Anand Parkash , Abudukeremu Kadier , Peng-Cheng Ma
{"title":"化学镀铜玄武岩纤维,重量轻,电导率高,耐腐蚀,适用于下一代通信网络","authors":"Anand Parkash , Abudukeremu Kadier , Peng-Cheng Ma","doi":"10.1016/j.materresbull.2025.113770","DOIUrl":null,"url":null,"abstract":"<div><div>The increasing demand for high-performance materials in advanced technological applications, such as next-generation communication networks and efficient energy transmission, necessitates materials with enhanced mechanical, electrical, and corrosion properties. To address this, this study presents surface-modified basalt fibers (BFs) achieved through a novel, precisely controlled electroless copper (Cu) deposition, resulting in enhanced properties. The electroless Cu deposition onto BFs was optimized by varying the deposition temperature (20–60 °C) to maximize electrical conductivity and tensile strength. An optimal deposition temperature of 50 °C yielded desirable properties, with microstructural analysis confirming a dense, highly crystalline Cu deposition that exhibited a high tensile strength of 1561 ± 320 MPa and a direct current (DC) electrical conductivity of 9.63 × 10<sup>7</sup> S/m, surpassing that of commercial Cu (5.96 × 10<sup>7</sup> S/m) and Ag (6.30 × 10<sup>7</sup> S/m). The corrosion behavior, evaluated by immersion testing in 5 v/v% sulfuric acid (H<sub>2</sub>SO<sub>4</sub>), indicated minimal corrosion. This surface modification also resulted in a significantly lower density of 3.34 g/cm³ (post-corrosion at 50 °C) compared to bulk Cu (8.96 g/cm³) and alternating current (AC) conductivities of 3.88 × 10<sup>7</sup> and 1.86 × 10<sup>7</sup> S/m (at 0.2 and 0.5 MHz, respectively). Consequently, these light-weight, sustainable materials demonstrate significant potential as alternatives to conventional Cu in applications demanding high conductivity, mechanical strength, and corrosion resistance, such as fifth-generation (5G) and future sixth-generation (6G) telecommunications, aerospace, and light-weight wires for power transmission.</div></div>","PeriodicalId":18265,"journal":{"name":"Materials Research Bulletin","volume":"194 ","pages":"Article 113770"},"PeriodicalIF":5.7000,"publicationDate":"2025-09-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Electroless copper-deposited basalt fibers with light-weight, high conductivity, and corrosion-resistance for next-generation communication networks\",\"authors\":\"Anand Parkash , Abudukeremu Kadier , Peng-Cheng Ma\",\"doi\":\"10.1016/j.materresbull.2025.113770\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>The increasing demand for high-performance materials in advanced technological applications, such as next-generation communication networks and efficient energy transmission, necessitates materials with enhanced mechanical, electrical, and corrosion properties. To address this, this study presents surface-modified basalt fibers (BFs) achieved through a novel, precisely controlled electroless copper (Cu) deposition, resulting in enhanced properties. The electroless Cu deposition onto BFs was optimized by varying the deposition temperature (20–60 °C) to maximize electrical conductivity and tensile strength. An optimal deposition temperature of 50 °C yielded desirable properties, with microstructural analysis confirming a dense, highly crystalline Cu deposition that exhibited a high tensile strength of 1561 ± 320 MPa and a direct current (DC) electrical conductivity of 9.63 × 10<sup>7</sup> S/m, surpassing that of commercial Cu (5.96 × 10<sup>7</sup> S/m) and Ag (6.30 × 10<sup>7</sup> S/m). The corrosion behavior, evaluated by immersion testing in 5 v/v% sulfuric acid (H<sub>2</sub>SO<sub>4</sub>), indicated minimal corrosion. This surface modification also resulted in a significantly lower density of 3.34 g/cm³ (post-corrosion at 50 °C) compared to bulk Cu (8.96 g/cm³) and alternating current (AC) conductivities of 3.88 × 10<sup>7</sup> and 1.86 × 10<sup>7</sup> S/m (at 0.2 and 0.5 MHz, respectively). Consequently, these light-weight, sustainable materials demonstrate significant potential as alternatives to conventional Cu in applications demanding high conductivity, mechanical strength, and corrosion resistance, such as fifth-generation (5G) and future sixth-generation (6G) telecommunications, aerospace, and light-weight wires for power transmission.</div></div>\",\"PeriodicalId\":18265,\"journal\":{\"name\":\"Materials Research Bulletin\",\"volume\":\"194 \",\"pages\":\"Article 113770\"},\"PeriodicalIF\":5.7000,\"publicationDate\":\"2025-09-02\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Materials Research Bulletin\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0025540825004775\",\"RegionNum\":3,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Materials Research Bulletin","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0025540825004775","RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
Electroless copper-deposited basalt fibers with light-weight, high conductivity, and corrosion-resistance for next-generation communication networks
The increasing demand for high-performance materials in advanced technological applications, such as next-generation communication networks and efficient energy transmission, necessitates materials with enhanced mechanical, electrical, and corrosion properties. To address this, this study presents surface-modified basalt fibers (BFs) achieved through a novel, precisely controlled electroless copper (Cu) deposition, resulting in enhanced properties. The electroless Cu deposition onto BFs was optimized by varying the deposition temperature (20–60 °C) to maximize electrical conductivity and tensile strength. An optimal deposition temperature of 50 °C yielded desirable properties, with microstructural analysis confirming a dense, highly crystalline Cu deposition that exhibited a high tensile strength of 1561 ± 320 MPa and a direct current (DC) electrical conductivity of 9.63 × 107 S/m, surpassing that of commercial Cu (5.96 × 107 S/m) and Ag (6.30 × 107 S/m). The corrosion behavior, evaluated by immersion testing in 5 v/v% sulfuric acid (H2SO4), indicated minimal corrosion. This surface modification also resulted in a significantly lower density of 3.34 g/cm³ (post-corrosion at 50 °C) compared to bulk Cu (8.96 g/cm³) and alternating current (AC) conductivities of 3.88 × 107 and 1.86 × 107 S/m (at 0.2 and 0.5 MHz, respectively). Consequently, these light-weight, sustainable materials demonstrate significant potential as alternatives to conventional Cu in applications demanding high conductivity, mechanical strength, and corrosion resistance, such as fifth-generation (5G) and future sixth-generation (6G) telecommunications, aerospace, and light-weight wires for power transmission.
期刊介绍:
Materials Research Bulletin is an international journal reporting high-impact research on processing-structure-property relationships in functional materials and nanomaterials with interesting electronic, magnetic, optical, thermal, mechanical or catalytic properties. Papers purely on thermodynamics or theoretical calculations (e.g., density functional theory) do not fall within the scope of the journal unless they also demonstrate a clear link to physical properties. Topics covered include functional materials (e.g., dielectrics, pyroelectrics, piezoelectrics, ferroelectrics, relaxors, thermoelectrics, etc.); electrochemistry and solid-state ionics (e.g., photovoltaics, batteries, sensors, and fuel cells); nanomaterials, graphene, and nanocomposites; luminescence and photocatalysis; crystal-structure and defect-structure analysis; novel electronics; non-crystalline solids; flexible electronics; protein-material interactions; and polymeric ion-exchange membranes.