonatites range from Neoarchean to Jurassic, and display extreme diversity in geological characteristics, ranging from large, multiphase intrusive complexes dominated by either carbonatite (e.g. Gifford Creek and Mt. Weld, Western Australia) or silicate rocks (e.g. Cummins Range and Cundeelee, Western Australia), to single phase and small volume carbonatite dykes (e.g. Yungal dykes, Western Australia). Studied occurrences show similarly diverse radiogenic isotopic signatures (Rb/Sr and Sm/Nd), indicating derivation from a variety of mantle sources ranging from HIMU through to EM1.</div><div>Significant rare earth element (REE) and niobium (Nb) mineralisation occurs in both fresh and weathered carbonatites throughout Australia, with markedly different mineralogical and grade characteristics. While weathering history and preservation are crucial to the formation of supergene enrichments in REE and Nb, analysis of whole-rock geochemical data for different carbonatite types from the Mt. Weld and Gifford Creek complexes suggest primary magmatic composition plays the strongest determinant in the magnitude of grade increase, with siderite-dominated carbonatites having less potential for supergene upgrade than dolomite, ankerite and calcite-dominated examples.</div><div>The distinct geophysical signatures of Australia's known carbonatites have aided exploration efforts leading to early discoveries of deposits within highly magnetic complexes such as Mt. Weld and Cummins Range. Recent discoveries of geophysically subtle complexes (e.g. Gifford Creek complex, West Arunta) suggests both alternative geophysical techniques and a comprehensive structural understanding are crucial to discovery.</div><div>Explorers should focus on areas of known carbonatite magmatism, with a particular focus on developing an understanding of the regional structures that can facilitate carbonatite intrusion. On a local scale, the selection of relevant carbonatite geophysical and exploration signatures leveraging previous local discoveries should be prioritised. The small number of known carbonatites in Australia compared to the other continents abundances indicates further carbonatites and associated mineralisation may be discovered with increased exploration.</div></div>\",\"PeriodicalId\":16336,\"journal\":{\"name\":\"Journal of Geochemical Exploration\",\"volume\":\"279 \",\"pages\":\"Article 107870\"},\"PeriodicalIF\":3.3000,\"publicationDate\":\"2025-09-05\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Geochemical Exploration\",\"FirstCategoryId\":\"89\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S037567422500202X\",\"RegionNum\":2,\"RegionCategory\":\"地球科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"GEOCHEMISTRY & GEOPHYSICS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Geochemical Exploration","FirstCategoryId":"89","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S037567422500202X","RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"GEOCHEMISTRY & GEOPHYSICS","Score":null,"Total":0}
A review of Australian carbonatites and associated REE-Nb mineralisation
Australia has 16 known carbonatites, and two other occurrences of REE mineralisation interpreted as carbonatite-related. These are all located within Precambrian crust, and host known resources of c. 7.2 Mt. of rare earth oxides (containing c. 1.73 Mt. of Nd2O3 and Pr6O11), and c. 2.7 Mt. of Nb2O5.
Australia's carbonatites range from Neoarchean to Jurassic, and display extreme diversity in geological characteristics, ranging from large, multiphase intrusive complexes dominated by either carbonatite (e.g. Gifford Creek and Mt. Weld, Western Australia) or silicate rocks (e.g. Cummins Range and Cundeelee, Western Australia), to single phase and small volume carbonatite dykes (e.g. Yungal dykes, Western Australia). Studied occurrences show similarly diverse radiogenic isotopic signatures (Rb/Sr and Sm/Nd), indicating derivation from a variety of mantle sources ranging from HIMU through to EM1.
Significant rare earth element (REE) and niobium (Nb) mineralisation occurs in both fresh and weathered carbonatites throughout Australia, with markedly different mineralogical and grade characteristics. While weathering history and preservation are crucial to the formation of supergene enrichments in REE and Nb, analysis of whole-rock geochemical data for different carbonatite types from the Mt. Weld and Gifford Creek complexes suggest primary magmatic composition plays the strongest determinant in the magnitude of grade increase, with siderite-dominated carbonatites having less potential for supergene upgrade than dolomite, ankerite and calcite-dominated examples.
The distinct geophysical signatures of Australia's known carbonatites have aided exploration efforts leading to early discoveries of deposits within highly magnetic complexes such as Mt. Weld and Cummins Range. Recent discoveries of geophysically subtle complexes (e.g. Gifford Creek complex, West Arunta) suggests both alternative geophysical techniques and a comprehensive structural understanding are crucial to discovery.
Explorers should focus on areas of known carbonatite magmatism, with a particular focus on developing an understanding of the regional structures that can facilitate carbonatite intrusion. On a local scale, the selection of relevant carbonatite geophysical and exploration signatures leveraging previous local discoveries should be prioritised. The small number of known carbonatites in Australia compared to the other continents abundances indicates further carbonatites and associated mineralisation may be discovered with increased exploration.
期刊介绍:
Journal of Geochemical Exploration is mostly dedicated to publication of original studies in exploration and environmental geochemistry and related topics.
Contributions considered of prevalent interest for the journal include researches based on the application of innovative methods to:
define the genesis and the evolution of mineral deposits including transfer of elements in large-scale mineralized areas.
analyze complex systems at the boundaries between bio-geochemistry, metal transport and mineral accumulation.
evaluate effects of historical mining activities on the surface environment.
trace pollutant sources and define their fate and transport models in the near-surface and surface environments involving solid, fluid and aerial matrices.
assess and quantify natural and technogenic radioactivity in the environment.
determine geochemical anomalies and set baseline reference values using compositional data analysis, multivariate statistics and geo-spatial analysis.
assess the impacts of anthropogenic contamination on ecosystems and human health at local and regional scale to prioritize and classify risks through deterministic and stochastic approaches.
Papers dedicated to the presentation of newly developed methods in analytical geochemistry to be applied in the field or in laboratory are also within the topics of interest for the journal.