Zhi-wei Yu, Ting-ting Huang, Chang-yi Deng, Juan Xiao, Hui Ding, Guan-cheng Xu, Li Zhang
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This review systematically summarizes the recent advancements in Cu-MOF derivatives for electrocatalytic CO<sub>2</sub>RR, focusing on preparation technologies such as the pyrolysis method, electrochemical in situ reconstruction method, and other methods. Subsequently, we investigated the enhancement mechanism of the reactivity of electrocatalysts by discussing multidimensional aspects, which include structural design, metal composition adjustment, ligand engineering, and composite structure construction. Finally, the critical challenges and future research directions of Cu-MOF derivatives for electrocatalytic CO<sub>2</sub>RR are prospectively discussed, which aims to provide theoretical references for the design methods and modification strategies of Cu-MOF derivatives.</p><h3>Graphical Abstract</h3><p>This manuscript highlights the application of copper-based metal–organic framework (Cu-MOF) derivatives in electrocatalytic CO<sub>2</sub> reduction reaction (CO<sub>2</sub>RR). We specifically carry out the following three key aspects: synthesis methods of Cu-MOF derivatives, modification strategies, and prospects. It aims to propose rational synthesis methods and modification strategies for the preparation of Cu-MOF-derived electrocatalysts with superior CO<sub>2</sub>RR performance.</p>\n<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":802,"journal":{"name":"Topics in Current Chemistry","volume":"383 4","pages":""},"PeriodicalIF":8.8000,"publicationDate":"2025-09-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Encompassing Synthetic Methods to Modification Strategies: Cu-MOF-Derived Electrocatalysts for Enhancing CO2 Reduction\",\"authors\":\"Zhi-wei Yu, Ting-ting Huang, Chang-yi Deng, Juan Xiao, Hui Ding, Guan-cheng Xu, Li Zhang\",\"doi\":\"10.1007/s41061-025-00524-w\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>To address the global climate challenge, carbon emissions reduction and carbon neutrality have emerged as pivotal goals for the international community. Copper-based metal–organic framework (Cu-MOF) derivatives exhibit unique advantages in electrocatalytic carbon dioxide reduction reaction (CO<sub>2</sub>RR) applications due to their controllable pore structure, abundant active sites, and efficient charge transport. Nevertheless, the structure–activity correlation mechanisms and performance enhancement methodologies of Cu-MOF derivatives have not yet been comprehensively elucidated in existing literature. This review systematically summarizes the recent advancements in Cu-MOF derivatives for electrocatalytic CO<sub>2</sub>RR, focusing on preparation technologies such as the pyrolysis method, electrochemical in situ reconstruction method, and other methods. Subsequently, we investigated the enhancement mechanism of the reactivity of electrocatalysts by discussing multidimensional aspects, which include structural design, metal composition adjustment, ligand engineering, and composite structure construction. Finally, the critical challenges and future research directions of Cu-MOF derivatives for electrocatalytic CO<sub>2</sub>RR are prospectively discussed, which aims to provide theoretical references for the design methods and modification strategies of Cu-MOF derivatives.</p><h3>Graphical Abstract</h3><p>This manuscript highlights the application of copper-based metal–organic framework (Cu-MOF) derivatives in electrocatalytic CO<sub>2</sub> reduction reaction (CO<sub>2</sub>RR). We specifically carry out the following three key aspects: synthesis methods of Cu-MOF derivatives, modification strategies, and prospects. It aims to propose rational synthesis methods and modification strategies for the preparation of Cu-MOF-derived electrocatalysts with superior CO<sub>2</sub>RR performance.</p>\\n<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>\",\"PeriodicalId\":802,\"journal\":{\"name\":\"Topics in Current Chemistry\",\"volume\":\"383 4\",\"pages\":\"\"},\"PeriodicalIF\":8.8000,\"publicationDate\":\"2025-09-05\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Topics in Current Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s41061-025-00524-w\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"Chemistry\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Topics in Current Chemistry","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s41061-025-00524-w","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"Chemistry","Score":null,"Total":0}
Encompassing Synthetic Methods to Modification Strategies: Cu-MOF-Derived Electrocatalysts for Enhancing CO2 Reduction
To address the global climate challenge, carbon emissions reduction and carbon neutrality have emerged as pivotal goals for the international community. Copper-based metal–organic framework (Cu-MOF) derivatives exhibit unique advantages in electrocatalytic carbon dioxide reduction reaction (CO2RR) applications due to their controllable pore structure, abundant active sites, and efficient charge transport. Nevertheless, the structure–activity correlation mechanisms and performance enhancement methodologies of Cu-MOF derivatives have not yet been comprehensively elucidated in existing literature. This review systematically summarizes the recent advancements in Cu-MOF derivatives for electrocatalytic CO2RR, focusing on preparation technologies such as the pyrolysis method, electrochemical in situ reconstruction method, and other methods. Subsequently, we investigated the enhancement mechanism of the reactivity of electrocatalysts by discussing multidimensional aspects, which include structural design, metal composition adjustment, ligand engineering, and composite structure construction. Finally, the critical challenges and future research directions of Cu-MOF derivatives for electrocatalytic CO2RR are prospectively discussed, which aims to provide theoretical references for the design methods and modification strategies of Cu-MOF derivatives.
Graphical Abstract
This manuscript highlights the application of copper-based metal–organic framework (Cu-MOF) derivatives in electrocatalytic CO2 reduction reaction (CO2RR). We specifically carry out the following three key aspects: synthesis methods of Cu-MOF derivatives, modification strategies, and prospects. It aims to propose rational synthesis methods and modification strategies for the preparation of Cu-MOF-derived electrocatalysts with superior CO2RR performance.
期刊介绍:
Topics in Current Chemistry provides in-depth analyses and forward-thinking perspectives on the latest advancements in chemical research. This renowned journal encompasses various domains within chemical science and their intersections with biology, medicine, physics, and materials science.
Each collection within the journal aims to offer a comprehensive understanding, accessible to both academic and industrial readers, of emerging research in an area that captivates a broader scientific community.
In essence, Topics in Current Chemistry illuminates cutting-edge chemical research, fosters interdisciplinary collaboration, and facilitates knowledge-sharing among diverse scientific audiences.