耐久的双驱涂层,具有防污和防冰性能

IF 2.7 4区 化学 Q3 POLYMER SCIENCE
Shuyang Xing, Xin Wang, Wei Kuang, Xinyu Wang, Huilin Tian, Jianhan Huang, Ruiyi Luo
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引用次数: 0

摘要

开发环境可持续的制备方法对于开发高机械强度和优异防污性能的涂料至关重要。本文以γ-环氧基氧基三甲氧基硅烷(KH560)、纳米二氧化硅(SiO2)和1H,1H,2H,2H-全氟癸基三甲氧基硅烷(PFAS)为原料,在水环境中通过环氧开环反应制备了双驱涂料PKF-SiO2。所得的PKF-SiO2涂层具有优异的机械坚固性和防污性能。值得注意的是,即使经过1000次摩擦或弯曲试验,正十六烷、大豆油和甘油等液体也没有与涂层表面粘附。防冰评价进一步表明,PKF-SiO2涂层上的冰附着压力降低至17 kPa,而水滴的冻结时间延长至1167 s,与裸基材相比延迟了9 min。这些发现强调了PKF-SiO2涂层在纺织品和建筑等不同领域增强防污和自清洁保护方面的巨大潜力。以γ-缩水氧基丙基三甲氧基硅烷作为疏水粒子与聚氨酯之间的桥梁,制备了双驱水性涂料。该涂层具有优异的机械强度、防污性能和自清洁能力。与未涂覆的基底相比,双疏涂层的冻结时间延迟了9分钟,附着强度降低了17 kPa。这些结果突出了PKF-SiO2涂层在包括纺织和建筑在内的各种应用中增强防污和自清洁功能的潜力
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Durable dual-repellent coatings with anti-fouling and anti-icing performance

Durable dual-repellent coatings with anti-fouling and anti-icing performance
The development of environmentally sustainable preparation methods is crucial for developing coatings that combine high mechanical strength with superior antifouling properties. Herein, a dual-repellent coating (PKF-SiO2) was fabricated through an epoxy ring-opening reaction in an aqueous environment using γ-glycidoxypropyltrimethoxysilane (KH560), nanosilica (SiO2), and 1H,1H,2H,2H-perfluorodecyltrimethoxysilane (PFAS) as raw materials. The resulting PKF-SiO2 coating exhibited exceptional mechanical robustness and antifouling properties. Remarkably, liquids such as n-hexadecane, soybean oil, and glycerin showed no adhesion to the coating surface even after being subjected to 1000 cycles of friction or bending tests. Anti-icing evaluations further demonstrated that the ice adhesion pressure on the PKF-SiO2 coating was reduced to 17 kPa, whereas the freezing time of the water droplets was extended to 1167 s, representing a 9-min delay compared with that of the bare substrate. These findings underscore the promising potential of the PKF-SiO2 coating for enhancing antifouling and self-cleaning protection in diverse fields, such as textiles and construction. γ-glycidoxypropyltrimethoxysilane was used as a bridge between hydrophobic particles and polyurethane to prepare dual-repellent coating in aqueous environment. This coating demonstrates superior mechanical strength, antifouling properties, and self-cleaning capabilities. In comparison to the uncoated substrate, the amphiphobic coating exhibited a 9-minute delay in freezing time and a reduced adhesion strength of 17 kPa. These results highlight the promising potential of the PKF-SiO2 coating for enhancing antifouling and self-cleaning functionalities in various applications, including textiles and construction
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来源期刊
Polymer Journal
Polymer Journal 化学-高分子科学
CiteScore
5.60
自引率
7.10%
发文量
131
审稿时长
2.5 months
期刊介绍: Polymer Journal promotes research from all aspects of polymer science from anywhere in the world and aims to provide an integrated platform for scientific communication that assists the advancement of polymer science and related fields. The journal publishes Original Articles, Notes, Short Communications and Reviews. Subject areas and topics of particular interest within the journal''s scope include, but are not limited to, those listed below: Polymer synthesis and reactions Polymer structures Physical properties of polymers Polymer surface and interfaces Functional polymers Supramolecular polymers Self-assembled materials Biopolymers and bio-related polymer materials Polymer engineering.
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