Dae-Yeong Kim, Zhang Wenjun, Kaiyue Dong, Bang Lu, Duanxing Li, Satoru Takakusagi, Shinya Furukawa and Tomohiro Nozaki
{"title":"Ni-In金属间催化剂上逆水气转换反应的等离子体驱动氧化还原机制","authors":"Dae-Yeong Kim, Zhang Wenjun, Kaiyue Dong, Bang Lu, Duanxing Li, Satoru Takakusagi, Shinya Furukawa and Tomohiro Nozaki","doi":"10.1039/D5EY00101C","DOIUrl":null,"url":null,"abstract":"<p >The reverse water–gas shift (RWGS) reaction has been recognized as a promising strategy for CO<small><sub>2</sub></small> valorization. However, it faces limitations due to low activity and poor CO selectivity at low temperatures. In this study, we report that plasma can effectively promote the low-temperature RWGS reaction over Ni–In intermetallic catalysts. The formation of the Ni–In intermetallic phases completely suppresses CH<small><sub>4</sub></small> formation and achieves 100% CO selectivity. Through <em>in situ</em> transmission infrared spectroscopy (TIR) and <em>in situ</em> X-ray absorption fine-structure (XAFS) analysis, we monitored the changes occurring on the catalyst surface during the plasma reaction. The interaction between redox-active sites present in the Ni–In intermetallic catalysts and plasma-activated species lowers the activation energy, thereby facilitating the RWGS reaction at low temperatures. This study offers fundamental insights into how plasma-activated species enhance catalysis and the underlying mechanisms of low-temperature activation in plasma catalysis.</p>","PeriodicalId":72877,"journal":{"name":"EES catalysis","volume":" 5","pages":" 1098-1105"},"PeriodicalIF":0.0000,"publicationDate":"2025-07-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.rsc.org/en/content/articlepdf/2025/ey/d5ey00101c?page=search","citationCount":"0","resultStr":"{\"title\":\"Plasma-driven redox mechanism in the reverse water–gas shift reaction over Ni–In intermetallic catalysts†\",\"authors\":\"Dae-Yeong Kim, Zhang Wenjun, Kaiyue Dong, Bang Lu, Duanxing Li, Satoru Takakusagi, Shinya Furukawa and Tomohiro Nozaki\",\"doi\":\"10.1039/D5EY00101C\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p >The reverse water–gas shift (RWGS) reaction has been recognized as a promising strategy for CO<small><sub>2</sub></small> valorization. However, it faces limitations due to low activity and poor CO selectivity at low temperatures. In this study, we report that plasma can effectively promote the low-temperature RWGS reaction over Ni–In intermetallic catalysts. The formation of the Ni–In intermetallic phases completely suppresses CH<small><sub>4</sub></small> formation and achieves 100% CO selectivity. Through <em>in situ</em> transmission infrared spectroscopy (TIR) and <em>in situ</em> X-ray absorption fine-structure (XAFS) analysis, we monitored the changes occurring on the catalyst surface during the plasma reaction. The interaction between redox-active sites present in the Ni–In intermetallic catalysts and plasma-activated species lowers the activation energy, thereby facilitating the RWGS reaction at low temperatures. This study offers fundamental insights into how plasma-activated species enhance catalysis and the underlying mechanisms of low-temperature activation in plasma catalysis.</p>\",\"PeriodicalId\":72877,\"journal\":{\"name\":\"EES catalysis\",\"volume\":\" 5\",\"pages\":\" 1098-1105\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2025-07-17\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://pubs.rsc.org/en/content/articlepdf/2025/ey/d5ey00101c?page=search\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"EES catalysis\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://pubs.rsc.org/en/content/articlelanding/2025/ey/d5ey00101c\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"EES catalysis","FirstCategoryId":"1085","ListUrlMain":"https://pubs.rsc.org/en/content/articlelanding/2025/ey/d5ey00101c","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Plasma-driven redox mechanism in the reverse water–gas shift reaction over Ni–In intermetallic catalysts†
The reverse water–gas shift (RWGS) reaction has been recognized as a promising strategy for CO2 valorization. However, it faces limitations due to low activity and poor CO selectivity at low temperatures. In this study, we report that plasma can effectively promote the low-temperature RWGS reaction over Ni–In intermetallic catalysts. The formation of the Ni–In intermetallic phases completely suppresses CH4 formation and achieves 100% CO selectivity. Through in situ transmission infrared spectroscopy (TIR) and in situ X-ray absorption fine-structure (XAFS) analysis, we monitored the changes occurring on the catalyst surface during the plasma reaction. The interaction between redox-active sites present in the Ni–In intermetallic catalysts and plasma-activated species lowers the activation energy, thereby facilitating the RWGS reaction at low temperatures. This study offers fundamental insights into how plasma-activated species enhance catalysis and the underlying mechanisms of low-temperature activation in plasma catalysis.